Search results for " bulk"

Thin-Film Heterojunction by Carbon Nanotube Derivatives with Enhanced Solubility and Optical Properties

2012

THIN-FILM HETROJUNCTION BY CARBON NANOTUBE DERIVATIVES WITH ENHANCED SOLUBILITY AND OPTICAL PROPERTIES

2012

The combination of single-walled carbon nanotubes (SWNTs), characterized by high electron mobility, with p-type semiconducting polymers could lead to an overall improvement in the exciton dissociation and carrier extraction efficiencies in practical devices.1However, one of the main concern in the use of SWNTs, relates to the their scarce solubility. Chemical modification has been widely employed to increase the solubility of SWNTs, but usual reaction conditions limit such syntheses to a small scale with low productivity. Here, we employ SWNTs which have been functionalized with aromatic and heteroaromatic moieties via 1,3-dipolar cycloaddition and through diazotization reaction under batch…

Role of photoactive layer morphology in high fill factor all-polymer bulk heterojunction solar cells

2011

We report on the realization of all-polymer solar cells based on blends of poly(3-hexylthiophene-2,5-diyl) (P3HT) as a donor and poly{[N,N'-bis(2-octyldodecyl)-naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,5'-(2,2'-bithiophene)} (P(NDI2OD-T2)) as an acceptor. High fill factors are demonstrated for the first time in this class of devices suggesting high dissociation efficiency for the bounded electron-hole pairs and balanced electron and hole mobility along the thin films. The use of the high-mobility n-type P(NDI2OD-T2) polymer enables us to overcome one of the problems limiting the efficiency of all-polymer solar cells, resulting in fill factors comparable with those reported for …

Study of the factors affecting activated sludge settling in domestic wastewater treatment plants

1992

A study has been made of the influence of the process parameters on the settling characteristics of sludge in domestic wastewater treatment plants. The experiments were conducted at a pilot plant situated at the Wastewater Treatment Plant of Valencia, Spain (1,000,000 inhabitants). The influent to the pilot plant was the same as that of the plant. It was found that F/M ratios in the range of 0.25-0.60 g DBO5/g MLVSS day produce values of SVI representative of good settleability of the sludge. Values of sulphide concentration in the influent above 1.0 mg/l negatively affect the process, causing bulking and floating sludge. High values of fats were found to have no influence on the SVI, but d…

Removal of DEHP in composting and aeration of sewage sludge.

2003

The potential of composting and aeration to remove bis(2-ethylhexyl) phthalate (DEHP) from municipal sewage sludge was studied with two dewatered sludges: raw sludge and anaerobically digested sludge. Composting removed 58% of the DEHP content of the raw sludge and 34% of that of the anaerobically digested sludge during 85 days stabilisation in compost bins. A similar removal for the anaerobically digested sludge was achieved in a rotary drum in 28 days. Less than 1% of DEHP was removed with the compost leachate. Although DEHP removal was greater from raw sludge compost than anaerobically digested sludge compost, the total and volatile solids removals were on the same level in the two compo…

Stima dei flussi energetici all’interfaccia aria-mare con l’impiego di SST da Satellite e dati rilevati in situ.

2007

La conoscenza dei flussi energetici scambiati fra oceano e bassa atmosfera è un requisito utile per modellare e comprendere il sistema climatico e la dinamica degli oceani. L’elevata difficoltà di effettuare misure in situ ed in continuo in ambiente marino induce spesso all’utilizzo ausiliario di strumentazione satellitare. Nel presente lavoro è stato effettuato un confronto tra la stima dei flussi energetici superficiali valutati con dati provenienti da satellite e quelli ottenuti da misure in situ. In particolare, per il confronto, sono stati utilizzati i dati SST acquisiti dal satellite NOAA e i dati raccolti in situ dai sensori istallati a bordo della Nave Oceanografica Urania nel corso…

Molecular and Cellular Insights into the Development of Uterine Fibroids

2021

Uterine leiomyomas represent the most common benign gynecologic tumor. These hormone-dependent smooth-muscle formations occur with an estimated prevalence of ~70% among women of reproductive age and cause symptoms including pain, abnormal uterine bleeding, infertility, and recurrent abortion. Despite the prevalence and public health impact of uterine leiomyomas, available treatments remain limited. Among the potential causes of leiomyomas, early hormonal exposure during periods of development may result in developmental reprogramming via epigenetic changes that persist in adulthood, leading to disease onset or progression. Recent developments in unbiased high-throughput sequencing technolog…

Comparative Study of the Compressibility of M3V2O8 (M = Cd, Zn, Mg, Ni) Orthovanadates

2022

We report herein a theoretical study of the high-pressure compressibility of Cd3V2O8, Zn3V2O8, Mg3V2O8, and Ni3V2O8. For Cd3V2O8, we also present a study of its structural stability. Computer simulations were performed by means of first-principles methods using the CRYSTAL program. In Cd3V2O8, we found a previously unreported polymorph which is thermodynamically more stable than the already known polymorph. We also determined the compressibility of all compounds and evaluated the different contributions of polyhedral units to compressibility. We found that the studied vanadates have an anisotropic response to compression and that the change in volume is basically determined by the compressi…

Evaluation of marginal sealing quality of restorations with low shrinkage composite resins

2020

Background This study compared the quality of marginal sealing in the gingival wall of class II preparations of two low-shirinkage resins of the bulk fill type with a conventional resin isolated or associated with a glass ionomer cement (GIC). Material and methods 40 human molars were divided into 4 groups and 80 occlusal-mesial and occlusal-distal restorations were performed with the following materials: SureFil SDR flow, Filtek Bulk Fill Posterior, Z250 resins and Riva Light Cure GIC. 40 restorations were evaluated in Scanning Electron Microscopy (SEM) with Elemental Microanalysis Spectrometry (EDS) initially and the remainder after a period of 6 months of aging in a 37 ± 5°C oven. An ave…

Signature of the 24th December 2018 eruption of Mt. Etna on the chemical composition of bulk deposition in the Siracusa area (Italy)

2020

Mt. Etna, in the eastern coast of Sicily (Italy), is one of the most active and most intensely monitored volcanoes of the planet. It is widely recognized as a big source of volcanic gases, such as CO2, SO2 and halogens, to the troposphere in the Mediterranean basin, and its gas emissions account for a significant percentage respect to the worldwide average volcanic budget. The SO2 flux from Mt. Etna’s plume has been routinely measured by the INGV since 1987. SO2 flux ranges between 600 to 25000 Mg/d; fluxes greater than 100000 Mg/d were prevalently measured during eruptive events. During eruptive periods, Etna’s emissions can be dispersed over long distances and cover wide areas of the Medi…