Search results for " Isolation"
showing 10 items of 374 documents
Matrix Isolation and Ab Initio Study of Trans−Trans and Trans−Cis Dimers of Formic Acid
2010
Six trans-trans and five trans-cis dimeric structures of formic acid (HCOOH) are revealed by ab initio calculations. Four trans-trans and two trans-cis dimers are identified in the IR absorption spectra in argon matrices. The trans-cis dimers are obtained by narrow-band IR excitation of the vibrational transitions of the trans-trans dimers. Two trans-trans (tt3 and tt6) and one trans-cis (tc4) dimer are characterized experimentally for the first time. The tunneling decay rates of two trans-cis dimers (tc1 and tc4) are evaluated at different temperatures. A greater lifetime of the trans-cis dimers at elevated temperatures compared to the cis-monomer suggests that the high-energy conformers c…
Complexes of Glycolic Acid with Nitrogen Isolated in Argon Matrices. II. Vibrational Overtone Excitations
2019
Structural changes of glycolic acid (GA) complex with nitrogen induced by selective overtone excitation of the &nu
Quality of life following third molar removal under conscious sedation
2012
Aim: The aim of this study was to assess quality of life (QoL) and degree of satisfaction among outpatients subjected to surgical extraction of all four third molars under conscious sedation. A second objective was to describe the evolution of self-reported pain measured in a visual analogue scale (VAS) in the 7 days after extraction. Study design: Fifty patients received a questionnaire assessing social isolation, working isolation, eating and speaking ability, diet modifications, sleep impairment, changes in physical appearance, discomfort at suture removal and overall satisfaction at days 4 and 7 after surgery. Pain was recorded by patients on a 100-mm pain visual analogue scale (VAS) ev…
On the FCNS⇆FC(NS) reaction: A matrix isolation and theoretical study
2015
Abstract The FCNS ⇆ FC(NS) photoisomerization process is a simple model system for molecular switches. Here, we examined the switching processes by experimental and theoretical methods. Prior matrix-isolation IR spectroscopic studies were complemented by matrix-isolation UV spectroscopic measurements to assist the interpretation of the mechanism of the ring closure and opening processes and to verify the accuracy of the computations on the vertical excitation energies. Vertical excitation energies were computed by the EOMEE-CCSD, MCSCF, and MR-CISD methods. Conical intersections were also searched for and three conical intersections along the reaction path FCNS → FC(NS) were located, one co…
Contextual factors predicting compliance behavior during the COVID-19 pandemic: A machine learning analysis on survey data from 16 countries.
2022
Voluntary isolation is one of the most effective methods for individuals to help prevent the transmission of diseases such as COVID-19. Understanding why people leave their homes when advised not to do so and identifying what contextual factors predict this non-compliant behavior is essential for policymakers and public health officials. To provide insight on these factors, we collected data from 42,169 individuals across 16 countries. Participants responded to items inquiring about their socio-cultural environment, such as the adherence of fellow citizens, as well as their mental states, such as their level of loneliness and boredom. We trained random forest models to predict whether someo…
Multivariate SPC of a sequencing batch reactor for wastewater treatment
2007
Data from a sequencing batch reactor (SBR) operated for enhanced biological phosphorus removal from wastewater have been analysed in order to propose an efficient MSPC scheme of the process. Different multivariate bilinear approaches have been applied and compared in terms of their capabilities for on-line and off-line fault detection and diagnosis. The typical three-way data structure from a batch process was unfolded batch-wise and variable-wise. In the latter case, two models were built: with (AT) and without (WKFH) removing the main non-linear behaviour of the process data. Since the process consists of several stages, the monitoring strategies tested include: one model for all stages a…
Post-weaning social isolation rearing influences the expression of molecules related to inhibitory neurotransmission and structural plasticity in the…
2012
Several lines of evidence indicate that alterations in the structure of neural circuits and inhibitory neurotransmission underlie the physiopathogenesis of schizophrenia. Most of the studies on these parameters have been focused on cortical regions and, despite the crucial role of the amygdala in this psychiatric disorder, there is less information on this region. In order to expand this knowledge, we have studied the expression of molecules related to inhibitory neurotransmission and structural plasticity in rats subjected to post-weaning isolation rearing, an animal model that reproduces several core symptoms of schizophrenia. We have analyzed, using qRT-PCR and immunohistochemistry, the …
Comparative study on enzymatic activity and molecules stability of some commercial proteolytic enzymes used in pancreatic islet isolation.
2009
In pancreatic islets purification, for cell therapy applications, the major enzymes used are obtained from Clostridium hystoliticum; class I and class II collagenases (COLL G and COLL H). They are used in a defined tissue dissociation enzyme (TDE) mixtures together neutral protease (Dispase) or thermolysin (Thermostable Neutral Protease). The TDE mixtures were in part responsible for the success of the Edmonton protocol; however, just to now, people working in islets purification found discrepancy in an application to another one. This variability in application see in the enzymatic blend composition the higher accused, such as the contamination from endotoxines due to extractive production…
Nontraditional configuration of tuned liquid column damper inerter for base-isolated structures
2023
In this paper, the concept of a novel passive control device, namely the Nontraditional Tuned Liquid Column Damper Inerter (NT-TLCDI), is investigated in combination with seismic base isolation (BI), to control lateral displacement demands in base-isolated structures during seismic events. The considered NT-TLCDI is a revision of the ordinary configuration of the recently proposed Tuned Liquid Column Damper Inerter (TLCDI). Unlike the traditional TLCDI layout, which involves a secondary liquid mass in a U-shaped tank coupled with a grounded inerter and connected to the isolation system by a spring-dashpot system, in the NT-TLCDI configuration, the damper is in parallel with the inerter rath…
Sample pretreatment techniques for oligopeptide analysis from natural sources
2008
The analysis of oligopeptides in samples of food, tissues, and body fluids attracts considerable attention. The complexity of such samples requires efficient sample preparation (i.e., concentration and cleanup) procedures to remove interfering endogenous compounds and inorganic or organic salts. The methods of sample pretreatment that enable effective and selective isolation and/or preconcentration of oligopeptides from complex sample matrices have been reviewed. In each case, examples of application were presented and discussed, taking into account selectivity, enrichment, method automation, cleanup, and environmental aspects of the developed methods.