Search results for " POLYASPARTAMIDE"

showing 4 items of 14 documents

Mechanical Characterization of Polysaccharide/polyaminoacid Hydrogels as Potential Scaffolds for Tissue Regeneration

2011

The mechanical properties of hydrogel scaffolds based on hyaluronic acid (HA) that were chemically crosslinked with α,β-poly(N-2-hydroxyethyl)(2-aminoethylcarbamate)-D,L-aspartamide (PHEA-EDA) were investigated. Variation of these properties as a function of three different PHEA-EDA amounts used to crosslink HA has been related to the reaction efficiency evaluated using a colorimetric assay. Moreover, the amount of unreacted amino groups that was still present in the hydrogels was related to the attachment behavior of human dermal fibroblasts to the hydrogel surface. The mechanical data and biological results suggest the suitability of the investigated hydrogels as scaffolds for the regener…

chemistry.chemical_classificationMaterials sciencePolymers and PlasticsGeneral Chemical EngineeringRegeneration (biology)Organic Chemistrytechnology industry and agriculturemacromolecular substancesfibroblast attachment; hyaluronic acid; mechanical properties; polyaspartamide; scaffoldsPolysaccharidePolymer engineeringCharacterization (materials science)chemistry.chemical_compoundchemistryhyaluronic acid polyaspartamide scaffolds mechanical properties fibroblast attachment.Settore CHIM/09 - Farmaceutico Tecnologico ApplicativoHyaluronic acidPolymer chemistrySelf-healing hydrogelsMaterials ChemistryBiophysics
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pH-sensitive hydrogel based on a novel photocross-linkable copolymer.

2004

A pH sensitive hydrogel has been prepared by a UV irradiation technique. Starting polymer was the PHM (poly hydroxyethylaspartamide methacrylated) obtained from polyaspartamide (PHEA) partially derivatized with methacrylic anhydride (MA). This new copolymer has been further derivatized with succinic anhydride (SA) to obtain PHM-SA that has been cross-linked by UV irradiation to form a pH sensitive hydrogel. The network, recovered after washing as a powder, has been been characterized by FT-IR spectrophotometry and particle size distribution analysis. Moreover, to have information about water affinity of the prepared sample, swelling measurements have been carried out in aqueous media mimick…

chemistry.chemical_classificationPolymers and PlasticspH sensitive hydrogels polyaspartamide drug releasePolymersSuccinic anhydrideMethacrylic anhydrideChemical modificationBioengineeringHydrogelsPolymerHydrogen-Ion ConcentrationBiomaterialschemistry.chemical_compoundCross-Linking ReagentschemistryDrug deliveryPolymer chemistryMaterials ChemistryCopolymerMicroparticleDrug carrierNuclear chemistryBiomacromolecules
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Preparation of Polymeric Nanoparticles by Photo-Crosslinking of an Acryloylated Polyaspartamide in w/o Microemulsion

2004

Biodegradable polymeric nanoparticles have been prepared by UV irradiation of an acryloylated water soluble polymer by an inverse microemulsion. The starting polymer was a α,β‐poly(N‐2‐hydroxyethyl)‐D,L‐aspartamide (PHEA) partially functionalized with glycidyl methacrylate (GMA) in order to introduce reactive vinyl groups in the side chain. The PHEA‐GMA copolymer obtained (PHG) was crosslinked by UV irradiation of the inverse microemulsion prepared by mixing an aqueous solution of PHG with propylene carbonate (PC)/ethyl acetate (EtOAc) in the presence of sorbitan trioleate (SPAN 85) as surfactant. Nanoparticles obtained were characterized by FTIR spectrophotometry, transmission electron mic…

inverse microemulsionGlycidyl methacrylatePHGAqueous solutionPolymers and PlasticsChemistryOrganic ChemistryNanoparticleCondensed Matter Physicsacryloylated polyaspartamide inverse microemulsion irradiation nanoparticles PHG photo‐crosslinkingphoto-crosslinkingchemistry.chemical_compoundSettore CHIM/09 - Farmaceutico Tecnologico ApplicativoPolymer chemistryMaterials ChemistryZeta potentialSide chainCopolymernanoparticlesMicroemulsionPhysical and Theoretical ChemistryDrug carrieracryloylated polyaspartamideMacromolecular Chemistry and Physics
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Polymeric nanoparticles for siRNA delivery: Production and applications

2017

Gene therapy through the use of siRNA and a polymeric carrier are becoming an efficient therapeutic option to conventional pharmaceutical formulations for the treatment of deadly diseases, such as cancer, pulmonary, ocular and neurodegenerative diseases. However, several considerations regarding the stability, formulation, and efficacy have to be faced up until these systems could be considered to be a marketable pharmaceutical products for to extend siRNA application to clinical practice. This review is focused on the key challenges of siRNA therapeutics, with special attention on the faced obstacles and on the formulation-related difficulties, providing a list of requirements needed for o…

siRNA deliveryPolymersPharmaceutical ScienceNanotechnology02 engineering and technologyPolyethylenimine010402 general chemistry01 natural scienceschemistry.chemical_compoundPolyaminesHumansRNA Small InterferingPolyethylenimineChitosanPolymeric non viral vectorInulinChitosan; Inulin; Polyaspartamide; Polyethylenimine; Polymeric non viral vectors; siRNA delivery.Genetic Therapy021001 nanoscience & nanotechnologyPolymeric nanoparticles0104 chemical sciencesClinical PracticePolyaspartamidechemistrySettore CHIM/09 - Farmaceutico Tecnologico ApplicativoPolymeric non viral vectorsNanoparticles0210 nano-technologyPeptidessiRNA delivery.
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