Search results for " SPECT"

Detecting explosive substances by the IR spectrography

2014

Fast and safe detection methods of explosive substances are needed both before and after actualized explosions. This article presents an experiment of the detection of three selected explosives by the ATR FTIR spectrometer and by three different IR hyperspectral imaging devices. The IR spectrometers give accurate analyzing results, whereas hyperspectral imagers can detect and analyze desired samples without touching the unidentified target at all. In the controlled explosion experiment TNT, dynamite and PENO were at first analyzed as pure substances with the ATR FTIR spectrometer and with VNIR, SWIR and MWIR cameras. After three controlled explosions also the residues of TNT, dynamite and P…

The challenges of analysing blood stains with hyperspectral imaging

2014

Hyperspectral imaging is a potential noninvasive technology for detecting, separating and identifying various substances. In the forensic and military medicine and other CBRNE related use it could be a potential method for analyzing blood and for scanning other human based fluids. For example, it would be valuable to easily detect whether some traces of blood are from one or more persons or if there are some irrelevant substances or anomalies in the blood. This article represents an experiment of separating four persons' blood stains on a white cotton fabric with a SWIR hyperspectral camera and FT-NIR spectrometer. Each tested sample includes standardized 75 _l of 100 % blood. The results s…

High-precision measurement of the mass difference between 102Pd and 102Ru

2019

Abstract The Q-value for the neutrinoless double electron capture on 102Pd, Qϵϵ(102Pd), is determined as the atomic mass difference between 102Pd and 102Ru. A precise measurement of the Qϵϵ(102Pd) at the SHIPTRAP Penning trap showed a more than 10σ deviation to the adopted Atomic Mass Evaluation (AME) value. The reliability of the SHIPTRAP measurement was challenged because the AME value was based on numerous experiments including β and electron capture decays and very precise (n, γ) data, all agreeing with each other. To solve the discrepancy, the Qϵϵ(102Pd) has now been determined with the JYFLTRAP Penning trap at the IGISOL facility in the Accelerator Laboratory of the University of Jyva…

Molecule-like photodynamics of Au102(pMBA)44 nanocluster.

2015

Photophysical properties of a water-soluble cluster Au102(pMBA)44 (pMBA = para-mercaptobenzoic acid) are studied by ultrafast time-resolved mid-IR spectroscopy and density functional theory calculations in order to distinguish between molecular and metallic behavior. In the mid-IR transient absorption studies, visible or near-infrared light is used to electronically excite the sample, and the subsequent relaxation is monitored by studying the transient absorption of a vibrational mode in the ligands. Based on these studies, a complete picture of energy relaxation dynamics is obtained: (1) 0.5-1.5 ps electronic relaxation, (2) 6.8 ps vibrational cooling, (3) intersystem crossing from the low…

Electronic Structure and Optical Properties of the Intrinsically Chiral 16-Electron Superatom Complex [Au20(PP3)4]4+

2014

The recently solved crystal structure of the [Au20(PP3)4]Cl4 cluster (PP3: tris(2-(diphenylphophino)ethyl)phosphine) is examined using density functional theory (DFT). The Au20 core of the cluster is intrinsically chiral by the arrangement of the Au atoms. This is in contrast to the chirality of thiolate-protected gold clusters, in which the protecting Au-thiolate units are arranged in chiral patterns on achiral cores. We interpret the electronic structure of the [Au20(PP3)4]Cl4 cluster in terms of the superatom complex model. The 16-electron cluster cannot be interpreted as a dimer of 8-electron clusters (which are magic). Instead, a superatomic electron configuration of 1S(2) 1P(6) 1D(6) …

One-pot synthesis and characterization of subnanometre-size benzotriazolate protected copper clusters

2012

A simple one-pot method for the preparation of subnanometre-size benzotriazolate (BTA) protected copper clusters, Cu(n)BTA(m), is reported. The clusters were analyzed by optical and infrared spectroscopy, mass spectrometry and transmission electron microscopy together with computational methods. We suggest a structural motif where the copper core of the Cu(n)BTA(m) clusters is protected by BTA-Cu(i)-BTA units.

Multi-hop D2D Communications with Network Coding : From A Performance Perspective

2019

Multi-hop device-to-device (D2D) communications play an important role in expanding D2D coverage. In this paper, we study a relay-based and network-coding-assisted (in particular, XOR coding) multi-hop D2D communication system. In the system, toward jointly considering the impact of interference and network traffic conditions on the quality of D2D communications, various channel fading models and traffic models are investigated, and the packet loss probability of D2D links is meticulously computed using these models. With the packet loss probability of D2D links, the general closed-form expressions of end-to-end packet loss probability (E2EPLP) of the system with the presence (or absence) o…

Chandra study of the eclipsing M dwarf binary, YY Gem

2012

The eclipsing M dwarf binary system, YY Gem, was observed using Chandra covering 140 ks (2Prot) in total, split into two even exposures separated by 0.76 d (0.94 Prot). The system was extremely active: three energetic flares were observed over the course of these observations. The flaring and non-flaring states of the system are analysed in this paper. The activity level increased between the first and second observations even during the quiescent (non-flaring) phases. An analysis of the dynamics of the X-ray-emitting plasma suggests that both components are significantly active. Contemporaneous Hα spectra also suggest that both components show similar levels of activity. The primary star i…

A wideband THz Time Domain Spectroscopy system based on pulsed laser: model and experiments

2014

Understanding the White-Emitting CaMoO4 Co-Doped Eu3+, Tb3+, and Tm3+ Phosphor through Experiment and Computation

2019

In this article, the synthesis by means of the spray pyrolysis method, of the CaMoO4 and rare-earth cation (RE3+)-doped CaMoO4:xRE3+ (RE3+ = Eu3+, Tb3+, and Tm3+; and x = 1, 2, and 4% mol) compounds, is presented. The as-synthesized samples were characterized using X-ray diffraction, Rietveld refinement, field emission scanning electron microscopy (FE-SEM), Raman spectroscopy, and photoluminescence (PL) spectroscopy. To complement and rationalize the experimental results, first-principles calculations, at the density functional theory level, have been performed to analyze the band structure and density of states. In addition, a theoretical method based on the calculations of surface energie…