Search results for " CO2."
showing 10 items of 160 documents
Optimisation of Conditions for Extraction of Biologically Active Compounds from Common Bryophytes in Latvia / Latvijâ Augoðu Briofîtu Ekstrakcijas Ap…
2015
Abstract Bryophytes are the second largest taxonomic group in the plant kingdom. They contain a high number of biologically active compounds. Studies of their composition are important for understanding evolutionary processes in the plant kingdom. The aim of this study was to assess bryophyte secondary metabolite extraction options and to increase the yields of polyphenols and substances determining the free radical scavenging activity of bryophyte extracts. Similar studies have been conducted using higher plants as model organisms, but not using bryophytes. Comparison of five extraction methods (conventional, Soxhlet extraction, treatment with microwaves, ultrasound, and supercritical CO2 …
Aspectos medioambientales y biomédicos de la Química Supramolecular de azaciclofanos derivados de la piridina y el pirazol
2015
Basándonos en las pautas descritas para obtener receptores capaces de interaccionar con determinados sustratos, se ha sintetizado un gran familia de azaciclofanos de condensación [1+1] en los que se han utilizado diferentes cadenas poliamínicas. Además, los receptores presentan un anillo heterocíclico a modo de espaciador, que aporta rigidez al ciclo y al mismo tiempo átomos de union adicionales. En este caso, se han utilizado anillos de piridina y pirazol. Por su parte, trabajar con poliaminas, ofrece una serie de ventajas ya que son relativamente económicas, fáciles de modificar mediante rutas sintéticas, presentan una gran versatilidad a la hora de interaccionar con los sustratos en func…
Behavior of rare earth elements in an aquifer perturbed by CO2 injection: Environmental implications
2019
International audience; Three cubic-meters of CO2-saturated water was injected into a subsurface fractured aquifer in a post-mined area, using a push-pull test protocol. Groundwater samples were collected before and after CO2-injection to quantify geochemical changes. CO2-injection initially reduced the pH of water from 7.3 to 5.7, led to the enrichment of major ions (Ca2+, Mg2+, and alkalinity), and dissolved trace metals (including Fe, Mn, As, and Zn) in the groundwater. Rare earth elements (REE) and yttrium concentrations were also measured in these samples before and after CO2 perturbation, to evaluate their behavior. An enrichment of total Y plus REE (REY) occurred. REY fractionation w…
Isotope distribution of dissolved carbonate species in southeastern coastal aquifers of Sicily (Italy)
2007
Concentrations of major ions and the δ13C composition of dissolved inorganic carbon in groundwater and submarine groundwater discharges in the area between Siracusa and Ragusa provinces, southeastern Sicily, representing coastal carbonate aquifers, are presented and discussed. Most of groundwater analysed belongs to calcium bicarbonate type, in agreement with the geological nature of carbonate host rocks. Carbonate groundwater acquires, besides the dissolution of carbonate minerals, dissolved carbon (and the relative isotopic composition) from the atmosphere and from soil biological activity. In fact, δ13C values and total dissolved inorganic carbon contents show that both these sources con…
Measurements of volcanic SO2 and CO2 fluxes by combined DOAS, Multi-GAS and FTIR observations: a case study from Turrialba and Telica volcanoes
2014
Over the past few decades, substantial progress has been made to overcome the technical difficulties of continuously measuring volcanic SO2 emissions. However, measurements of CO2 emissions still present many difficulties, partly due to the lack of instruments that can directly measure CO2 emissions and partly due to its strong atmospheric background. In order to overcome these difficulties, a commonly taken approach is to combine differential optical absorption spectroscopy (DOAS) by using NOVAC scan-DOAS instruments for continuous measurements of crateric SO2 emissions, and electrochemical/NDIR multi-component gas analyser system (multi-GAS) instruments for measuring CO2/SO2 ratios of exc…
Continuous monitoring of hydrogen and carbon dioxide at Mt Etna
2013
article i nfo This study assessed the use of an H2 fuel cell as an H2-selective sensor for volcano monitoring. The resolution, repeatability, and cross-sensitivity of the sensor were investigated and evaluated under known laboratory conditions. A tailor-made device was developed and used for continuously monitoring H2 and CO2 at Mt Etna throughout 2009 and 2010. The temporal variations of both parameters were strongly correlated with the evolution of the volcanic activity during the monitoring period. In particular, the CO2 flux exhibited long-term variations, while H2 exhibited pulses immediately before the explosive activity that occurred at Mt Etna during 2010.
Fault-controlled Soil CO2 Degassing and Shallow Magma Bodies: Summit and Lower East Rift of Kilauea Volcano (Hawaii), 1997
2006
Soil CO2 flux measurements were carried out along traverses across mapped faults and eruptive fissures on the summit and the lower East Rift Zone of Kilauea volcano. Anomalous levels of soil degassing were found for 44 of the tectonic structures and 47 of the eruptive fissures intercepted by the surveyed profiles. This result contrasts with what was recently observed on Mt. Etna, where most of the surveyed faults were associated with anomalous soil degassing. The difference is probably related to the differences in the state of activity at the time when soil gas measurements were made: Kilauea was erupting, whereas Mt. Etna was quiescent although in a pre-eruptive stage. Unlike Mt. Etna, fl…
Long-time variation of soil CO2 fluxes at the summit crater of Vulcano (Italy)
2012
Here, we report the first continuous data of geochemical parameters acquired directly from the active summit crater of Vulcano. This approach provides a means to better investigate deep geochemical processes associated with the degassing system of Vulcano Island. In particular, we report on soil CO2 fluxes from the upper part of Vulcano, a closed-conduit volcano, from September 2007 to October 2010. Large variations in the soil CO2 and plume SO2 fluxes (order of magnitude), coinciding with other discontinuous geochemical parameters (CO2 concentrations in fumarole gas) and physical parameters (increase of shallow seismic activity and fumarole temperatures) have been recorded. The results fro…
Volcanic CO2 flux measurement at Campi Flegrei by tunable diode laser absorption spectroscopy
2014
Near-infrared room-temperature Tunable Diode Lasers (TDL) have recently found increased usage in atmospheric chemistry and air monitoring research, but applications in volcanology are still limited to a few examples. Here, we explored the potential of a commercial infrared laser unit (GasFinder 2.0 from Boreal Laser Ltd) for measurement of volcanic CO2 mixing ratios, and ultimately for estimating the volcanic CO2 flux. Our field tests were conducted at Campi Flegrei near Pozzuoli, Southern Italy, where the GasFinder was used during three campaigns in October 2012, January 2013 and May 2013 to repeatedly measure the path-integrated mixing ratios of CO2 along cross-sections of the atmospheric…
Volcanic CO2 measurements at Campi Flegrei by Infrared Tunable Diode Laser absorption Spectroscopy
2014
Gas studies add information for the interpretation of fluid circulation dynamics at dormant volcanoes and can contribute to eruption forecasting. Direct in-situ and remote-sensing techniques were used in order to improve volcanic gas monitoring, essential for hazard assessment. In the last decades, near-infrared diode lasers have increasingly been used in atmospheric research and, though in an experimental phase, are now finding applications in volcanic gas studies. The Tunable Diode Laser Spectroscopy technique (TDLS) relies on measuring the absorbance at specific wavelengths due to the absorption of IR radiation by a target gas. Here, we report on the application of the GasFinder 2.0, an …