Search results for " Formation"
showing 10 items of 1920 documents
Diastereoselective Synthesis of Dialkylated Bis(phosphino)ferrocenes: Their Use in Promoting Silver-Mediated Nucleophilic Fluorination of Chloroquino…
2017
International audience; The diastereoselective synthesis of dialkylated ferrocenyl bis(phosphane)s bearing aryl, alkyl, and hetero- or polycyclic substituents on the phosphino groups is reported, together with their characterization in the solid state by X-ray structure analysis and in solution by multinuclear NMR spectroscopy. Introduction of various alkyl groups on the ferrocene backbone, namely, tert-butyl, isopropyl, and trimethylsilyl, has a significant influence on the stereoselectivity of the ensuing lithiation/phosphination reactions. Only the introduction of the tert-butyl groups ensures both a high yield and perfect diastereoselectivity, which leads to the exclusive formation of t…
Analyse didactique clinique des pratiques d'enseignement et de formation: Les effets du déjà-là expérientiel sportif
2016
Cette note de synthèse s'inscrit dans la suite de mes travaux sur les filtres de l'action didactique qui questionnent le " déjà-là " des sujets. Dans le " déjà-là expérientiel ", je m'intéresse ici aux expériences corporelles importantes des sportifs et plus particulièrement à celles vécues par les professeurs d'EPS. M'appuyant à la fois sur les trois temps de la didactique clinique (le déjà-là, l'épreuve et l'après-coup) et sur une introspection, je montre combien ces expériences sportives liées à la spécialité chez les enseignants d'EPS, expériences souvent traduites en épreuves, laissent des traces profondes qui viennent structurer le rapport au corps, le rapport à soi et aux autres de c…
L'utilisation du cadre de la didactique clinique afin d'expliquer les raisons soutenant les choix des contenus d'apprentissage par les enseignants d'…
2017
International audience
Thermodynamic approach of supercontinuum generation
2009
International audience; This paper is aimed at providing an overview on recent theoretical and experimental works in which a thermodynamic description of the incoherent regime of supercontinuum generation has been formulated. On the basis of the wave turbulence theory, we show that this highly nonlinear and quasi-continuous-wave regime of supercontinuum generation is characterized by two different phenomena. (i) A process of optical wave thermalization ruled by the four-wave mixing effects: The spectral broadening inherent to supercontinuum generation is shown to result from the natural tendency of the optical field to reach its thermodynamic equilibrium state, i. e., the state of maximum n…
Focal plane array infrared camera transfer function calculation and image restoration
2004
Infrared images often present distortions induced by the measurement system. Image processing is thus an essential part of infrared measurements. A distortion model based on a convolution product is presented. The analytical form of the convolution kernel has been obtained from an image formation theory, along with an analysis of the sampling of the focal plane array camera detector's matrix. Image restoration is an ill-posed problem, and its solution can be obtained using regularization methods. In this work, image restoration is performed using a variation of Tikhonov regularization that makes use of the particular form of the convolution kernel matrix, which is built as a block-circulant…
Study of spatial lateral resolution in off-axis digital holographic microscopy
2015
The lateral resolution in digital holographic microscopy (DHM) has been widely studied in terms of both recording and reconstruction parameters. Although it is understood that once the digital hologram is recorded the physical resolution is fixed according to the diffraction theory and the pixel density, still some researches link the resolution of the reconstructed wavefield with the recording distance as well as with the zero-padding technique. Aiming to help avoiding these misconceptions, in this paper we analyze the lateral resolution of DHM through the variation of those two parameters. To support our outcomes, we have designed numerical simulations and experimental verifications. Both…
Experimental demonstration of hyperbolic patterns.
2008
We give experimental evidence of hyperbolic patterns in a nonlinear optical resonator. Such transverse patterns are a new kind of 2D dissipative structures, characterized by a distribution of the active modes along hyperbolas in the transverse wave-vector domain, in contrast with the usual (elliptic) patterns where the active modes distribute along rings. The hyperbolic character is realized by manipulating diffraction inside the optical resonator with cylindrical lenses. We also investigate theoretically hyperbolic patterns in corresponding Swift-Hohenberg models.
Dark spatial solitary waves in a cubic-quintic-septimal nonlinear medium
2017
We consider the evolution of light beams in nonlinear media exhibiting nonlinearities up to the seventh order wherein the beam propagation is governed by the cubic-quintic-septimal nonlinear Schr\"odinger equation. An exact analytic solution that describes dark solitary wave propagation is obtained, based on a special ansatz. Unlike the well-known $\text{tanh}$-profile dark soliton in Kerr media, the present one has a functional form given in terms of ``${\text{sech}}^{2/3}$''. The requirements concerning the optical material parameters for the existence of this localized structure are discussed. This propagating solitary wave exists due to a balance among diffraction, cubic, quintic, and s…
Diffusion stabilizes cavity solitons in bidirectional lasers
2009
We study the influence of field diffusion on the spatial localized structures (cavity solitons) recently predicted in bidirectional lasers. We find twofold positive role of the diffusion: 1) it increases the stability range of the individual (isolated) solitons; 2) it reduces the long-range interaction between the cavity solitons. Latter allows the independent manipulation (writing and erasing) of individual cavity solitons.
Pattern formation in clouds via Turing instabilities
2020
Pattern formation in clouds is a well-known feature, which can be observed almost every day. However, the guiding processes for structure formation are mostly unknown, and also theoretical investigations of cloud patterns are quite rare. From many scientific disciplines the occurrence of patterns in non-equilibrium systems due to Turing instabilities is known, i.e. unstable modes grow and form spatial structures. In this study we investigate a generic cloud model for the possibility of Turing instabilities. For this purpose, the model is extended by diffusion terms. We can show that for some cloud models, i.e special cases of the generic model, no Turing instabilities are possible. However,…