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El proyecto mapa escolar de Valencia: Análisis de la zonificación educativa de la ciudad de Valencia
2018
The research project Mapa Escolar de Valencia (School Map of Valencia) was born out of an agreement between the City Council and the University of Valencia in order to carry out an investigation of the compulsory education system of the city and propose, if necessary, modifications to the current school zoning. The project is structured in several research areas. An analysis of the specialized scientific literature and public policies concerning education and schooling has been done, and it is currently analysing the evolution of quantitative and qualitative data on compulsory schooling in Valencia, its school zoning, the representations of education and the school climate in the city schoo…
The "Historia de la doncella Teodor" in Burgos’ Printing Press: Regarding a New Edition from Juan de Junta’s Workshop, c. 1535-1540
2020
En este trabajo se da noticia y se lleva a cabo el estudio tipobibliográfico de una edición sine notis de la Historia de la doncella Teodor. El análisis permite identificar la impresión en Burgos en el taller de Juan de Junta, c. 1535-1540. El rasgo material que singulariza este impreso es que la última hoja del primer cuaderno ha sido remedada por una copia manuscrita que no solo reproduce la tipografía original, sino también, a plumilla, las estampas. El estudio textual e iconográfico nos permitirá identificar la fuente del folio contrahecho.
Dioxygen reduction by cobalt(II) octaethylporphyrin at liquid|liquid interfaces.
2010
Oxygen reduction catalyzed by cobalt(II) (2,3,7,8,12,13,17,18-octaethylporphyrin) [Co(OEP)] at soft interfaces is studied by voltammetry and biphasic reactions. When Co(OEP) is present in a solution of 1,2-dichloroethane in contact with an aqueous acidic solution, oxygen is reduced if the interface is positively polarized (water phase versus organic phase). This reduction reaction is facilitated when an additional electron donor, here ferrocene, is present in excess in the organic phase.
Midinfrared FT-IR as a Tool for Monitoring Herbaceous Biomass Composition and Its Conversion to Furfural
2015
A semiquantitative analysis by means of midinfrared FT-IR spectroscopy was tuned for the simultaneous determination of cellulose, hemicellulose, and lignin in industrial crops such as giant reed (Arundo donaxL.) and switchgrass (Panicum virgatumL.). Ternary mixtures of pure cellulose, hemicellulose, and lignin were prepared and a direct correlation area/concentration was achieved for cellulose and lignin, whereas indirect correlations were found for hemicellulose quantification. Good correspondences between the values derived from our model and those reported in the literature or obtained according to the official Van Soest method were ascertained. Average contents of 40–45% of cellulose, 2…
Arundo Donax particles as reinforcement for PLA based composites
2015
Aim of this work was to use particles obtained by grinding the culms of Arundo Donax used as reinforcement for PLA based composites. The influence of the content (10 wt% and 20 wt%) and size (150-300 μm and 300-500 μm) of Arundo Donax filler (ADF) on the morphology and on the properties of PLA-ADF composites was evaluated. The composites were prepared by melt compounding the PLA with ADF using a co-rotating modular twin screw extruder. For comparison, neat PLA was processed under the same conditions. Both the neat PLA and the composites were characterized by SEM, DSC, tensile and flexural measurements.
Lista de los libros legados en su último testamento por el Dr. D. Francisco Asensi, Catedrático y Vice-Rector que fue de la Vniversidad literaria de …
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Glycosyl azides as building blocks in convergent syntheses of oligomeric lactosamine and Lewisx saccharides
1997
Abstract Oligosaccharides containing type 2 lactosamine repeating units, e.g. neo-lacto-octaose and trimeric Lewis x derivatives, are constructed using neo-lactosamine azide building blocks. The azido group provides a favorable protection of the anomeric position which is stable to versatile protecting group manipulations and glycosylation reactions. On the other hand, glycosyl azides can be converted into glycosyl fluorides via a 1,3-dipolar cycloaddition with di- tert -butyl-acetylenedicar☐ylate and subsequent treatment of the resulting N -glycosyl triazoles with hydrogen fluoride-pyridine complex. Activation of the lactosamine fluorides with Lewis acids affords the possibility to extend …
A new method of anomeric protection and activation based on the conversion of glycosyl azides into glycosyl fluorides
1993
Glycosyl azides provide reliable anomeric protection stable to conditions for hydrolytic removal of ester groups, for reductive opening or release of acetalic diol protection, for the introduction of ether-type protection, and for glycosylation processes. The utility of this anomeric protection is further enhanced as glycosyl azides may be converted into glycosyl fluorides, which can be activated for glycosylation reactions. To this end, glycosyl azides have been subjected to 1,3-dipolar cycloaddition with di-tert-butyl acetylenedicarboxylate. On treatment with hydrogen fluoride-pyridine complex the N-glycosyl triazole derivatives directly give glycosyl fluorides.
Acene-type donors bearing one 1,3-dithiole ring
1999
Abstract A series of acene-type donors bearing only one 1,3-dithiole ring have been synthesized by following a Wittig-Horner reaction from 7 H -benz[ d,e ]anthracen-7-one and several phosphonate esters. The excellent donor properties have been studied using both experimental techniques and quantum-chemical calculations and reveal that the extraction of the first electron in the oxidation process occurs from the dithiole ring (0.42 e) and the acene unit (0.58 e).
Nota de los libros qe. en su testamento legó á la Rl. Universidad Literaria de Valencia el Sor. D. Matias Beltran
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