Search results for " acid"
showing 10 items of 12150 documents
Anthropogenic lead distribution in soils under arable land and permanent grassland estimated by Pb isotopic compositions
2008
International audience; The role of land use on fate of metals in soils is poorly understood. In this work, we studied the incorporation of lead in two neighboring soils with comparable pedogenesis but under long-term different agricultural management. Distributions of anthropogenic Pb were assessed from concentrations and isotopic compositions determined on bulk horizon samples, systematical 5–10 cm increment samples, and on 24-h EDTA extracts. Minor amounts of anthropogenic lead were detected until 1-m depth under permanent grassland, linked to high earthworm activity. In arable land, exogenous Pb predominantly accumulated at depths <60 cm. Although the proximity between the two sites ens…
New insights on secondary minerals from Italian sulfuric acid caves
2018
Sulfuric acid minerals are important clues to identify the speleogenetic phases of hypogene caves. Italy hosts ~25% of the known worldwide sulfuric acid speleogenetic (SAS) systems, including the famous well-studied Frasassi, Monte Cucco, and Acquasanta Terme caves. Nevertheless, other underground environments have been analyzed, and interesting mineralogical assemblages were found associated with peculiar geomorphological features such as cupolas, replacement pockets, feeders, sulfuric notches, and sub-horizontal levels. In this paper, we focused on 15 cave systems located along the Apennine Chain, in Apulia, in Sicily, and in Sardinia, where copious SAS minerals were observed. Some of the…
Hydroxylamine released by nitrifying microorganisms is a precursor for HONO emission from drying soils
2018
AbstractNitrous acid (HONO) is an important precursor of the hydroxyl radical (OH), the atmosphere´s primary oxidant. An unknown strong daytime source of HONO is required to explain measurements in ambient air. Emissions from soils are one of the potential sources. Ammonia-oxidizing bacteria (AOB) have been identified as possible producers of these HONO soil emissions. However, the mechanisms for production and release of HONO in soils are not fully understood. In this study, we used a dynamic soil-chamber system to provide direct evidence that gaseous emissions from nitrifying pure cultures contain hydroxylamine (NH2OH), which is subsequently converted to HONO in a heterogeneous reaction w…
Steroid Biomarkers Revisited - Improved Source Identification of Faecal Remains in Archaeological Soil Material.
2017
Steroids are used as faecal markers in environmental and in archaeological studies, because they provide insights into ancient agricultural practices and the former presence of animals. Up to now, steroid analyses could only identify and distinguish between herbivore, pig, and human faecal matter and their residues in soils and sediments. We hypothesized that a finer differentiation between faeces of different livestock animals could be achieved when the analyses of several steroids is combined (Δ5-sterols, 5α-stanols, 5β-stanols, epi-5β-stanols, stanones, and bile acids). We therefore reviewed the existing literature on various faecal steroids from livestock and humans and analysed faeces …
Selenium mobilization in soils due to volcanic derived acid rain: An example from Mt Etna volcano, Sicily
2011
International audience; The significant amounts of selenium (Se) emitted by volcanoes may have important impact on human health due to the narrow range between nutrition requirement and toxic effects for living organisms upon Se exposure. Although soils play a key role in determining the level in food and water and thereby human health, little is known about the behaviour of Se in volcanic soils. In this work we evaluated the Se release during rainwater–soil interaction under controlled conditions using soils collected on the flanks of Etna volcano and synthetic rain. Selenium concentrations in soil leachate solutions displayed a spatial distribution, which cannot be explained by plume depo…
Evidence for marine biogenic influence on summertime Arctic aerosol
2017
International audience; We present vertically-resolved observations of aerosol composition during pristine summertime Arctic background conditions. The methansulfonic acid (MSA)-to-sulfate ratio peaked near the surface (mean 0.10), indicating a contribution from ocean-derived biogenic sulfur. Similarly, the organic aerosol (OA)-to-sulfate ratio increased towards the surface (mean 2.0). Both MSA-to-sulfate and OA-to-sulfate ratios were significantly correlated with FLEXPART-WRF-predicted airmass residence time over open water, indicating marine influenced OA. External mixing of sea salt aerosol from a larger number fraction of organic, sulfate and amine-containing particles, together with lo…
Dating of the hominid (Homo neanderthalensis) remains accumulation from El Sidrón cave (Piloña, Asturias, North Spain): an example of multi-methodolo…
2010
The age of Neanderthal remains and associated sediments from El Sidrón cave has been obtained through different dating methods (14CAMS, U/TH, OSL, ESR and AAR) and samples (charcoal debris, bone, tooth dentine, stalagmitic flowstone, carbonate-rich sediments, sedimentary quartz grains, tooth enamel and land snail shells). Detrital Th contamination rendered Th/U dating analyses of flowstone unreliable. Recent 14C contamination produced spurious age-values from charcoal samples as well as from inadequately pretreated tooth samples. Most consistent 14C dates are grouped into two series: one between 35 and 40 ka and the other between 48 and 49 ka. Most ESR and AAR samples yielded concordant age…
Steroids aid in human decomposition fluid identification in soils of temporary mass graves from World War II
2020
Abstract Steroids are widely used for the detection of faecal matter and also – in recent years – for characterising human decomposition in the terrestrial environment. Until now it was not clear whether all commonly used faecal (i.e. 5β-stanols, 5β-stanones and bile acids) and tissue derived steroids (i.e. cholesterol, 5α-cholestanol and 5α-cholestanone) could reveal the presence of human decomposition products in temporary graves. In this study, soil was sampled from three putative mass graves where concentration camp prisoners were temporarily buried for 10 months at the end of World War II (1944 – 45). We hypothesised that soil from the putative temporary mass graves exhibits elevated c…
Transient metazoan reefs in the aftermath of the end-Permian mass extinction
2011
5 pages; International audience; Recovery from the devastating Permian-Triassic mass extinction about 252 million years ago is usually assumed to have spanned the entire 5 million years of the Early Triassic epoch1,2. The post-crisis interval was characterized by large-scale fluctuations of the global carbon cycle and harsh marine conditions, including a combination of ocean acidification, euxinia, and fluctuating productivity3. During this interval, metazoan-dominated reefs are thought to have been replaced by microbial deposits that are considered the hallmark of the Early Triassic4-7. Here we use field and microscopic investigations to document Early Triassic bioaccumulations and reefs f…
Bioavailable 87Sr/86Sr in different environmental samples — Effects of anthropogenic contamination and implications for isoscapes in past migration s…
2012
(87)Sr/(86)Sr reference maps (isoscapes) are a key tool for investigating past human and animal migrations. However, there is little understanding of which biosphere samples are best proxies for local bioavailable Sr when dealing with movements of past populations. In this study, biological and geological samples (ground vegetation, tree leaves, rock leachates, water, soil extracts, as well as modern and archeological animal teeth and snail shells) were collected in the vicinity of two early medieval cemeteries ("Thuringians", 5-6th century AD) in central Germany, in order to characterize (87)Sr/(86)Sr of the local biosphere. Animal tooth enamel is not appropriate in this specific context t…