Search results for " PHOSPHATE"

showing 10 items of 293 documents

Enhanced levels of S-linalool by metabolic engineering of the terpenoid pathway in spike lavender leaves

2013

Transgenic Lavandula latifolia plants overexpressing the linalool synthase (LIS) gene from Clarkia breweri, encoding the LIS enzyme that catalyzes the synthesis of linalool were generated. Most of these plants increased significantly their linalool content as compared to controls, especially in the youngest leaves, where a linalool increase up to a 1000% was observed. The phenotype of increased linalool content observed in young leaves was maintained in those T1 progenies that inherit the LIS transgene, although this phenotype was less evident in the flower essential oil. Cross-pollination of transgenic spike lavender plants allowed the generation of double transgenic plants containing the …

LavenderAcyclic MonoterpenesLavandulaTransgeneLavandula latifoliaBioengineeringGenetically modified cropsClarkiaBiologyApplied Microbiology and Biotechnologylaw.inventionchemistry.chemical_compoundLinaloollawBotanyTransgenesHydro-LyasesEssential oilPlant ProteinsPlants Genetically Modifiedbiology.organism_classificationTerpenoidPlant LeavesErythritolLavandulachemistryMonoterpenesSugar PhosphatesBiotechnologyMetabolic Engineering
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Raman spectroscopic study of some lead phosphate glasses with tungsten ions

2006

Abstract The structure of x WO 3  · (100 −  x )[2P 2 O 5  · PbO] glass system with 0 ⩽  x  ⩽ 50 mol% was investigated by Raman spectroscopy. The characteristic bands of these glasses due to the stretching and bending vibrations were identified and analyzed by the increasing of WO 3 content. This fact allowed us to identify the specific structural units which appear in these glasses and thus to point out the network modifier role of tungsten oxide for low concentrations and its former role at high concentrations.

Lead phosphateChemistryInorganic chemistryAnalytical chemistrychemistry.chemical_elementTungstenCondensed Matter PhysicsElectronic Optical and Magnetic MaterialsIonPhosphate glasssymbols.namesakeChemical bondMolecular vibrationMaterials ChemistryCeramics and CompositessymbolsRaman spectroscopyChemical compositionJournal of Non-Crystalline Solids
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Stir bar sorptive-dispersive microextraction for trace determination of triphenyl and diphenyl phosphate in urine of nail polish users

2018

Abstract This work describes a new analytical method useful for monitoring the human exposure to the endocrine-disrupting plasticizer triphenyl phosphate (TPP) via nail polish use. The method allows trace determination of this parent compound and its main metabolite, namely diphenyl phosphate (DPP), in urine samples of nail polish users. The method is based on a novel microextraction technique termed stir bar sorptive-dispersive microextraction (SBSDME) using a magnetic composite made of CoFe2O4 magnetic nanoparticles embedded into a mixed-mode weak anion exchange polymer (Strata™-X-AW), followed by liquid chromatography-tandem mass spectrometry (LC–MS/MS). The main parameters involved in t…

Liquid Phase MicroextractionCosmetics010402 general chemistryMass spectrometry01 natural sciencesBiochemistryAnalytical Chemistrychemistry.chemical_compoundLimit of DetectionTandem Mass SpectrometryHumansDetection limitChromatographyIon exchangeBiphenyl Compounds010401 analytical chemistryOrganic ChemistryExtraction (chemistry)PlasticizerReproducibility of ResultsGeneral MedicineOrganophosphates0104 chemical sciencesNail polishchemistryLinear ModelsMagnetic nanoparticlesChromatography LiquidTriphenyl phosphateJournal of Chromatography A
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Calcium Carbonate and Phosphate Reference Materials for Monitoring Bulk and Microanalytical Determination of Sr Isotopes

2017

In situ laser ablation analyses rely on the microanalytical homogeneity of reference materials (RMs) and a similar matrix and mass fraction between unknown samples and RMs to obtain reliable results. Suitable carbonate and phosphate RMs for determination of Sr isotope ratios in such materials are limited. Thus, we determined Sr-87/Sr-86 ratios of several carbonate (JCt-1, JCp-1, MACS-1, MACS-3) and phosphate (MAPS-4, MAPS-5, NIST SRM 1400, NIST SRM 1486) international RMs using dissolved samples and two different multi-collector inductively coupled plasma-mass spectrometers (MC-ICP-MS). Our Sr isotope data are in agreement with published data and have an improved measurement precision for s…

MACS-1phosphatesMACS-3LA-MC-ICP-MS010502 geochemistry & geophysics01 natural sciencesNIST SRM 1400carbonate and phosphate reference materialsLA-MC-ICP-MS MC-ICP-MS carbonate and phosphate reference materials JCt-1 JCp-1 MACS-1 MACS-3 MAPS-4 MAPS-5 NIST SRM 1400 NIST SRM 1486NIST SRM 1486chemistry.chemical_compoundGeochemistry and Petrologycalcium carbonateMC-ICP-MSreference material0105 earth and related environmental sciencesLaser ablationIsotopeChemistryMc icp ms010401 analytical chemistryGeologyPhosphateIsotopes of strontiumstrontium isotope0104 chemical sciencesMAPS-4Calcium carbonateJCp-1JCt-1laser ablationMAPS-5Nuclear chemistrymulti-collector inductively coupled plasma-mass spectrometer
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a1D-Adrenoceptors are responsible for the high sensitivity and the slow time-course of noradrenaline-mediated contraction in conductance arteries.

