Search results for " Total"
showing 10 items of 385 documents
Influence of Polyvinyl Alcohol (PVA) on PVA-Poly-N-hydroxyethyl-aspartamide (PVA-PHEA) Microcrystalline Solid Dispersion Films
2020
AbstractThis study was conducted to formulate buccal films consisting of polyvinyl alcohol (PVA) and poly-N-hydroxyethyl-aspartamide (PHEA), to improve the dissolution of the drug through the oral mucosa. Ibuprofen sodium salt was used as a model drug, and the buccal film was expected to enhance its dissolution rate. Two different concentrations of PVA (5% w/v and 7.5% w/v) were used. Solvent casting was used to prepare films, where a solution consisting of drug and polymer was cast and allowed to dry. Attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR), differential scanning calorimetry (DSC), and scanning electron microscopy (SEM) were used to investigate the pr…
Thermal restraint of a bacterial exopolysaccharide of shallow vent origin
2018
This is the post-print version of the following article: "Thermal restraint of a bacterial exopolysaccharide of shallow vent origin", which has been published in final form at https://www.sciencedirect.com/science/article/pii/S0141813018308250?via%3Dihub; International audience; To dynamically characterize the thermal properties of the fructose-rich exopolysaccharide (EPS1-T14), produced by themarine thermophilic Bacillus licheniformis T14, the Attenuated Total Reflectance Fourier Transform Infra-Redspectroscopy was coupled to variable temperature ranging from ambient to 80 °C.The spectra were analyzed by the following innovative mathematical tools: i) non-ideal spectral deviation, ii) OHst…
Ultrasonic phased array inspection of wire plus arc additive manufacture samples using conventional and total focusing method imaging approaches
2019
In this study, three aluminium samples produced by wire + arc additive manufacture (WAAM) are inspected using ultrasonic phased array technology. Artificial defects are machined using a centre drill, ø 3 mm, and electrical discharge machining (EDM), ø 0.5-1 mm, in a cylindrical through-hole topology. The samples are first inspected using a single-element wheel probe mounted on a KUKA robot in order to investigate the feasibility of using a conventional ultrasonic transducer approach. Unfortunately, the wheel probe is found to be unsuitable for scanning the WAAM specimens and ultrasonic phased arrays are employed next. The set-up includes 5 MHz and 10 MHz arrays (128 elements) in direct cont…
Two-component self-assembly with solvent leading to "wet" and microcrystalline organogel fibers
2014
Abstract Hypothesis The microcrystalline fibers of N -(2-aminoethyl)-3α-hydroxy-5β-cholan-24-amide 1 provided a useful model system for studying the complex relationship between morphology, experimental parameters, solvent, and the phenomenon of organogelation. The presence of solvents in the solid forms of 1 along with crystallization behavior suggested solvate formation and polymorphic behavior. Experiments Forty solid state- and xerogel samples of 1 formed in organic solvents and in three categories of experimental conditions were analyzed with single crystal X-ray diffraction (XRD), powder X-ray diffraction (PXRD), Raman microscopy, and attenuated total reflection Fourier-transform infr…
A generalization of the orthogonal regression technique for life cycle inventory
2012
Life cycle assessment (LCA) is a method used to quantify the environmental impacts of a product, process, or service across its whole life cycle. One of the problems occurring when the system at hand involves processes delivering more than one valuable output is the apportionment of resource consumption and environmental burdens in the correct proportion amongst the products. The mathematical formulation of the problem is represented by the solution of an over-determined system of linear equations. The paper describes the application of an iterative algorithm for the implementation of least square regression to solve this over-determined system directly in its rectangular form. The applied …
On the checking of g-coherence of conditional probability bounds
2003
We illustrate an approach to uncertain knowledge based on lower conditional probability bounds. We exploit the coherence principle of de Finetti and a related notion of generalized coherence (g-coherence), which is equivalent to the "avoiding uniform loss" property introduced by Walley for lower and upper probabilities. Based on the additive structure of random gains, we define suitable notions of non relevant gains and of basic sets of variables. Exploiting them, the linear systems in our algorithms can work with reduced sets of variables and/or constraints. In this paper, we illustrate the notions of non relevant gain and of basic set by examining several cases of imprecise assessments d…
Comparison of near and mid infrared spectroscopy as green analytical tools for the determination of total polar materials in fried oils
2017
Abstract Total polar materials (TPM) are used as an indicator of the quality in the frying oil because of high values may be harmful for human health. Spanish legislation establishes the maximum level of total polar materials for frying fats and oils for human consumption around 25% (w/w). Official methods to monitor oil quality are time consuming and use a lot of chemicals; therefore it is necessary a simple and quick analytical technique to evaluate fried oils. Transmittance near-infrared (NIR) and attenuated total reflection mid-infrared (ATR-MIR) spectroscopy measurements, combined with partial least squares (PLS) regression, offer alternatives to determine TPM in fried oils with relati…
High-to-low (Regional) fertility transitions in a peripheral european country: The contribution of exploratory time series analysis
2021
Diachronic variations in demographic rates have frequently reflected social transformations and a (more or less evident) impact of sequential economic downturns. By assessing changes over time in Total Fertility Rate (TFR) at the regional scale in Italy, our study investigates the long-term transition (1952–2019) characteristic of Mediterranean fertility, showing a continuous decline of births since the late 1970s and marked disparities between high- and low-fertility regions along the latitude gradient. Together with a rapid decline in the country TFR, the spatiotemporal evolution of regional fertility in Italy—illustrated through an exploratory time series statistical approach—outlines th…
The growth of “black crusts” on calcareous building stones in Palermo (Sicily): a first appraisal of anthropogenic and natural sulphur sources
2008
Chemical, mineralogical and isotopic composition (34S/32S) analyses were carried out on “black crusts” developed on the old buildings of Palermo (Sicily) with the aim to distinguish between natural and anthropogenic sulphur sources. Furthermore individual samples of total suspended particulate (TSP) were collected and analysed in order to estimate the influence of air pollution on the decay process of calcareous stones in a typical southern Mediterranean coastal environment. SEM/EDS analysis, X-ray diffractometry, IR spectroscopy and liquid chromatography led to the compositional characterization of “black crusts” and airborne particulate matter in the city. Sulphur isotopic compositions of…
Treatment of Oily Wastewater with Membrane Bioreactor Systems
2017
The aim of the present work was to investigate the behavior of a membrane bioreactor (MBR) system for the treatment of oily wastewater. A bench scale MBR was fed with synthetic wastewater containing diesel fuel. Organic carbon, hydrocarbon and ammonium removal, kinetic constants, extracellular polymeric substances production, and membrane fouling rates were monitored. The MBR plant was operated for more than 200 days, and the results highlighted good carbon removal and nitrification, suggesting a sort of biomass adaptation to hydrocarbons. Membrane fouling analysis showed an increase in total resistance, likely due to hydrocarbons, which caused an irreversible fouling (pore blocking) mainly…