Search results for " coordination"
showing 10 items of 215 documents
Clathration of Five-Membered Aromatic Rings in the Bimetallic Spin Crossover Metal–Organic Framework [Fe(TPT)2/3{MI(CN)2}2]·G (MI = Ag, Au)
2014
Six clathrate compounds of the three-dimensional spin crossover metal−organic framework formulated [Fe(TPT)2/3{MI (CN)2}2]· nG, where TPT is 2,4,6-tris(4-pyridyl)-1,3,5-triazine, MI = Ag or Au and G represent the guest molecules furan, pyrrole and thiophene, were synthesized using slow diffusion techniques. The clathrate compounds were characterized by single-crystal X-ray diffraction at 120 and 300 K, thermogravimetric analysis and thermal dependence of the magnetic susceptibility. All compounds crystallize in the R3̅ m trigonal space group. The FeII defines a unique [FeN6] crystallographic site with the equatorial positions occupied by four dicyanometallate ligands while the axial positio…
Blending Collaborative Governance and Dynamic Performance Management to Foster Policy Coordination in Renewable Energy Supply Chains
2020
As the use of renewable energy is growing worldwide, the wind industry is being endorsed as a promising source for clean energy supply. In this context, the strategic management of the supply chain is fundamental to pursue a steady expansion of renewable energy. However, the fragmentation between energy policy design and implementation has been considered as a major cause threatening the effectiveness in managing the supply chain. This problem has been provoked mainly by an unsynchronized and uncoordinated decision-making process that involves public and private institutions. This chapter proposes the adoption of a dynamic performance management approach for enhancing a collaborative govern…
How to support energy policy coordination? Findings from the Brazilian wind industry
2019
Abstract Despite a growing sense of urgency, the deployment of clean technologies has been affected by fragmentation of energy policy design and implementation. In some case, wicked policy issues around renewable energy infrastructure have delayed or even halted the uptake of renewables. To find possible answer to consistent policy design that involves public/private institutions of the electricity sector, the authors propose the adoption of a dynamic performance management approach to support the energy policy coordination.
A Heterobimetallic Anionic 3,6-Connected 2D Coordination Polymer Based on Nitranilate as Ligand
2016
In order to synthesize new coordination polymers with original architectures and interesting magnetic properties, we used the nitranilate ligand (C₆O₄(NO₂)₂2- = C₆N₂O₈2-), derived from the dianionic ligand dhbq2- (2,5-dihydroxy-1,4-benzoquinone = H₂C₆O₄2-). The use of this bis-bidentate bridging ligand led to [(DAMS)₂{FeNa(C₆N₂O₈)₃}·CH₃CN]n (1) (DAMS⁺ = C16H17N₂⁺ = 4-[4-(dimethylamino)-α-styryl]-1-methylpyridinium), a 2D heterometallic coordination polymer presenting an unprecedented structure for any anilato-based compound. This structural type is a 3,6-connected 2D coordination polymer derived from the well-known honeycomb hexagonal structure, where Fe(III) ions alternate with Na⁺ dimers …
Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]−
2016
The encapsulation of functional molecules inside porous coordination polymers (also known as metal-organic frameworks, MOFs) has become of great interest in recent years at the field of multifunctional materials. In this article, we present a study of the effects of size and charge in the anion exchange process of a Gd based MOF, involving molecular species like polyoxometalates (POMs), and [AuCl4]−. This post-synthetic modification has been characterized by IR, EDAX, and single crystal diffraction, which have provided unequivocal evidence of the location of the anion molecules in the framework.
Chimie de coordination du phosphore aux métaux du groupe 11 : progrès en catalyse de couplage C-N au Cu(I) et nouveaux complexes polyphosphines de l'…
2014
Nowadays, sustainable development encourages chemists to develop new economic and ecologic synthesis, because natural ressources are reducing. Most exploited ressources are gas and petroleum, but precious metals are also essential. This thesis is focusing on the enhancement of gold and copper complexes, obtained in our laboratory from phosphorous-based ligands. In the first part, we will develop a new system for the N-arylation of pyrazoles from a copper complexe coordinated by a new hybrid phosphinoalkene ligand. In the second part, coordination properties of gold to different ferrocenic polyphosphine will be studied. Several new innovative complexes will be isolated, and could be used in …
El Proyect3ES como metodología transdisciplinar de aprendizaje por proyectos en el Grado de Educació Social. Plan de evaluación y valoración del alum…
2020
[ES] Se presenta una estrategia didáctica para educación superior, basada en la interdisciplinariedad y el diseño de un proyecto de intervención interáreas. Está dirigida al alumnado del Grado de Educación Social, de la Universitat de València, y busca que el alumnado construya el de manera autónoma, en equipos de trabajo, abordando desde varias asignaturas simultáneamente el diseño de un proyecto de intervención, centrado en una necesidad real del contexto. A partir de la presentación, se centra el trabajo en el proceso de evaluación y en los instrumentos que se han utilizado. Se presenta un plan de evaluación que recoge información de alumnado, profesorado y organizaciones externas para r…
Teaching mechanical oscillations using an integrate curriculum
1997
Abstract A set of teaching materials dealing with harmonic oscillations was developed as part of a research project investigating the influence of different pedagogical tools on physics learning. The materials incorporate simulation software and laboratory activities associated with Teacher and Student Units. The project involved research groups at seven Italian universities and the materials have been trialled in high schools nation‐wide. This paper describes the experimental protocol for the use of these materials in pilot classes and the evaluation of student learning and teacher training results. The intervention was found to improve physics education at school praxis level and to promo…
Interpersonal Coordination in Dyadic Performance
2017
Dyadic musical performance provides an excellent framework to study interpersonal coordination because it involves multiple agents performing matched, rhythmic and/or interactive behaviors. In this chapter, we explore interpersonal coordination using Canonical Correlation Analysis as a coupling measure. To provide some context when interpreting the output of CCA, musicians performed using different expressive manners (deadpan, normal, exaggerated). Overall the results showed the normal performances were slightly more interpersonally coordinated than deadpan and exaggerated. peerReviewed
Reciprocity as source of Coordination and Spontaneous Cooperation
2013
The diffusion of yhe use of reciprocity as an alternative as an complementary category to standard economic behaviours is connected to the creation and development ,during the last thirty years, of experimental economics and behavioural economics. This paper analyses, the concept of reciprocity as a source of spontaneous cooperation in the Prisoner's Dilemma and in the Gift-Exchange Game (both in the one-shot and repeated game versions). In order to attain spontaneous coordination a relational strategy based upon a cognitive-relstional structure of agtrrment assumes, that the participants share not only the traditionally intended payoffs, but also social values and relational norms and that…