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RESEARCH PRODUCT
Spin crossover behaviour in the iron(II)-2,2-dipyridilamine system: Synthesis, X-ray structure and magnetic studies
Ana B. GasparJosé Antonio RealGloria AgustíGeorgiy LevchenkoVíctor MartínezMari Carmen Munozsubject
Condensed matter physicsX-raychemistry.chemical_elementNitrogenMagnetic susceptibilityIonInorganic Chemistrychemistry.chemical_compoundCrystallographyMonomerchemistrySpin crossoverMaterials ChemistryPhysical and Theoretical ChemistryMonoclinic crystal systemAmbient pressuredescription
Abstract The monomeric compounds [Fe(dpa)2(X)2] · solv [X = NCS−(solv = 0.5H2O) (1), N ( CN ) 2 - (2) and dpa = 2,2-dipyridilamine] have been synthesised and characterised. They crystallise in the P21/n and in the Cc monoclinic systems, respectively. Four of six nitrogen atoms coordinated to the Fe(II) ions belong to two dpa ligands which lie in cis conformation. The remaining positions are occupied by two nitrogen atoms of the pseudo-halide ligands. The magnetic susceptibility measurements at ambient pressure have revealed that compound 1 exhibits an incomplete spin crossover behaviour (T1/2 ≈ 88 K), whereas compound 2 remains in the high-spin configuration. Pressure studies performed on compound 1 have shown virtually complete spin crossover behaviour as pressure attains 6.5 kbar.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2005-09-01 | Inorganica Chimica Acta |