2013

The objective of this study was to determine whether the different time-course characteristics of α1-adrenoceptor-mediated contraction in arteries can be related to the subtypes involved. Contractile responses to noradrenaline (NA) were compared with inositol phosphate accumulation and extracellular signal-regulated kinase (ERK)1/2 phosphorylation after α1-agonist stimuli in the same vessels in the presence or absence of α1-antagonists in rat or in α1-subtype knockout (KO) mice. Aorta, where α1D-AR is the main functional subtype, had higher sensitivity to NA (in respect of inositol phosphate [IP], pERK1/2, and contractile response) than tail artery, where the α1A-adrenoceptor subtype is pre…

MAPK/ERK pathwaychemistry.chemical_classificationAgonistmedicine.medical_specialtyAortaContraction (grammar)business.industryKinasemedicine.drug_classcontraction time-courseconductance and resistance vesselsOriginal ArticlesEndocrinologyNeurologychemistryInternal medicinemedicine.arterymedicineExtracellularPhosphorylationGeneral Pharmacology Toxicology and Pharmaceuticsconductance and resistance vessels contraction time-course a1A-adrenoceptorsα1A-adrenoceptorsInositol phosphatebusiness
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Crystal structure and magnetism of Co(HPO3)⋅H2O : A novel layered compound of Co(II)

1990

Under the terms of the Creative Commons Attribution (CC BY) license to their work.-- et al.

Magnetic PropertiesMagnetismGeneral Physics and AstronomyCrystal structureMagnetic Susceptibility:FÍSICA [UNESCO]HydratesMedium TemperatureMagnetic structureChemistryCritical ExponentsUNESCO::FÍSICASpace groupHydrogen BondsMagnetic susceptibilityCobalt Compounds ; Acid Phosphates ; Hydrates ; Layers ; Crystal Structure ; Magnetic Properties ; Lattice Parameters ; Space Groups ; Hydrogen Bonds ; Magnetic Susceptibility ; Magnetic Structure ; Critical Exponents ; Ising Model ; Medium TemperatureCrystallographySpace GroupsIsing ModelOctahedronAcid PhosphatesCrystal StructureLattice ParametersIsing modelMagnetic StructureCobalt CompoundsLayersCritical exponent
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Influence of Dimerization of Apocynin on Its Effects in Experimental Colitis

2017

Apocynin has been widely used as an inhibitor of the nicotinamide adenine dinucleotide phosphate oxidase (NADPH-oxidase) system and shows promise as an anti-inflammatory drug. Diapocynin, the dimeric product generated by the oxidation of apocynin in the presence of myeloperoxidase (MPO), is supposed to be its active form. In this study, diapocynin has been chemically synthesized and its activity on several inflammatory mediators in LPS-stimulated RAW 264.7 macrophages and its anti-inflammatory effect on ulcerative colitis induced by dextran sodium sulfate (DSS) in mice analyzed. We found that diapocynin showed higher inhibitory activity than apocynin. The dimer reduced ROS production, TNF-α…

Male0301 basic medicineDimerInterleukin-1betaPharmacologyInhibitory postsynaptic potentialMice03 medical and health scienceschemistry.chemical_compoundIn vivoAnimalsHumansMice Inbred BALB COxidase testMolecular StructurebiologyInterleukin-6Tumor Necrosis Factor-alphaMacrophagesBiphenyl CompoundsNF-kappa BAcetophenonesGeneral ChemistryColitis030104 developmental biologychemistryDiapocyninBiochemistryCyclooxygenase 2MyeloperoxidaseApocyninbiology.proteinGeneral Agricultural and Biological SciencesDimerizationNicotinamide adenine dinucleotide phosphateJournal of Agricultural and Food Chemistry
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The LepR-mediated leptin transport across brain barriers controls food reward

2018

Objective Leptin is a key hormone in the control of appetite and body weight. Predominantly produced by white adipose tissue, it acts on the brain to inhibit homeostatic feeding and food reward. Leptin has free access to circumventricular organs, such as the median eminence, but entry into other brain centers is restricted by the blood–brain and blood–CSF barriers. So far, it is unknown for which of its central effects leptin has to penetrate brain barriers. In addition, the mechanisms mediating the transport across barriers are unclear although high expression in brain barriers suggests an important role of the leptin receptor (LepR). Methods We selectively deleted LepR in brain endothelia…

