Search results for " coupling"

Thermal 1,6-Electrocyclization Reactions of Acceptor-Substituted 2,3-Divinyl-1H-indoles Yielding Functionalized Carbazoles

1990

Three new synthetic procedures for and thermal 1,6-electrocyclizations of acceptor-substituted 2,3-divinyl-1H-indoles leading to functionalizing carbazoles are described. The scope and limitations as well as some mechanistic aspects of the methodologies are discussed. The key strategies employed include Pd(II)-catalyzed coupling and Wittig procedures.

Metal- and reagent-free highly selective anodic cross-coupling reaction of phenols.

2014

The direct oxidative cross-coupling of phenols is a very challenging transformation, as homo-coupling is usually strongly preferred. Electrochemical methods circumvent the use of oxidizing reagents or metal catalysts and are therefore highly attractive. Employing electrolytes with a high capacity for hydrogen bonding, such as methanol with formic acid or 1,1,1,3,3,3-hexafluoro-2-propanol, a direct electrolysis in an undivided cell provides mixed 2,2′-biphenols with high selectivity. This mild method tolerates a variety of moieties, for example, tert-butyl groups, which are not compatible with other strong electrophilic media but vital for later catalytic applications of the formed products.

Temperature dependence of the isotropic hyperfine coupling constants in 1,4-hydroquinone and 1,4-dihydroxynaphthalene cation radicals

1998

Electric control of the spin Hall effect by intervalley transitions

2013

Controlling spin-related material properties by electronic means is a key step towards future spintronic technologies. The spin Hall effect (SHE) has become increasingly important for generating, detecting and using spin currents, but its strength-quantified in terms of the SHE angle-is ultimately fixed by the magnitude of the spin-orbit coupling (SOC) present for any given material system. However, if the electrons generating the SHE can be controlled by populating different areas (valleys) of the electronic structure with different SOC characteristic the SHE angle can be tuned directly within a single sample. Here we report the manipulation of the SHE in bulk GaAs at room temperature by m…

Integrating Advanced Visual Information with Ball Projection Technology Constrains Dynamic Interceptive Actions

2014

The role of advanced visual information in ball catching was investigated by integrating video images of action and ball projection technology in four different conditions: Integrated video and ball projection (VBP), Video-Only (VO), Ball Projection-Only (BPO) and Misleading Ball projection (MBP). Hand kinematics and gaze behaviour data were collected from participants who attempted to catch balls one handed in all conditions. During VBP, catching performance was more successful, tracking of the ball occurred earlier and lasted longer, with maximum grip aperture emerging earlier with a slower maximum velocity than in BPO. During VO, movement emerged later than VBP, with larger maximum and m…

Optimum Performance of Permanent Magnet Synchronous Generators Coupled to Wind Turbines

2007

In this paper a control algorithm for the efficiency improvement of permanent magnet synchronous generators (PMSG) is presented. The proposed algorithm reduces the losses of the generator without affecting its performances. In details, after a description of a dynamic model of the PMSG, which has been purposely modified in order to take into account the iron losses, the basic equations and the constraints to obtain the loss minimization are presented and discussed. Some simulations of a specific PMSG employing the proposed algorithm are performed. The results of these simulations show that enhancement of the efficiency up to 3% can be reached in comparison to a PMSG using a traditional cont…

TRACE Code Analyses for the IAEA ICSP on “Integral PWR Design Natural Circulation Flow Stability and Thermo-Hydraulic Coupling of Containment and Pri…

2011

Considering the world energy demand increase in order to fulfill an environmental and economic sustainability, the energy policy of each country has to diversify the sources of energy and use stable, safe energy production option able of producing electricity in a clean way contributing in cutting the CO2 emission. In the framework of the sustainable development, today the use of advanced nuclear power plant, have an important role in the environmental and economic sustainability of country energy strategy. In the last 20 years, in fact, the international community, taking into account the operational experience of the nuclear reactors, starts the development of new advanced reactor designs…

Analyses of the OSU-MASLWR Experimental Test Facility

2012

Today, considering the sustainability of the nuclear technology in the energy mix policy of developing and developed countries, the international community starts the development of new advanced reactor designs. In this framework, Oregon State University (OSU) has constructed, a system level test facility to examine natural circulation phenomena of importance to multi-application small light water reactor (MASLWR) design, a small modular pressurized water reactor (PWR), relying on natural circulation during both steady-state and transient operation. The target of this paper is to give a review of the main characteristics of the experimental facility, to analyse the main phenomena characteri…

Grafting of Hindered Phenol Groups onto Ethylene/α-Olefin Copolymer by Nitroxide Radical Coupling

2017

The covalent immobilization of hindered phenol groups, with potential antioxidant activity, onto an ethylene/α-olefin (EOC) copolymer was carried out by the nitroxide radical coupling (NRC) reaction performed in the melt with a peroxide and the 3,5-di-tert-butyl-4-hydroxybenzoyl-2,2,6,6-tetramethylpiperidine-1-oxyl radical (BHB-T). Functionalized EOC (EOC-g-(BHB-T)) was exposed to photo- and thermo-oxidation. By comparison with some model compounds bearing the (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) moiety or the hindered phenol unit, it was observed that the grafted BHB-T could effectively help the stabilization of the polymer matrix both under photo- and thermo-oxidation. In addit…

Observation of Geometric Parametric Instability Induced by the Periodic Spatial Self-Imaging of Multimode Waves

2016

Spatio-temporal mode coupling in highly multimode physical systems permits new routes for exploring complex instabilities and forming coherent wave structures. We present here the first experimental demonstration of multiple geometric parametric instability sidebands, generated in the frequency domain through resonant space-time coupling, owing to the natural periodic spatial self-imaging of a multimode quasi-continuous-wave beam in a standard graded-index multimode fiber. The input beam was launched in the fiber by means of an amplified microchip laser emitting sub-nanosecond pulses at 1064 nm. The experimentally observed frequency spacing among sidebands agrees well with analytical predic…