Search results for " Resolution"

showing 10 items of 1159 documents

Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium as Racemization Catalyst in the Dynamic Kinetic Resolution of Secondary Alcohols

2009

Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium has been prepared and its structure confirmed by X-ray analysis. This complex shows excellent catalytic activity and modest stability against air in racemization reactions of secondary alcohols. In Candida antarctica lipase B (CAL-B) catalyzed dynamic kinetic resolution (DKR) of 1-phenyl- and 1-(furan-2-yl)ethanol compounds, the new complex shows improved performance as an alcohol racemization catalyst in comparison with its well-known pentaphenylcyclopentadienyl analogue, hitherto considered as the leading catalyst candidate. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

biologyChemistryOrganic Chemistrychemistry.chemical_elementAlcoholbiology.organism_classificationEnzyme catalysisRutheniumCatalysisKinetic resolutionchemistry.chemical_compoundTransition metalOrganic chemistryCandida antarcticaPhysical and Theoretical ChemistryRacemizationEuropean Journal of Organic Chemistry
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Improved superresolution in coherent optical systems.

2001

Objects that temporally vary slowly can be superresolved by the use of two synchronized moving masks such as pinholes or gratings. This approach to superresolution allows one to exceed Abbe’s limit of resolution. Moreover, under coherent illumination, superresolution requires a certain approximation based on the time averaging of intensity rather than of field distribution. When extensive digital postprocessing can be incorporated into the optical system, a detector array and some postprocessing algorithms can replace the grating that is responsible for information decoding. In this way, no approximation is needed and the synchronization that is necessary when two gratings are used is simpl…

business.industryApertureComputer scienceMaterials Science (miscellaneous)Aperture synthesisPhysics::OpticsGratingSuperresolutionIndustrial and Manufacturing EngineeringSynchronizationsymbols.namesakeOpticssymbolsSpatial frequencyBusiness and International ManagementbusinessImage resolutionDoppler effectDecoding methodsApplied optics
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Optimization of a Time-to-Digital Converter and a coincidence map algorithm for TOF-PET applications

2015

This contribution describes the optimization of a multichannel high resolution Time-to-Digital Converter (TDC) in a Field-Programmable Gate Array (FPGA) initially capable of obtaining time resolutions below 100ps for multiple channels. Due to its fast propagation capability it has taken advantage of the FPGA internal carry logic for accurate time measurements. Furthermore, the implementation of the TDC has been performed in different clock regions and tested with different frequencies as well, achieving improvements of up to 50% for a pair of channels. Moreover, since the TDC is potentially going to be used in a trigger system for Positron Emission Tomography (PET), the algorithm for coinci…

business.industryComputer scienceCarry (arithmetic)High resolutionCoincidenceTime-to-digital converterIdentification (information)Hardware and ArchitectureGate arraybusinessDifference-map algorithmField-programmable gate arraySoftwareComputer hardwareJournal of Systems Architecture
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Integrating Social Skills in Task-Oriented 3D IVA

2005

This paper presents a set of mechanisms oriented to incorporate social information into the decision taking of task-oriented 3DIVA. The aim of this approach is to integrate collaborative skills in different character's roles (seller/buyer, worker, pedestrian, etc.) in order to enhance its behavioral animation. The collective intelligence expected in this kind of multi-character domains (e.g. storytelling, urban simulation, interactive games, etc.) requires agents able to dialogue/interact with other characters, to autonomously group/ungroup (according to their goals), or to distribute tasks and coordinate their execution for solving possible conflicts. The social model implemented follows t…

business.industryComputer scienceCollective intelligenceContext (language use)computer.software_genreTask (project management)Intelligent agentResource (project management)Social skillsHuman–computer interactionConflict resolutionNarrativeArtificial intelligencebusinessSet (psychology)computerComputer animationStorytelling
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Design and development of a fNIRS system prototype based on SiPM detectors

2014

Functional Near Infrared Spectroscopy (fNIRS) uses near infrared sources and detectors to measure changes in absorption due to neurovascular dynamics in response to brain activation. The use of Silicon Photomultipliers (SiPMs) in a fNIRS system has been estimated potentially able to increase the spatial resolution. Dedicated SiPM sensors have been designed and fabricated by using an optimized process. Electrical and optical characterizations are presented. The design and implementation of a portable fNIRS embedded system, hosting up to 64 IR-LED sources and 128 SiPM sensors, has been carried out. The system has been based on a scalable architecture whose elementary leaf is a flexible board …

business.industryComputer scienceDetectorNear-infrared spectroscopySettore ING-INF/02 - Campi ElettromagneticiNear Infrared SpectroscopySilicon PhotomultipliersReflectivitySettore ING-INF/01 - ElettronicaImaging phantomlaw.inventionOpticsSilicon photomultiplierlawOptoelectronicsSensitivity (control systems)businessEmbedded SystemsImage resolutionSilicon PhotomultiplierLight-emitting diode
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Extended Depth-of-Field 3-D Display and Visualization by Combination of Amplitude-Modulated Microlenses and Deconvolution Tools

