Search results for " engineering"
showing 10 items of 38291 documents
Controlling the crystal growth of potassium iodide with a 1,1'-bis(pyridin-4-ylmethyl)-2,2'-biimidazole ligand (L) – formation of a linear [K4I4L4]n …
2018
The crystal growth of potassium iodide was controlled by using the neutral organic 1,1′-bis(pyridin-4-ylmethyl)-2,2′-biimidazole (L) ligand as a modifier. The selected modifier allows the preservation of original cubic [K4I4] units and their arrangement into a linear ligand-supported 1D chain. The supported [K4I4] cubes are only slightly distorted compared to the cubes found in pure KI salt. The N–K binding of the ligand to the KI salt, as well as weak I⋯H, N⋯H, and N⋯I interactions, stabilizes the structure to create a unique 1D polymer of neutral potassium iodide ionic salt inside the [K4I4L4]n complex.
Frozen or dynamic? : An atomistic simulation perspective on the timescales of electrochemical reactions
2023
Electrochemical systems span a wide range of timescales, and several recent works have put forth the idea that the reaction environment should remain frozen and out of equilibrium during electrochemical electron or proton transfer reactions. Furthermore, simplified treatments of the electrochemical interface model the solvent and ions as frozen molecules. However, the claims and practices of a frozen environment strongly clash with most theoretical and simulation approaches developed to study electrochemical reaction rates. It has also been suggested that the electrode potential should not be fixed when simulating reaction rates due to conductivity limitations, which indicates constant pote…
Ehdotus ihmistä suhteellistavaksi sanastoksi
2021
”Ehdotus ihmistä suhteellistavaksi sanastoksi” käsittelee ja esittelee teoriasuuntausta, joka tunnetaan ”posthumanistisena”, keskittyen erityisesti sen käsitteisiin ja termeihin. Posthumanistinen ajattelu pyrkii käsitteelliseen uudistamiseen, jotta tunnistaisimme paremmin ne suhteellisuudet, joiden varassa ja lomassa ihmisten elämä ja merkitykset muotoutuvat – ja ne historiat, joissa ihminen on muotoutunut erilliseksi. Ehdotamme sanastoa, joka suhteellistaa juuri tätä käsitteellistä, kartesiolaisen humanismin ihmistä. Yhtäältä seuraamme käsitteellisen ajattelun muotoutumista erilaisten kontekstien paineissa, toisaalta pysähdymme tarkastelemaan tiettyjä, työskentelyssämme tärkeitä käsitteitä…
Nonlinear Absorption and Refraction of Picosecond and Femtosecond Pulses in HgTe Quantum Dot Films
2021
We report measurements of the saturated intensities, saturable absorption, and nonlinear refraction in 70-nm thick films containing 4 nm HgTe quantum dots. We demonstrate strong nonlinear refraction and saturable absorption in the thin films using tunable picosecond and femtosecond pulses. Studies were carried out using tunable laser pulses in the range of 400–1100 nm. A significant variation of the nonlinear refraction along this spectral range was demonstrated. The maximal values of the nonlinear absorption coefficients and nonlinear refractive indices determined within the studied wavelength range were −2.4 × 10−5 cm2 W−1 (in the case of 28 ps, 700 nm probe pulses) and −3 × 10−9 cm2 W−1 …
Développement, optimisation et utilisation d'un simulateur de mastication "bouche artificielle"
2009
National audience
Why Use Interactive Multi-Objective Optimization in Chemical Process Design?
2008
Problems in chemical engineering, like most real-world optimization problems, typically, have several conflicting performance criteria or objectives and they often are computationally demanding, which sets special requirements on the optimization methods used. In this chapter, we point out some shortcomings of some widely used basic methods of multi-objective optimization. As an alternative, we suggest using interactive approaches where the role of a decision maker or a designer is emphasized. Interactive multi-objective optimization has been shown to suit well for chemical process design problems because it takes the preferences of the decision maker into account in an iterative manner tha…
Psychrophiles: A source of cold-adapted enzymes for energy efficient biotechnological industrial processes
2021
Biocatalysts are the backbone of bioprocessing industries that are going through a phase of transition with reference to the requirement of extraordinary enzymes for various biochemical processes. This transition is well reported and documented by various researchers through elucidation of different features and applications of mesophilic and thermophilic enzymes. However, there is little information available about psychrophilic enzymes and their involvement in industrial processes. Therefore, understanding the features and functions of psychrophilic enzymes could suggest some of their novel applications in various industries such as food, agriculture, chemicals, pharmaceuticals, and waste…
ESTIMATION ET CORRECTION DES ERREURS SYSTEMATIQUES D'UN SYSTEME DE MESURE 3D ASSOCIANT SCANNER NAPPE LASER ET MMT
2012
Les techniques de mesure sans contact par scanning laser permettent d'acquérir un grand nombre de points, à une cadence très rapide. Elles sont de plus en plus utilisées pour des applications industrielles telles que la rétro-conception, le contrôle de forme,... Toutefois, les incertitudes de mesures sont plus importantes que celles obtenues par les techniques classiques de mesure par contact. Nous proposons une procédure de correction des erreurs systématiques basée sur démarche expérimentale et qui concerne la mesure de pièces présentant une surface mate (peu de présence de bruit spéculaire). Les paramètres retenus dans la procédure sont les paramètres de positionnement du capteur par rap…
Experimental Observation of a Large Low-Frequency Band Gap in a Polymer Waveguide
2018
The quest for large and low-frequency band gaps is one of the principal objectives pursued in a number of engineering applications, ranging from noise absorption to vibration control, and to seismic wave abatement. For this purpose, a plethora of complex architectures (including multiphase materials) and multiphysics approaches have been proposed in the past, often involving difficulties in their practical realization. To address the issue of proposing a material design that enables large band gaps using a simple configuration, in this study we propose an easy-to-manufacture design able to open large, low-frequency complete Lamb band gaps exploiting a suitable arrangement of masses and stif…
The influence of distractors on olfactory identification ability in schizophrenia patients and controls: relationships to negative symptomatology
2010
International audience