Male0301 basic medicineLeptinHFD high-fat dietEndothelial cellsWhite adipose tissueCSF cerebrospinal fluidMice0302 clinical medicineCPP conditioned place preferenceBBB blood–brain barrierCells Culturedmedia_commonLeptindigestive oral and skin physiologyi.p. intraperitonealmedicine.anatomical_structureLepRBlood-Brain BarrierBlood–brain barrier; Endothelial cells; LepR; Leptin; Obesity; RewardMedian eminenceqPCR quantitative polymerase chain reactionReceptors LeptinOriginal ArticleChoroid plexusmedicine.medical_specialtylcsh:Internal medicinemedia_common.quotation_subjectHyperphagiaBiologyBlood–brain barrierVTA ventral tegmental areaBC bottle choice testCapillary PermeabilityBlood–brain barrierARC arcuate nucleus03 medical and health sciencesPBS phosphate buffered salineRewardInternal medicinemedicineAnimalsObesitylcsh:RC31-1245Molecular BiologyCircumventricular organsBlood-Nerve BarrierLeptin receptorNCD normal chow dietAppetiteCell Biology030104 developmental biologyEndocrinologyLepR leptin receptorChoroid PlexusBSA bovine serum albuminPFA paraformaldehyde030217 neurology & neurosurgeryDAPI 4′6-diamidino-2-phenylindoleMolecular Metabolism
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Molecular mechanisms mediating the neuroprotective role of the selective estrogen receptor modulator, bazedoxifene, in acute ischemic stroke: A compa…

2017

As the knowledge on the estrogenic system in the brain grows, the possibilities to modulate it in order to afford further neuroprotection in brain damaging disorders so do it. We have previously demonstrated the ability of the selective estrogen receptor modulator, bazedoxifene (BZA), to reduce experimental ischemic brain damage. The present study has been designed to gain insight into the molecular mechanisms involved in such a neuroprotective action by investigating: 1) stroke-induced apoptotic cell death; 2) expression of estrogen receptors (ER) ERα, ERβ and the G-protein coupled estrogen receptor (GPER); and 3) modulation of MAPK/ ERK1/2 and PI3K/Akt signaling pathways. For comparison, …

Male0301 basic medicineMAPK/ERK pathwayIndolesSignaling pathwaysEndocrinology Diabetes and MetabolismClinical BiochemistryEstrogen receptorApoptosisEstrogen receptorsSecond Messenger SystemsBiochemistryBrain IschemiaReceptors G-Protein-Coupled0302 clinical medicineEndocrinologyPhosphatidylinositol PhosphatesCerebral CortexNeuronsEstradiolNeuroprotectionStrokeNeuroprotective AgentsSelective estrogen receptor modulatorReperfusion InjuryMolecular MedicineSelective estrogen receptor modulatorsGPERmedicine.medical_specialtyMAP Kinase Signaling Systemmedicine.drug_classAcute ischemic strokeNerve Tissue ProteinsBazedoxifeneBiologyNeuroprotection03 medical and health sciencesInternal medicinemedicineAnimalsEstrogen Receptor betaRats WistarMolecular BiologyProtein kinase BPI3K/AKT/mTOR pathwayEstrogen Receptor alphaEstrogensCell BiologyEstrogen030104 developmental biologyEndocrinologyEstrogen030217 neurology & neurosurgeryThe Journal of Steroid Biochemistry and Molecular Biology
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N-acetyl-L-glutamate in brain: assay, levels, and regional and subcellular distribution.

1991

N-Acetyl-L-glutamate (NAG), the activator of mitochondrial carbamoyl phosphate synthetase (CPS), is demonstrated by several methods, including a new HPLC assay, in the brain of mammals and of chicken. The brain levels of NAG are 200-300 times lower than the levels of N-acetyl-L-aspartate (NAA), and are similar to the levels of NAG in rat liver. The NAG levels in chicken liver are very low. Although NAG is mitochondrial in the liver, it is cytosolic in brain. Using enzyme activity and immuno assays we did not detect CPS in brain (detection limit, 12.5 micrograms/g brain), excluding that brain NAG is involved in citrullinogenesis. The regional distribution of brain NAG differs from that of NA…

MaleCentral nervous systemurologic and male genital diseasesBiochemistryCellular and Molecular NeuroscienceMiceGlutamatesSpecies SpecificitymedicineAnimalsChromatography High Pressure Liquidchemistry.chemical_classificationN acetyl L glutamateBrain ChemistryAspartic AcidSheepbiologyurogenital systemActivator (genetics)Rats Inbred StrainsGeneral MedicineCarbamoyl phosphate synthetaseEnzyme assayRatsCytosolSubcellular distributionEnzymemedicine.anatomical_structurechemistryBiochemistrybiology.proteinChickensNeurochemical research
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