2005

One of the main challenges in 3-D display and visualization is to overcome its limited depth of field. Such limitation is due to the fast deterioration of lateral resolution for out-of-focus object positions. Here we propose a new method to significantly extend the depth of field. The method is based on the combined benefits of a proper amplitude modulation of the microlenses, and the application of deconvolution tools. Numerical tests are presented to verify the theoretical analysis.

business.industryComputer scienceIterative reconstructionCondensed Matter PhysicsElectronic Optical and Magnetic MaterialsVisualizationAmplitude modulationOpticsAmplitudeModulation (music)Depth of fieldDeconvolutionElectrical and Electronic EngineeringbusinessImage resolutionJournal of Display Technology
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Superresolving optical system with time multiplexing and computer decoding

2008

Objects that have slow temporal variations may be superresolved with two moving masks such as pinhole or grating. The first mask is responsible for encoding the input image, and the second one performs the decoding operation. This approach is efficient for exceeding the resolving capability beyond Abbe’s limit of resolution. However, the proposed setup requires two physical gratings that should move in a synchronized manner. We propose what is believed to be a novel configuration in which the second grating responsible for the information decoding is replaced with a detector array and some postprocessing digital procedures. In this way the synchronization problem that exists when two gratin…

business.industryComputer scienceMaterials Science (miscellaneous)Aperture synthesisPhysics::OpticsImage processingGratingMultiplexingSuperresolutionIndustrial and Manufacturing EngineeringSynchronizationsymbols.namesakeOpticssymbolsPinhole (optics)Business and International ManagementbusinessDoppler effectImage resolutionDecoding methodsApplied Optics
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Measuring the Spatial and Spectral Performance of WorldView-3

2015

The new WorldView-3 satellite provides a unique combination of very high spatial resolution and super-spectral capabilities. This presentation explores the practical and theoretical usefulness of this platform as compared against other hyperspectral and multispectral sensors.

business.industryComputer scienceMultispectral imageHigh spatial resolutionHyperspectral imagingSatelliteComputer visionArtificial intelligenceEarth remote sensingImage sensorbusinessImage resolutionRemote sensingFourier Transform Spectroscopy and Hyperspectral Imaging and Sounding of the Environment
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Fast algorithm for detection of reference spheres in digital panoramic radiography.

2009

In this paper, an algorithm for detection of reference spheres from digital panoramic radiographic images is presented. The proposed algorithm was tested on a database of 107 digital panoramic radiographic images which were used for dental diagnostics. Results show that the proposed method exhibits for detection of reference spheres, a sensitivity of 97.33% and specificity of 93.85%. Performance time differed between 0.55 and 2.36s depending on image size. The aim of this work was to provide a fast ellipse detection algorithm to reduce measuring time on preoperative implant planning by lowering the computational cost.

business.industryComputer scienceRadiographyHealth InformaticsRadiography Dental DigitalEllipseFast algorithmSensitivity and SpecificityComputer Science ApplicationsDental ImplantationSurgery Computer-AssistedPattern recognition (psychology)HumansComputer visionSPHERESArtificial intelligenceSensitivity (control systems)Diagnosis Computer-AssistedbusinessImage resolutionAlgorithmsSoftwareComputers in biology and medicine
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Reconstruction Improvement in Integral Fourier Holography by Micro-Scanning Method

2015

Although integral holography has many promising advantages in the field of 3D imaging, the resolution of reconstructed holographic image is still limited by the insufficient information captured. To improve the reconstruction quality, an integral Fourier holographic imaging method based on micro-scanning of the micro-lens array is proposed in this paper. The micro-scanning of the micro-lens array can increase the sampling rate in spatial frequency domain and the information of the generated Fourier hologram, which will eventually eliminate the overlapping effect in the reconstructed 3D image. Experiments for different micro-scanning modes are carried out to verify the feasibility of the pro…

business.industryComputer scienceResolution (electron density)HolographyIterative reconstructionCondensed Matter PhysicsElectronic Optical and Magnetic Materialslaw.inventionsymbols.namesakeFourier transformOpticslawFrequency domainsymbolsComputer visionDigital holographic microscopySpatial frequencyArtificial intelligenceElectrical and Electronic EngineeringbusinessImage resolutionJournal of Display Technology
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