Search results for " kinetic"
showing 10 items of 416 documents
Approach Matters : The Kinetics of Interfacial Inverse-Electron Demand Diels-Alder Reactions
2017
Rapid and quantitative click functionalization of surfaces remains an interesting challenge in surface chemistry. In this regard, inverse electron demand Diels Alder (IEDDA) reactions represent a promising metal-free candidate. Herein, we reveal quantitative surface functionalization within 15 min. Furthermore, we report the comprehensive effects of substrate stereochemistry, surrounding microenvironment and substrate order on the reaction kinetics as obtained via a combination of XPS and surface-bound mass spectrometry (DART-MS).
Coadsorption of NRR and HER Intermediates Determines the Performance of Ru-N4 toward Electrocatalytic N2 Reduction
2021
Efficiency of the electrochemical N2 reduction reaction (NRR) to ammonia is seriously limited by the competing hydrogen evolution reaction (HER) but our current atomic-scale insight on the factors controlling HER/NRR competition are unknown. Herein we unveil the elementary mechanism, thermodynamics, and kinetics determining the HER/NRR selectivity on the state-of-the-art NRR electrocatalyst, Ru-N4 using constant potential density functional theory calculations (DFT). The calculations show that NRR and HER intermediates coadsorb on the catalyst where HER is greatly suppressed by the NRR intermediates. The first reaction step leading to either *NNH or *H determines the selectivity towards NRR…
Sex steroids, carcinogenesis, and cancer progression
2004
The relationship between sex steroids and cancer has been studied for more than a century. Using an original intact cell analysis, we investigated sex steroid metabolism in a panel of human cancer cell lines, either hormone responsive or unresponsive, originating from human breast, endometrium, and prostate. We found that highly divergent patterns of steroid metabolism exist and that the catalytic preference (predominantly reductive or oxidative) is strictly associated with the steroid receptor status of cells. We explored intra-tissue concentrations and profiles of estrogens in a set of human breast tumors as compared to normal mammary tissues, also in relation to their estrogen receptor s…
Field- and irradiation-induced phenomena in memristive nanomaterials
2016
The breakthrough in electronics and information technology is anticipated by the development of emerging memory and logic devices, artificial neural networks and brain-inspired systems on the basis of memristive nano-materials represented, in a particular case, by a simple 'metal-insulator-metal' (MIM) thin-film structure. The present article is focused on the comparative analysis of MIM devices based on oxides with dominating ionic (ZrOx, HfOx) and covalent (SiOx, GeOx) bonding of various composition and geometry deposited by magnetron sputtering. The studied memristive devices demonstrate reproducible change in their resistance (resistive switching - RS) originated from the formation and …
Effect of the pacing strategy during half-duration resistance test on the mechanic, metabolic and cardio-respiratory response
2017
Objective: Changes in pacing rhythm are translated into functional and metabolic changes that can be significantly reflected in the final results of an athlete. Method: Ten male subjects, with moderate performance level (age: 25.2 ± 2.2 years; VO2max: 56.9 ± 5.7 ml kgâ1 minâ1), performed four 5-min races with different pacing strategies: constant-pace (CP), record-pace (RP), kicker-pace (KP), incremental-pace (IP). Results: The cardio-respiratory response did not show statistically significant. There were statistically significant differences (p â¤Â 0.05) in the energetic efficiency among the protocols CP vs. RP, CP vs. KP and RP vs. IP. When results were analyzed by partials (1-m…
Lateral reorganization of plasma membrane is involved in the yeast resistance to severe dehydration
2010
International audience; In this study, we investigated the kinetic and the magnitude of dehydrations on yeast plasma membrane (PM) modifications because this parameter is crucial to cell survival. Functional (permeability) and structural (morphology, ultrastructure, and distribution of the protein Sur7-GFP contained in sterol-rich membrane microdomains) PM modifications were investigated by confocal and electron microscopy after progressive (non-lethal) and rapid (lethal) hyperosmotic perturbations. Rapid cell dehydration induced the formation of many PM invaginations followed by membrane internalization of low sterol content PM regions with time. Permeabilization of the plasma membrane occ…
Characterizing rainfall erosivity by kinetic power-Median volume diameter relationship
2018
Abstract Kinetic power, i.e. kinetic energy per unit time and area, is the variable widely used to represent the rainfall erosivity which affects soil loss and sediment yield. This paper shows the results of an experimental investigation using the raindrop size distributions (DSDs) measured by an optical disdrometer installed at the Department of Agricultural, Food and Forestry Sciences of University of Palermo in Italy (June 2006–March 2014) and at the El Teularet experimental station in Spain (July 2015–May 2016). At first an analysis of the DSDs aggregated into intensity classes is carried out, then the measured kinetic power values are determined. The aggregated DSDs allowed to establis…
Existence of a traveling wave solution in a free interface problem with fractional order kinetics
2021
Abstract In this paper we consider a system of two reaction-diffusion equations that models diffusional-thermal combustion with stepwise ignition-temperature kinetics and fractional reaction order 0 α 1 . We turn the free interface problem into a scalar free boundary problem coupled with an integral equation. The main intermediary step is to reduce the scalar problem to the study of a non-Lipschitz vector field in dimension 2. The latter is treated by qualitative topological methods based on the Poincare-Bendixson Theorem. The phase portrait is determined and the existence of a stable manifold at the origin is proved. A significant result is that the settling time to reach the origin is fin…
Verifica delle equazioni disponibili per la stima della potenza cinetica delle precipitazioni naturali
2016
Nella memoria sono riportati i risultati delle indagini condotte utilizzando le distribuzioni dimensionali delle gocce di pioggia (DSD) rilevate mediante un disdrometro ottico installato, nel periodo Giugno 2006 - Marzo 2014, presso il Dipartimento di Scienze Agrarie e Forestali dell’Università degli Studi di Palermo e nel periodo Luglio 2015-Gennaio 2016 presso la stazione sperimentale di El Teularet in Spagna. Dopo aver aggregato le DSD per classi di intensità differenti in ampiezza, è stata determinata la potenza cinetica associando a ciascun diametro della DSD aggregata la relativa velocità di caduta calcolata mediante una relazione reperita in letteratura. I valori di potenza cinetica …