Search results for " RED"

Functionality transfer from C8 to C9 in sesquiterpenes. Synthesis of the named Herbolide E from artemisin.

1992

Abstract The key intermediate 6 was obtained in five steps from artemisin (1). The spectroscopic characteristics of the synthetic product 7a reveal that the proposed structure for the natural herbolide E must be revised.

Biodegradability Prediction of Fragrant Molecules by Molecular Topology

2016

Biodegradability is a key property in the development of safer fragrances. In this work we present a green methodology for its preliminary assessment. The structure of various fragrant molecules is characterized by computing a large set of topological indices. Those relevant to biodegradability are selected by means of a hybrid stepwise selection method to build a linear classifier. This model is compared with a more complex artificial neural network trained with the indices previously found. After validation, the models show promise for time and cost reduction in the development of new, safer fragrances. The methodology presented could easily be adapted to many quasi-big data problems in R…

A Neural Architecture for 3D Segmentation

2003

An original neural scheme for segmentation of range data is presented, which is part of a more general 3D vision system for robotic applications. The entire process relies on a neural architecture aimed to perform first order image irradiance analysis, that is local estimation of magnitude and orientation of the image irradiance gradient.

Gravitational wave content and stability of uniformly, rotating, triaxial neutron stars in general relativity

2017

Targets for ground-based gravitational wave interferometers include continuous, quasiperiodic sources of gravitational radiation, such as isolated, spinning neutron stars. In this work we perform evolution simulations of uniformly rotating, triaxially deformed stars, the compressible analogues in general relativity of incompressible, Newtonian Jacobi ellipsoids. We investigate their stability and gravitational wave emission. We employ five models, both normal and supramassive, and track their evolution with different grid setups and resolutions, as well as with two different evolution codes. We find that all models are dynamically stable and produce a strain that is approximately one-tenth …

A photometric redshift of z = 1.8$^{\sf{+0.4}}_{\sf{-0.3}}$ for the AGILE GRB 080514B

2008

Aims: The AGILE gamma-ray burst GRB 080514B is the first burst with detected emission above 30 MeV and an optical afterglow. However, no spectroscopic redshift for this burst is known. Methods: We compiled ground-based photometric optical/NIR and millimeter data from several observatories, including the multi-channel imager GROND, as well as ultraviolet \swift UVOT and X-ray XRT observations. The spectral energy distribution of the optical/NIR afterglow shows a sharp drop in the \swift UVOT UV filters that can be utilized for the estimation of a redshift. Results: Fitting the SED from the \swift UVOT $uvw2$ band to the $H$ band, we estimate a photometric redshift of $z=1.8^{+0.4}_{-0.3}$, c…

Deconvolution procedure of the UV-vis spectra. A powerful tool for the estimation of the binding of a model drug to specific solubilisation loci of b…

2015

UV-vis-spectra evolution of Nile Red loaded into Tween 20 micelles with pH and [Tween 20] have been analysed in a non-conventional manner by exploiting the deconvolution method. The number of buried sub-bands has been found to depend on both pH and bio-surfactant concentration, whose positions have been associated to Nile Red confined in aqueous solution and in the three micellar solubilisation sites. For the first time, by using an extended classical two-pseudo-phases-model, the robust treatment of the spectrophotometric data allows the estimation of Nile Red binding constant to the available loci. Hosting capability towards Nile Red is exalted by the pH enhancement. Comparison between bin…

2013

To identify factors limiting performance in multitone intensity discrimination, we presented sequences of five pure tones alternating in level between loud (85 dB SPL) and soft (30, 55, or 80 dB SPL). In the “overall-intensity task”, listeners detected a level increment on all of the five tones. In the “masking task”, the level increment was imposed only on the soft tones, rendering the soft tones targets and loud tones task-irrelevant maskers. Decision weights quantifying the importance of the five tone levels for the decision were estimated using methods of molecular psychophysics. Compatible with previous studies, listeners placed higher weights on the loud tones than on the soft tones i…

REDESIGN OF AN AUTO-LEVELLING BASE FOR SUBMARINE SEISMIC SENSOR

2011

The OBS (acronym of Ocean Bottom Seismometer) is a system to monitor the submarine seismic activity. To properly work, an OBS system needs a suitable auto-levelling base to maintain a fixed (horizontal) position during the measurement phases. In this work a new auto-levelling base for submarine seismic sensors has been designed. During the redesign process a preliminary phase of analysis of the state of art has been made. Afterwards, the technological solutions chosen by different manufactures have been critically analysed, and a full description of their functionalities, working principles and system performances has been carried out. Later, some innovative concepts have been proposed. Amo…

Über Hydroxy‐linolsäuremethylester und die Umsetzung von Linolsäuremethylester mit N‐Bromsuccinimid

1962

Hydroxy-linolsauremethylester wird durch selektive Reduktion von Linolsauremethylester-hydroperoxyd mit Na-Sulfit u. a. dargestellt. Die Autoxydation des Hydroxy-linolsauremethylesters verlauft nicht autokatalytisch und ist nach Aufnahme von 1 Mol Sauerstoff pro Mol Substanz nahezu beendet. Die Reaktionsprodukte sind relative niedermolekular. Die Reaktion von Linolsauremethylester mit N-Bromsuccinimid konnte durch Umsetzung des instabilen Reaktionsproduktes mit Silbernitrat weitgehend aufgeklart werden. About Hydroxy Methyl Linoleate and the Reaction of Methyl Linoleate with N-Bromosuccinimide Hydroxy methyl linoleate is prepared by selective reduction of methyl linoleate hydroperoxyde with…

Factorial structure of recklessness: To what extent are older drivers different?

2003

This study tests whether the original factorial structure of a recklessness questionnaire can be maintained for the current Spanish population of older drivers.Our recent interest in dedicating special attention to senior citizen mobility (Monterde, 2001), is due to the impending increase of the aging population in Western countries; this has led us to reinitiate the psychometric study of the construct validity, revising and including older drivers in the psychometric aspects of those evaluation instruments that will then be used in the Spanish psycho-medical check of drivers and in research.Factorial analysis was used to determine validity.There was an appearance of a different psychologic…