Search results for " Carbon Nanotubes"
showing 10 items of 84 documents
Cyclic moisture sorption and its effects on the thermomechanical properties of epoxy and epoxy/MWCNT nanocomposite
2019
The aim of this work was to reveal the moisture absorption&ndash
Electronic and optical properties of carbon nanotubes under pure bending
2010
The high aspect ratio of carbon nanotubes makes them prone to bending. To know how bending affects the tubes is therefore crucial for tube identification and for electrical component design. Very few studies, however, have investigated tubes under small bending well below the buckling limit, because of technical problems due to broken translational symmetry. In this Brief Report a cost-effective and exact modeling of singe-walled nanotubes under such small bending is enabled by revised periodic boundary conditions, combined with density-functional tight-binding. The resulting, bending-induced changes in electronic and optical properties fall in clear chirality-dependent trend families. Whil…
Morphology and structure of electrospun CoFe2O4/multi-wall carbon nanotubes composite nanofibers
2010
CoFe2O4/multiwall carbon nanotubes (MWCNTs) composite nanofibers were produced by electrospinning a dispersion of MWCNTs in a solution of polyvinylpyrrolidone, iron(III) nitrate nonahydrate, cobalt (II) acetate tetrahydrate, absolute ethanol and H2O. Microstructure was examined by scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HR-TEM). Thermal behaviour was studied by thermogravimetry and differential thermal analysis (TG-DTA) and phase analysis of calcined fibers was performed by X-ray diffraction (XRD). Upon thermal treatment at 450 °C defect-free, randomly oriented composite fibers having a mean diameter of 60 ± 10 nm were obtained. The results s…
Rheological Percolation Threshold in High-Viscosity Polymer/CNTs Nanocomposites
2017
AbstractPolystyrene (PS)/multi-walled carbon nanotubes (CNT) nanocomposites have been prepared through melt mixing processing aiming at obtaining a uniform and homogeneous dispersion of the used nanoparticles within the polymeric matrix. Optical and scanning electron microscopy has been employed to determine the dispersion and distribution of CNTs at different length scales. Furthermore, the linear viscoelastic behavior of formulated nanocomposites has been deeply investigated. As a result of CNTs added, the nanocomposites experience a transition from liquid-like to solid-like rheological behavior, and a disappearance of relaxation processes at low frequency can be noticed. By plotting G’ v…
Carbon nanotubes and organic solar cells
2012
The use of carbon nanotubes in photovoltaics is still challenging due to different issues connected to their synthesis, purification, functionalization, processing and device integration. From this perspective at first we review on selected contributions dealing with the above issues; then we focus on the advantages and limitations of carbon nanotubes for the development of organic solar cells.
Electromechanical Behavior of Single and Multiwall Carbon Nanotubes
2008
Carbon nanotubes (CNTs) can be metallic or semiconductors depending simply on geometric characteristics. This peculiar electronic behavior, combined with high mechanical strength, make them potential building blocks of a new nano-electronic technology. High resolution images of CNTs often disclose structural deformations such as bent, twisted, or collapsed tubes. These deformations break the tube symmetry, and a change in their electronic properties should result. A computationally effective mixed finite element-tight-binding approach able to simulate the electromechanical behavior of single and multiwall nanotubes used in nano-electronic devices is presented. The finite element (FE) comput…
Strong enhancement of the Breit-Wigner-Fano Raman line in carbon nanotube bundles caused by plasmon band formation
2002
We investigate the origin of the Breit-Wigner-Fano line in the Raman spectra of individual single-walled carbon nanotubes and their bundles. Using confocal Raman microscopy and atomic-force microscopy we found that the Breit-Wigner-Fano line intensity increases strongly with the bundle thickness. We confirmed this result by Raman investigations of partially decomposed bundles, which were additionally investigated by transmission electron microscopy. Our random-phase approximation based theory, which identifies the Breit-Wigner-Fano line as an excited band of plasmon-phonon modes, is fully consistent with the experimental results.
Combination of Confocal Raman Spectroscopy and Electron Microscopy on the Same Individual Bundles of Single-Walled Carbon Nanotubes
2002
We report a method to investigate the same individual single-walled carbon nanotube (SWNT) bundles with both transmission electron microscopy (TEM) and Raman spectroscopy. Free-standing individual bundles are obtained by depositing a solution of suspend SWNTs on a carbon film with a regular pattern of holes, which can be localized by TEM and also by confocal Raman microscopy. While most of the TEM images predict that the bundles consist of tubes with a similar diameter, we will show that occasionally a certain tube diameter can be associated with a particular radial breathing mode frequency of the Raman spectrum. Single-walled carbon nanotubes (SWNTs) are one-dimensional molecular structure…
Improved method of manufacturing carbon nanotube infused multifunctional 3D woven composites
2021
This research work aimed to develop smart multifunctional composites via a process for uniformly dispersing carbon nanotubes (CNT) on an orthogonal three-dimensional (3D) woven glass fabric with minimised filtering effect. These smart composites could detect strain under tensile and flexural loading by the piezoresistive response of the infused CNT network. Conventional vacuum assisted resin transfer moulding was modified to control the infusion of 0.25 wt% CNT on the 3D woven glass fabric by varying the vacuum pressure. Results showed that at 101.3 kPa vacuum pressure, the CNT percolated through the thickness of the orthogonal 3D woven glass fabric while being marginally filtered by the f…
Measurements of the transport gap in semiconducting multiwalled carbon nanotubes with varying diameter and length
2015
Low temperature transport in multiwalled carbon nanotubes (MWNTs) has been studied at different diameters and lengths, within 2–10 nm, and 0.3–3.5μm, respectively. In a majority of the samples, semiconductivity showed up as a transport gap in the gate voltage controlled conduction, but metallic MWNTs are found in all diameters. The transport gap is seen to be quantitatively determined by a diameter dependent band gap, and length dependent localization of charge carriers. The band gap of semiconducting MWNTs is estimated to be smaller than that extrapolated from the conventional expression applicable to semiconducting single wall carbon nanotubes. The results constitute a systematical study …