Search results for " ATO"

Bellbergite?a new mineral with the zeolite structure type EAB

1993

The new mineral bellbergite, (K, Ba, Sr)2Sr2Ca2(Ca, Na)4Al18Si18O72 · 30H2O, has been found in Ca-rich xenoliths at the Bellberg volcano near Mayen, Eifel, Germany. It occurs as well formed bipyramids with a length up to 0.3 mm. Possible space groups are P63/mmc, P62c and P63mc with a = 13.244(1) A, c = 15.988(2) A, V = 2429 A3, Z = 1. The density is: Dm, = 2.20(2) Mg/m3, Dc = 2.19 Mg/m3. The empirical formula based on 72 oxygen atoms is: Ba0.26Na0.72K1.33Sr2.36Ca5.32Al17.55Si18.36O72 · 30H2O. The mineral is uniaxial negative with ω = 1.522(2) and e = 1.507(2) (λ = 589 nm). The strongest lines in the X-ray powder pattern are (d (A), I, hkl): 3.80 (100) (300, 212, 104), 6.58 (80) (102), 2.95…

What Is the Limit of Atom Encapsulation for Icosahedral Carboranes?

2015

The stability of endohedral carboranes X@{1,n-C2B10H12} (X = Li(+), Be(2+); n = 2, 7, 12) and X@{CB11H12(-)} (X = Li(+), Be(2+)) is studied using electronic structure calculations with the B3LYP/6-311+G(d,p) model. Our calculations suggest that all endohedral compounds are local energy minima; for the exohedral complexes X···cage, the global energy minimum always corresponds to the X atom above a triangular face of the icosahedron. In the latter the X atom is furthest apart from the carbon atoms of the cage. As opposite to exohedral {Be(2+)···cage} complexes, no global energy minima were found for exohedral complexes {Li(+)···cage} whereby a carbon atom is present in the triangular face of …

Ab initiosimulations on rutile-based titania nanowires

2012

The rod symmetry groups for monoperiodic (1D) nanostructures have been applied for construction of models for bulk-like TiO2 nanowires (NWs) cut from a rutile-based 3D crystal along the chosen [001] and [110] directions of crystallographic axes. In this study, we have considered nanowires described by both the Ti-atom centered rotation axes as well as the hollow site centered axes passing through the interstitial positions between the Ti and O atoms closest to the axes. The most stable [001]-oriented TiO2 NWs with rhombic cross sections are found to display the energetically preferable {110} facets only while the nanowires with quasi-square sections across the [110] axis are formed by the a…

1,2,3-Triazoles Fused to Aromatic Rings

2014

The structure, synthesis, reactivity and applications of 1,2,3-triazoles fused to aromatic rings are described. These compounds have been classified in two groups by a structural approach: (a) fused 1,2,3-triazoles without a bridgehead nitrogen atom and (b) fused 1,2,3-triazoles with a bridgehead nitrogen atom. Although both systems present a similar structure, the synthetic procedures and their reactivity are different.

Gas cell studies of thorium using filament dispensers at IGISOL

2020

Abstract Filament-based dispensers of thorium have been investigated at the IGISOL facility, Jyvaskyla, for potential use as a thorium ion source for future collinear laser spectroscopy experiments. Several different filaments were manufactured in the Institute of Atomic and Subatomic Physics of TU Wien, with 232Th and 229Th prepared on tantalum substrates either by drying thorium nitrate solution or via molecular plating, while adding a layer of zirconium for oxide reduction. The filaments were characterized in a helium-filled gas cell by performing selective and efficient in-gas-cell resonance laser ionization and by analyzing the resulting ion beams by mass spectrometry. Additionally, th…

Multiple Site-Specific Binding of Fis Protein to Escherichia coli nuoA-N Promoter DNA and its Impact on DNA Topology Visualised by Means of Scanning …

2004

Therapeutic application of T cell receptor mimic peptides or cDNA in the treatment of T cell-mediated skin diseases

2000

An 8-amino acid peptide encoding a sequence of the transmembrane region of the T cell receptor alpha chain (TCR-alpha) was shown to inhibit T cell function by preventing functional assembly of the T cell receptor (mimic peptide). To avoid systemic immunosuppression by peptide application in vivo, we used a topical application of the peptide. In the system of murine contact sensitivity, topical application of the peptide inhibited the elicitation of contact sensitivity following application of a contact allergen in sensitized animals. Alternatively, when naked DNA encoding the peptide sequence was injected into skin before application of a contact allergen to sensitized animals, local immuno…

Modulational instability and generation of self-induced transparency solitons in resonant optical fibers

2009

International audience; We consider continuous-wave propagation through a fiber doped with two-level resonant atoms, which is described by a system of nonlinear Schrodinger-Maxwell-Bloch (NLS-MB) equations. We identify the modulational instability (MI) conditions required for the generation of ultrashort pulses, in cases of both anomalous and normal GVD (group-velocity dispersion). It is shown that the self-induced transparency (SIT) induces non-conventional MI sidebands. The main result is a prediction of the existence of both bright and dark SIT solitons in the anomalous and normal GVD regimes.

Dipolar coupling of nanoparticle-molecule assemblies: An efficient approach for studying strong coupling

2021

Strong light-matter interactions facilitate not only emerging applications in quantum and non-linear optics but also modifications of materials properties. In particular the latter possibility has spurred the development of advanced theoretical techniques that can accurately capture both quantum optical and quantum chemical degrees of freedom. These methods are, however, computationally very demanding, which limits their application range. Here, we demonstrate that the optical spectra of nanoparticle-molecule assemblies, including strong coupling effects, can be predicted with good accuracy using a subsystem approach, in which the response functions of the different units are coupled only a…

Continuous-Variable Tomography of Solitary Electrons

2019

A method for characterising the wave-function of freely-propagating particles would provide a useful tool for developing quantum-information technologies with single electronic excitations. Previous continuous-variable quantum tomography techniques developed to analyse electronic excitations in the energy-time domain have been limited to energies close to the Fermi level. We show that a wide-band tomography of single-particle distributions is possible using energy-time filtering and that the Wigner representation of the mixed-state density matrix can be reconstructed for solitary electrons emitted by an on-demand single-electron source. These are highly localised distributions, isolated fro…