6533b872fe1ef96bd12d2e1e

RESEARCH PRODUCT

High-pressure structural phase transition inMnWO4

Daniel ErrandoneaDavid Santamaría-pérezDavid Santamaría-pérezAlexandra FriedrichJuan Angel SansJavier Ruiz-fuertesOscar GomisWolfgang Morgenroth

subject

DiffractionPhase transitionMaterials scienceTungstatesCrystal structureTriclinic crystal systemCondensed Matter PhysicsElectronic Optical and Magnetic MaterialsCondensed Matter::Materials ScienceCrystallographychemistry.chemical_compoundsymbols.namesakeCrystal-structureTungstatechemistryFISICA APLICADAsymbolsCondensed Matter::Strongly Correlated ElectronsMultiferroicsRaman spectroscopyDiffractionMonoclinic crystal system

description

The pressure-induced phase transition of the multiferroic manganese tungstate MnWO4 is studied on single crystals using synchrotron x-ray diffraction and Raman spectroscopy. We observe the monoclinic P2/c to triclinic P (1) over bar phase transition at 20.1 GPa and get insight on the phase transition mechanism from the appearance of tilted triclinic domains. Selective Raman spectroscopy experiments with single crystals have shown that the onset of the phase transition occurs 5 GPa below the previously reported pressure obtained from experiments performed with powder samples.

https://doi.org/10.1103/physrevb.91.104109