Search results for " monolayer"
showing 10 items of 63 documents
Illumination-related pattern formations in lipid monolayers
1995
We report on the phenomenon that in the two phase coexistence region (LC-LE) of a lipid monolayer film the fractal-like solid domains may grow simply by continuous illumination of a fluorescence microscope. The mechanism of this 2D domain growth is discussed. This phenomenon gives insight into the two-dimensional ramified crystallization in monolayers.
Cluster growth with long-range interactions
1996
Abstract Growth models in which the morphology depends on interactions of the type V(r) = C r n are presented. The growth algorithms are generalizations of DLA. The particles diffuse on a triangular lattice and eventually either stick to the cluster or are lost. Several processes are simulated in this way: in one case only pure sticking is taken into account, in another case evaporation and rearrangement are also allowed to occur. In the former case (with attractive interactions) the clusters exhibit a highly symmetric shape (a sixfold star) whose detailed structure depends on n , C kT , and time. In the latter case (studied with repulsive dipolar interactions) the tendency to ramification …
Bioinspired catechol-terminated self-assembled monolayers with enhanced adhesion properties
2013
The role of the catechol moiety in the adhesive properties of mussel proteins and related synthetic materials has been extensively studied in the last years but still remains elusive. Here, a simplified model approach is presented based on a self-assembled monolayer (SAM) of upward-facing catechols thiol-bound to epitaxial gold substrates. The orientation of the catechol moieties is confirmed by spectroscopy, which also showed lack of significant amounts of interfering o-quinones. Local force-distance curves on the SAM measured by atomic force microscopy (AFM) shows an average adhesion force of 45 nN, stronger than that of a reference polydopamine coating, along with higher reproducibility …
Carbohydrate-Mediated Biomolecular Recognition and Gating of Synthetic Ion Channels
2013
Nanochannel-based biosensing devices have been proposed for selective detection of protein analyte molecules. However, the design and miniaturization of reusable channel-based biosensors is still a challenge in nanoscience and biotechnology. We present here a reusable nanofluidic biosensor based on reversible lectin-carbohydrate interactions. The nanochannels are fabricated in heavy ion tracked polymer membranes. The channel walls are functionalized with p-aminophenyl alpha-D-mannopyranoside (APMP) monolayers through carbodiimide coupling chemistry. The chemical (mannopyranoside) groups on the inner channel walls serve as binding sites and interact with specific protein molecules. The bindi…
Protein diffusion through charged nanopores with different radii at low ionic strength
2014
[EN] The diffusion of two similar molecular weight proteins, bovine serum albumin (BSA) and bovine haemoglobin (BHb), through nanoporous charged membranes with a wide range of pore radii is studied at low ionic strength. The effects of the solution pH and the membrane pore diameter on the pore permeability allow quantifying the electrostatic interaction between the chargedpore and the protein. Because of the large screening Debye length, both surface and bulk diffusion occur simultaneously. By increasing the pore diameter, the permeability tends to the bulk self-diffusion coefficient for each protein. By decreasing the pore diameter, the charges on the pore surface electrostatically hinder …
Modulating the luminance of organic light-emitting diodes via optical stimulation of a photochromic molecular monolayer at transparent oxide electrode
2020
Nanoscale 12(9), 5444-5451 (2020). doi:10.1039/D0NR00724B
Effect of self-assembled surfactant structures on ion transport across the liquid|liquid interface
1999
In this paper, the effect of a coadsorbed polyanion–cationic surfactant system on the transport of tetraethylammonium ion across the water|1,2-dichloroethane interface is studied. It is shown that the change in double-layer structure due to the presence of adsorbed or coadsorbed surfactant can explain the experimental observations, thus concluding that no other effects on ion transfer (e.g., steric hindrance) are relevant under these experimental conditions. The implications of these results are discussed. Keywords: ITIES, Ion transfer, Self-assembled monolayers, Surfactants, Double-layer effects
Surface functionalization and surface recognition: Plasmon optical detection of molecular recognition at self assembled monolayers
1991
The synthesis of biotin- functionalized organic mercaptans and their chemisorption on gold surfaces is described. Biotin bound covalently to self assembled monolayers is recognized by streptavidin from aqueous buffer solutions. Spacer length and packing density of the biotin labels on the organic surface determine the docking kinetics. With a flexible and hydrophilic spacer very fast -diffusion controlled-docking is observed. As an alternative method of self assembly the spreading of organic mercaptans on water surfaces is established. Pressure-area diagrams of different functionalized mercaptans and disulfides are shown and their monolayer properties are discussed.
Crystallization of SrCO3 on a self-assembled monolayer substrate: an in-situ synchrotron X-ray study
2001
Self-assembled monolayers (SAMs) of alkanethiols on gold surfaces show great promise in controlling the nucleation and growth of inorganic minerals from solution. In doing so, they mimic the role of some biogenic macromolecules in natural biomineralisation processes. Crystallization on SAM surfaces is usually monitored ex-situ; by allowing the process to commence and to evolve for some time, removing the substrate from the mother solution, and then examining it using microscopy, diffraction etc. We present here for the first time, the use of high energy monochromatic synchrotron X-radiation in conjunction with a two dimensional detector to monitor in situ, in a time resolved fashion, the gr…
Templated Crystallisation of Calcium and Strontium Carbonates on Centred Rectangular Self-Assembled Monolayer Substrates
1998
SrCO3crystals display patterns of templating when grown on tailored self-assembled monolayers (right). As SrCO3 is isostructural with aragonite, comparison of the crystallisation of SrCO3 in the aragonite/strontianite modification with the crystallisation of CaCO3 in all three modifications might yield some insights into which factors are important for crystal growth.