6533b874fe1ef96bd12d618e
RESEARCH PRODUCT
Manganese(III)-mediated oxidative carbon-carbon bond cleavage of the 1,10-phenanthroline-5,6-dione ligand
Isabel FernándezDante GatteschiAndrea CaneschiJosé Antonio RealAna B. GasparRafael RuizM. Carmen Muñozsubject
chemistry.chemical_classificationQuinone complexesPolynuclear complexesAqueous solutionLigandCarboxylato complexesPhenanthrolinechemistry.chemical_elementCrystal structureManganesePhotochemistryCleavage (embryo)Medicinal chemistryInorganic Chemistrychemistry.chemical_compoundchemistryCarbon–carbon bondYield (chemistry)FISICA APLICADACrystal structuresOxidationMaterials ChemistryPhysical and Theoretical ChemistryManganese complexesdescription
[EN] A new manganese(III)-1,10-phenanthroline-5,6-dione (phendione) complex possessing a putative Mn-2(mu-O) (mu-O2CMe)(2) core has been found to undergo a Ligand-based oxidative cleavage of the C(5)-C(6) bond in weak acid aqueous MeOH under aerobic conditions at room temperature to yield 2,2'-bipyridyl-3,3'-dicarboxylate with co-reduction to the corresponding Mn-II-phendione species.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1999-11-01 |