6533b872fe1ef96bd12d394a

RESEARCH PRODUCT

Crystal structure ofcis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-diene

Ernesto Schulz LangGabriela N. LedesmaSandra SignorellaDavi F. Back

subject

crystal structureC—H...O interactionsDieneStereochemistrychemistry.chemical_elementManganeseCrystal structureRelated derivatives010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesResearch Communications//purl.org/becyt/ford/1 [https]CrystalB-phenyldioxazaborocinechemistry.chemical_compoundzwitterionic heterocycleB-PhenyldioxazaborocineN-B Dative Bond//purl.org/becyt/ford/1.4 [https]General Materials ScienceZwitterionic HeterocycleCrystallographyC-Ho InteractionsHydrogen bondChemistryOtras Ciencias QuímicasCiencias QuímicasN—B dative bondGeneral ChemistryCondensed Matter Physics0104 chemical sciencesB-phenyl­dioxaza­borocineC—H⋯O inter­actionsQD901-999Tripodal ligandCrystal StructureCIENCIAS NATURALES Y EXACTASDeca-

description

The present work describes the synthesis and crystal structure of the new B-phenyl­oxaza­borocine, C26H23BN2O2. The title compound adopts a zwitterionic form with a significant intra­molecular N→B dative bond and inter­molecular C—H⋯O inter­actions connecting mol­ecules parallel to the b axis.

yearjournalcountryeditionlanguage
2017-11-01Acta Crystallographica Section E Crystallographic Communications
https://doi.org/10.1107/s2056989017016553