Search results for " Optics"
showing 10 items of 5880 documents
Immuno-MALDI-MS in Human Plasma and on-Chip Biomarker Characterizations at the Femtomole Level
2012
Immuno-SPR-MS is the combination of immuno-sensors in biochip format with mass spectrometry. This association of instrumentation allows the detection and the quantification of proteins of interest by SPR and their molecular characterization by additional MS analysis. However, two major bottlenecks must be overcome for a wide diffusion of the SPR-MS analytical platform: (i) To warrant all the potentialities of MS, an enzymatic digestion step must be developed taking into account the spot formats on the biochip and (ii) the biological relevancy of such an analytical solution requires that biosensing must be performed in complex media. In this study, we developed a procedure for the detection …
Spectral dynamics of incoherent waves with a noninstantaneous nonlinear response
2013
We study the influence of a constant background noise on the dynamics of spectral incoherent solitons, which are incoherent structures sustained by a noninstantaneous (Raman-like) nonlinearity. As the level of the noise background increases, the incoherent wave enters a novel nonlinear regime characterized by oscillatory dynamics of the incoherent spectrum, which develop within a spectral cone during the propagation. In contrast to the conventional Raman-like spectral red shift, such incoherent spectral dynamics can be characterized by a significant spectral blue shift. On the basis of the kinetic wave theory, we derive explicit analytical expressions of these incoherent oscillatory spectra…
PCB-Based Planar Inductive Loops for Partial Discharges Detection in Power Cables
2022
Partial discharge (PD) diagnosis tests, including detecting, locating, and identifying, are used to trace defects or faults and assess the degree of aging in order to monitor the insulation condition of medium- and high-voltage power cables. In this context, an experimental evaluation of three different printed circuit board (PCB)-based inductive sensor topologies, with spiral, non-spiral, and meander shapes, is performed. The aim is to assess their capabilities for PD detection along a transmission power cable. First, simulation and experimental characterization are carried out to determine the equivalent electrical circuit and the quality factor of the three sensors. PD activity was studi…
Characterization of high-temperature performance of cesium vapor cells with anti-relaxation coating
2017
© 2017 Author(s). Vapor cells with antirelaxation coating are widely used in modern atomic physics experiments due to the coating's ability to maintain the atoms' spin polarization during wall collisions. We characterize the performance of vapor cells with different coating materials by measuring longitudinal spin relaxation and vapor density at temperatures up to 95 °C. We infer that the spin-projection-noise-limited sensitivity for atomic magnetometers with such cells improves with temperature, which demonstrates the potential of antirelaxation coated cells in applications of future high-sensitivity magnetometers.
Catalytic Activity of Char Obtained from Fast Pyrolysis in Esterification Reactions
2021
In this study different pathways for obtaining activated carbon with catalytical activity were analysed. Industrially fast pyrolysis is an efficient way of lignocellulosic biomass processing, since in this process various important high value chemicals are obtained. Biochar is obtained as the by-product in fast pyrolysis process from which activated carbon can be acquired with further chemical activation. Different methods for chemical activation of biochar were tested with the obtained activated charcoals being used as a catalyst in esterification reactions to evaluate their potential use as a heterogenic catalyst. Highest catalytical activity was observed when biochar was pre-treated with…
Thermal Properties, Raman Spectroscopy and Tem Images of Neutron-Bombarded Graphite
2013
Neutron-irradiated graphite to a total dose of 3.6 × 1016 n cm−2 was studied by DSC, Raman spectroscopy and transmission electron microscopy (TEM). The Wigner energy of neutron-irradiated graphite was 9.5 J/g as measured by DSC; it was released with an exothermal peak at 220°C. The Raman spectroscopy has confirmed the expected effect caused by neutron irradiation of the graphite substrate. The TEM imaging has shown that neutron-irradiated graphite can be effectively exfoliated by sonication in comparison to pristine graphite, which under similar conditions does not exfoliate at all. The interstitial Frenkel defects in neutron-irradiated graphite are intercalated between the graphene layers …
Formation and characterization of oxidic and metallic Fe/Ni multilayers prepared from Langmuir-Blodgett films
1994
Oxidic and metallic iron, nickel, and mixed iron/nickel mono- and multilayers were prepared by some treatments of iron- and nickel-containing Langmuir-Blodgett films. The layers were characterized by several surface-sensitive methods. Interactions between the iron and the nickel could be observed. The results are different to those obtained from disordered bulk alloys and from simple diffusion calculations.
Investigation of the dynamics of bacteriorhodopsin
1990
Bacteriorhodopsin (bR) converted to the blue form by deionization has been reconstituted to the active purple membrane by addition of57Fe ions. Mossbauer spectra measured in a wide temperature range reveal Fe3+ binding places with oxygen atoms in the neighbourhood. No evidence for a well defined functional binding place of the iron has been found. On a timescale faster 100 ns the purple membrane shows increasing flexibility above 200 K. In order to analyse the influence of the lipids, a bacteriorhodopsin sample where the lipid content has been increased artificially by the incorporation of DMPC as well as a sample consisting of lipid bilayer have been investigated.
Mössbauer and TEM studies of the perovskite system (1-y)La2/3 $$A$$ 1/3TiO3·yLaFeO3
1994
The microscopic nature of the Mossbauer phase analysis has been found as being particularly valuable in testing assumptions suggested by TEM results regarding the microdomain structure and the population of different lattice sites by iron ions in the perovskite system (1-y)La2/3\(A\)1/3TiO3·yLaFeO3 with 0.04<y < 0.25 (\(A\) is an A-site vacancy). This system was found to contain only Fe3+-phases which are stable under normal conditions, but moderate heating in vacuo causes a partial reduction of ferric ions to ferrous ions.
Mössbauer spectroscopy on the reaction center of Rhodopseudomonas viridis
1992
Proteins called “reaction centers” (RC) can be isolated from many photosynthetic bacteria. They have one non-heme iron in a quinone acceptor region. The RC of Rhodopseudomonas viridis contains an additional tightly bound tetra-heme cytochrome c subunit. The electronic configuration of both cytochrome and the non-heme iron has been studied in the crystallized protein by Mossbauer spectroscopy at different redox potentials, pH-values, and with an addition of o-phenanthroline. At high potentials (Eh=+500mV) all heme irons are in the low spin Fe3+-state, and at low potential (Eh=−150mV) they are low spin Fe2+ with the same Mossbauer parameters for all hemes independent of pH. Redox titrations c…