Search results for " collo"
showing 10 items of 87 documents
Basic properties of the F-type centers in halides, oxides and perovskites
2010
We present a short survey of the optical properties of primary radiation-induced point defects in alkali halides, simple oxides and some ABO3 perovskites. We discuss in details the optical properties of single electron F and F + centers in rock-salt (f.c.c.) alkali halides and oxides and show that the Mollwo–Ivey law well-known for the F-type centers in alkali halides may be extended for other rock-salt structure insulators. We also discuss the major differences in point defect production mechanisms in halides and oxides. We show that the Rabin–Klick diagram may be generalized for a whole family of alkali halides. The F-type center migration and aggregation into metal colloids in alkali hal…
Computer modeling of metal colloid formation in tracks of swift heavy ions in ionic solids
2001
Abstract We present results of computer modelling of the aggregation of primary radiation defects—F centers—in ionic crystals within tracks of swift heavy ions. We study how F-aggregate properties depend on the initial density of primary Frenkel defects in the track and its radius. The mean number of F centers in aggregates is typically very small, about five defects, which greatly complicates detection of expected metal colloids by ESR.
Exponential convergence andH-c multiquadric collocation method for partial differential equations
2003
The radial basis function (RBF) collocation method uses global shape functions to interpolate and collocatethe approximate solution of PDEs. It is a truly meshless method as compared to some of the so-calledmeshless or element-free finite element methods. For the multiquadric and Gaussian RBFs, there are twoways to make the solution converge—either by refining the mesh size
Field-induced ordering phenomena and non-local elastic compliance in two-dimensional colloidal crystals
2008
Ordering phenomena in colloidal dispersions exposed to external one-dimensional, periodic fields or under confinement are studied systematically by Monte Carlo computer simulations. Such systems are useful models for the study of monolayers on a substrate. We find that the interaction with a substrate potential completely changes the miscibility of a binary, hard disc mixture at low external field amplitudes. The underlying ordering mechanisms leading to this laser-induced de-mixing differ, depending on which components interact with the substrate potential. Generic effects of confinement on crystalline order in two dimensions are studied in a model system of point particles interacting via…
Active photonic devices based on colloidal semiconductor nanocrystals and organometallic halide perovskites
2016
Semiconductor nanocrystals have arisen as outstanding materials to develop a new generation of optoelectronic devices. Their fabrication under simple and low cost colloidal chemistry methods results in cheap nanostructures able to provide a wide range of optical functionalities. Their attractive optical properties include a high absorption cross section below the band gap, a high quantum yield emission at room temperature, or the capability of tuning the band-gap with the size or the base material. In addition, their solution process nature enables an easy integration on several substrates and photonic structures. As a consequence, these nanoparticles have been extensively proposed to devel…
Nonlinear Optical Characterization of InP@ZnS Core-Shell Colloidal Quantum Dots Using 532 nm, 10 ns Pulses
2021
InP@ZnS core-shell colloidal quantum dots (CQDs) were synthesized and characterized using the z-scan technique. The nonlinear refraction and nonlinear absorption coefficients (γ = −2 × 10−12 cm2 W−1, β = 4 × 10−8 cm W−1) of these CQDs were determined using 10 ns, 532 nm pulses. The saturable absorption (β = −1.4 × 10−9 cm W−1, Isat = 3.7 × 108 W cm−2) in the 3.5 nm CQDs dominated at small intensities of the probe pulses (I ≤ 7 × 107 W cm−2) followed by reverse saturable absorption at higher laser intensities. We report the optical limiting studies using these CQDs showing the suppression of propagated nanosecond radiation in the intensity range of 8 × 107–2 × 109 W cm−2. The role of nonline…
Zr, Hf and REE distribution in river water under different ionic strength conditions
2018
International audience; The Platani River flowing in south-central Sicily, interacting with evaporite rocks, generates a wide range of ionic strength in the water catchment from 0.1 to 5.0 mol kg−1. We sampled 38 river sites and analysed the composition for the dissolved fraction filtered through 0.45 μm, the truly dissolved fraction obtained through ultrafiltration (10 kDa) and the relative included colloidal fraction.This study was focused on the recognition of Zr, Hf and REE behaviour under changing ionic strength conditions, since this is one of parameters responsible for colloid stability in natural waters. In turn, this phenomenon leads to REE release from the colloidal fraction and t…
Preparation and characterization of lipid nanoparticles as potential carriers for ester prodrugs of flurbiprofen
2011
Les colloïdes solubles du vin de champagne. Relation avec le « remuage »
1978
<p style="text-align: justify;">Dans ce travail on étudie un échantillonnage de vins de champagne, en vue d'établir une relation entre leur composition en colloïdes et la facilité du « remuage ».</p><p style="text-align: justify;">Après champagnisation, les teneurs en colloïdes totaux sont toujours supérieures à celles des vins tranquilles correspondants. Plus la durée de clarification et de remuage est grande plus la teneur en colloïdes est élevée.</p><p style="text-align: justify;">Le fractionnement des colloïdes glucidiques solubles, en quatre fractions, sur Sépharose 6 B montre que celle de plus haut poids moléculaire a l'influence la plus directe sur les d…