Search results for " Neutron scattering"
showing 10 items of 205 documents
Raman Scattering Applied to Materials Science
2015
Abstract One of the most powerful techniques to extract physical and chemical information of a material is the light scattering. Opposite to x-ray scattering for instance, where an average of the sample properties is obtained, Raman scattering is a local probe which can be used to detect inhomogeneities, local strain, lack of crystallinity, anharmonicities or information on the electronic structure by means of resonant Raman scattering. In this work, we will analyze the main contributions of Raman scattering in Materials Sciences. After a brief introduction of the technique and the equipment needed for the physical measurements, we will give practical examples of Raman scattering measuremen…
Kinetic evidence for the solubilization of pyridine-2-azo-p-dimethylaniline in alkanediyl-α,ω-bis(dimethylcetylammonium nitrate) surfactants. Role of…
2004
The incorporation of the bidentate ligand pyridine-2-azo-p-dimethylaniline (PADA) into micellar aggregates of the dimeric cationic surfactants propanediyl-, hexanediyl- and dodecanediyl-alpha,omega-bis(dimethylcetylammonium nitrate) (16-3-16,2NO(3)(-), 16-6-16,2NO(3)(-) and 16-12-16,2NO(3)(-), respectively) has been studied at 25 degreesC by examining the kinetics of the complexation reaction of the Ni(II) ion with this ligand. For comparison, cetyltrimethylammonium nitrate ( CTAN), which can be considered as the "monomeric'' surfactant of 16-3-16,2NO(3)(-), has also been used. The kinetic data have shown that, for 16-3-16,2NO(3)(-) and CTAN, at a surfactant concentration below the critical…
Inelastic neutron scattering measurements on Nd2Fe14B and Y2Fe14B single crystals
1992
Abstract Inelastic neutron scattering measurements have been carried out on Nd 2 Fe 14 B and Y 2 Fe 14 B single crystals. Temperature dependent acoustic magnon dispersion curves have been found along the high-symmetry directions [0,0,1] and [1,0,0] with a gap at (0,0,2). Soft mode behaviour at spin wave vector q = 0 was observed for Nd 2 Fe 14 B near the spin reorientation temperature. The inelastic scattering intensity decreases steeply for larger q . Therefore, the dispersion curves could be measured until the middle of the Brillouin zone only. The experimental results are discussed in the frame of a classical spin wave model.
Protein and solvent dynamics of the water-soluble chlorophyll-binding protein (WSCP)
2015
This study presents quasielastic neutron scattering data of the water-soluble chlorophyll-binding protein (WSCP) and the corresponding buffer solution at room temperature. The contributions of protein and buffer solution to the overall scattering are carefully separated. Otherwise, the fast water dynamics dominating the buffer contribution is likely to mask the slow protein dynamics. In the case of WSCP, the protein scattering can be described by two contributions: i) internal protein dynamics represented by a diffusion in a sphere with an average radius of 2.7 u A and ii) global (Brownian) diffusion of the WSCP macromolecule with an upper limit for the translational diffusion coefficient o…
Transport of Mobile Particles in an Immobile Environment: Computer Simulations of Sodium Silicates
2007
Molecular dynamics (MD) simulations of various sodium silicate melts, (Na2O)x(SiO2) with x=2, 3, 20, are presented. In these systems, the mobility of sodium ions is much higher, often by orders of magnitude, than that of the silicon and oxygen atoms forming a tetrahedral network structure. We show that the high mobility of sodium is intimately related to the chemical ordering in sodium silicates. A network of percolating sodium-rich channels is formed in the static structure that serve as diffusion channels for the sodium ions. This channel network is revealed in static structure factors by a prepeak at the wavenumber q=0.95 A-1. Inelastic neutron scattering experiments of sodium silicate m…
Surface Self-Diffusion and Mean Displacement of Hydrogen on Graphite and a PEM Fuel Cell Catalyst Support
2009
International audience; Quasielastic neutron scattering (QENS) measurements together with equilibrium molecular dynamic (EMD) simulations have been performed to investigate the surface interaction between hydrogen molecules and a carbon material commonly used in polymer electrolyte membrane fuel cells (PEMFC), called XC-72. Half a monolayer of molecular hydrogen was adsorbed on to the carbon material at 2 K. QENS spectra were recorded at the time-of-flight spectrometer IN5 at 40, 45, 50, 60, 70, 80, and 90 K. Simultaneously the pressure was measured as a function of time to monitor the equilibrium surface coverage at each temperature. By using the Chudley and Elliott model for jump diffusio…
Ferroelastic transition in Kbr:Kcn studied by neutrons, x-rays and ultrasonic
1986
The ferroelastic phase transition of (KBr) 0 27 (KNC) 0.73 has been studied by X-ray diffraction, ultrasonics and inelastic neutron scattering. It is the first example of a cubic crystal where the elastic shear constant C 44 softens completely corresponding to the m = 2 universality class. C 44 and the Bragg intensities show a non-classical critical behaviour.
A Switchable Molecular Rotator: Neutron Spectroscopy Study on a Polymeric Spin-Crossover Compound
2012
A quasielastic neutron scattering and solid-state 2H NMR spectroscopy study of the polymeric spin-crossover compound {Fe(pyrazine)[Pt(CN) 4]} shows that the switching of the rotation of a molecular fragment-the pyrazine ligand-occurs in association with the change of spin state. The rotation switching was examined on a wide time scale (10 -13-10 -3 s) by both techniques, which clearly demonstrated the combination between molecular rotation and spin-crossover transition under external stimuli (temperature and chemical). The pyrazine rings are seen to perform a 4-fold jump motion about the coordinating nitrogen axis in the high-spin state. In the low-spin state, however, the motion is suppres…
Combined SANS and SAXS experiments in polyolefins-hydrogenated oligocyclopentadiene (HOCP) blends
1998
Abstract Lamellar morphology in semicrystyalline polymer blends (iPP/HOCP and HDPE/HOCP) is investigated by means of Small Angle X-ray Scattering (SAXS) and Small Angle Neutron Scattering (SANS). The investigated blends present a complex phase diagram, as they show a miscibility gap. SAXS scattering curves of blends lying outside the miscibility gap can be analysed in the frame of the psuedo two phase model. In order to describe the complex morphology of blends lying inside the miscibility gap, the SANS technique revealed necessary. In this paper a novel method to describe the morphology of these complex systems by means of SANS is presented.
Scattering studies of large scale structures at the ultra small angle neutron scattering instrument S18
2002
Abstract In recent years ultra small angle neutron scattering (USANS) has developed into a powerful standard method for large scale structure investigations. The upgraded instrument S18 at the ILL's 58 MW high flux reactor is operated routinely with increasing beam time demand. The performance of the instrument and its abilities will be discussed in this paper. A peak to background ratio better than 10 5 is reached using Agamalian's tail reduction method. A q -range from 2.10 −5 up to 5.10 −2 A −1 can be covered. This allows a clear overlap with standard pinhole SANS instruments. The new way collecting scattering data logarithmically equidistant in q -space saves measuring time. This allows…