6533b872fe1ef96bd12d4207

RESEARCH PRODUCT

Phase Equilibria in the Systems 2-Methyl-2-propanol + Methyl 1,1-Dimethylpropyl Ether and 2-Methylpentane + 2-Methyl-2-propanol + Methyl 1,1-Dimethylpropyl Ether

Antonio AucejoSonia LorasLuis Miguel OrdoñezRosa Muñoz

subject

Ternary numeral systemUNIQUAC2-MethylpentaneGeneral Chemical EngineeringThermodynamicsEtherGeneral ChemistryMedicinal chemistryPropanolchemistry.chemical_compoundchemistryAzeotropeNon-random two-liquid modelBinary system

description

Consistent vapor−liquid equilibrium data for the binary and ternary systems 2-methyl-2-propanol (TBA) + methyl 1,1-dimethylpropyl ether (TAME) at temperatures from 353 to 359 K and 2-methylpentane + 2-methyl-2-propanol (TBA) + methyl 1,1-dimethylpropyl ether (TAME) from 332 to 353 K are reported at 101.3 kPa. The results indicate that the systems deviate positively from ideality and that only the binary system presents an azeotrope. The ternary system is well predicted from binary data. The activity coefficients and boiling points of the solutions were correlated with composition by Wilson, UNIQUAC, NRTL, and Wisniak−Tamir equations.

yearjournalcountryeditionlanguage
1999-10-14Journal of Chemical & Engineering Data
https://doi.org/10.1021/je990080q