Search results for " Fourier Transform"

FTIR approaches for diuron determination in commercial pesticide formulations.

2005

Two strategies have been developed for Diuron determination by FTIR spectrometry, an off-line extraction and stopped-flow determination and a fully mechanized procedure, based on the on-line extraction of Diuron and FIA-FTIR measurement of the extracts. The aforementioned procedures have been compared with a reference chromatographic method. The off-line FTIR spectra were obtained at a nominal resolution of 4 cm(-1) from 4000 to 900 cm(-1) by accumulating 25 scans. Diuron was determined using peak height measurements at 1582 cm(-1) corrected using a baseline defined between 1562 and 1614 cm(-1). The waste generation of the off-line procedure was 3.4 mL chloroform for each sample, and the me…

Chemical and spectroscopic characteristics of the wood of Vitis vinifera cv. Sangiovese affected by esca disease.

2009

Chemical and spectroscopic analyses ((13)C cross-polarization-magic angle spinning NMR and attenuated total reflection Fourier transform infrared spectroscopies) were carried out on the wood of Vitis vinifera cv. Sangiovese with brown-red discoloration and black streaks caused by esca disease. The analyses of the brown-red wood revealed the destruction of hemicelluloses and noncrystalline cellulose as well as modifications in the pectic and ligninic wood fractions. The pectic fraction consisted of carbohydrates associated with polyphenols. The lignin fraction exhibited only a few changes in the aromatic systems and a partial demethylation, and it appeared to be associated with condensed phe…

The influence of the propagation path length on the results of the time–frequency analysis of the acoustic emission generated by partial discharges i…

2006

The paper presents the measurement results of the acoustic emission (AE) signals generated by partial discharges (PDs) at various thickness of the oil insulation layer. For the AE signals registered the time - frequency analysis was carried out based on the use of the short-time Fourier transform (STFT). Two- and three-dimensional spectrograms of the power spectrum density and the amplitude spectrum were determined. The evaluation of the influence of the propagation path length of the AE signal on the results of the time - frequency analysis was performed through the analysis of the spectrograms determined.

DSP Implementation for Measuring the Loop Gain Frequency Response of Digitally Controlled Power Converters

2012

This paper presents a method for measuring the loop gain frequency response of digitally controlled power converters, without the need of any expensive measurement equipment such as frequency response analyzers (FRA). The method is based on the traditional perturbation and measurement scheme. The perturbation is internally synthesized by the DSP and applied as pulse-width modulation to the converter. The loop input and output data are sent to a PC via universal serial bus, which performs online the DFT of sent data. The perturbation amplitude is varied with frequency to improve signal-to-noise ratio of measurements. The number of cycles used to perform discrete Fourier transform calculation…

Flexible optical implementation of fractional Fourier transform processors. Applications to correlation and filtering

1997

Abstract Recently, in the field of fractional Fourier transforms (FRT) an operation coined “fractional correlation” has been proposed and investigated experimentally. In this paper we propose a new setup for obtaining the fractional correlation, which presents several advantages from the experimental point of view. The fractional filter plane can be adjusted accurately with the help of converging beam illumination and using an adjusting device consisting of a combination of Fresnel zone plates. Moreover the scaling factor between the input pattern and the filter can be adjusted at will. This degree of freedom is of special interest when using SLMs. In addition we present a configuration, ba…

Suppression law of quantum states in a 3D photonic fast Fourier transform chip

2015

The identification of phenomena able to pinpoint quantum interference is attracting large interest. Indeed, a generalization of the Hong–Ou–Mandel effect valid for any number of photons and optical modes would represent an important leap ahead both from a fundamental perspective and for practical applications, such as certification of photonic quantum devices, whose computational speedup is expected to depend critically on multi-particle interference. Quantum distinctive features have been predicted for many particles injected into multimode interferometers implementing the Fourier transform over the optical modes. Here we develop a scalable approach for the implementation of the fast Fouri…

Diversity of yeast strains of the genus Hanseniaspora in the winery environment: What is their involvement in grape must fermentation?

2015

Isolated yeast populations of Chardonnay grape must during spontaneous fermentation were compared to those isolated on grape berries and in a winery environment before the arrival of the harvest (air, floor, winery equipment) and in the air through time. Two genera of yeast, Hanseniaspora and Saccharomyces, were isolated in grape must and in the winery environment before the arrival of the harvest but not on grape berries. The genus Hanseniaspora represented 27% of isolates in the must and 35% of isolates in the winery environment. The isolates of these two species were discriminated at the strain level by Fourier transform infrared spectroscopy. The diversity of these strains observed in t…

Fractional Fourier Transforms and Geometrical Optics

2010

Assessment of temperature effects on beta-aggregation of native and glycated albumin by FTIR spectroscopy and PAGE: relations between structural chan…

2007

Abstract Structural modifications of bovine serum albumin (BSA) induced by heating, and the involvement of glycation of albumin in such processing were studied by using Fourier transform infrared spectroscopy (FTIR) and polyacrylamide gel electrophoresis (PAGE). For native BSA, heating treatments gave rise to β structures which were amplified to the detriment of α-helix form, and which were associated with increased aggregation. A very high correlation was obtained between FTIR Amide I band evolution and aggregation rate parameters, showing the contribution of β-form in aggregates formation. We further assessed the effect of glycation on protein sensibility to heating treatments. A reductio…

Thermal aggregation of glycated bovine serum albumin

2010

International audience; Aggregation and glycation processes in proteins have a particular interest in medicine fields and in food technology. Serum albumins are model proteins which are able to self-assembly in aggregates and also sensitive to a non-enzymatic glycation in cases of diabetes. In this work, we firstly reported a study on the glycation and oxidation effects on the structure of bovine serum albumin (BSA). The experimental approach is based on the study of conformational changes of BSA at secondary and tertiary structures by FTIR absorption and fluorescence spectroscopy, respectively. Secondly, we analysed the thermal aggregation process on BSA glycated with different glucose con…