Search results for " spectrum"

showing 10 items of 1439 documents

Laser-Induced Plasma Emission Spectrometric Study of Pigments and Binders in Paper Coatings:  Matrix Effects

1998

Laser-induced plasma emission spectroscopy (LIPS) has been used to study inorganic pigment and organic binder distributions in paper coatings, which are inhomogeneous and porous materials. The plasma was generated by focusing a pulsed XeCl excimer laser beam (diameter 100 μm, irradiance 0.3 GW/cm2) on the sample surface at atmospheric pressure. A gated intensified CCD detector was used to record time-delayed emission spectra. Linear correlations between the LIPS signals and the coat weight and the binder content of the coatings studied were obtained. Emission line intensities from ionic and neutral magnesium atoms were used to evaluate plasma temperature corrections in determining silicon a…

Coated paperArgonExcimer laserAtmospheric pressureSiliconmedicine.medical_treatmentAnalytical chemistrychemistry.chemical_elementPlasmaLaserAnalytical Chemistrylaw.inventionchemistrylawmedicineEmission spectrumAnalytical Chemistry
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The fragmentation of 5- and 3-substituted thiophene-2-carboxamides under electron impact

1980

The 70 eV electron impact mass spectra of twelve 5- and 3-substituted thiophene-2-carboxamides are discussed with the aid of exact mass measurements and labelling experiments. All mass spectra exhibit pronounced molecular ions. Some isomeric 5- and 3-substituted title compounds can be differentiated by mass spectrometry. The fragmentation is influenced by a strong ‘ortho-effect’ which activates the NH3 elimination. In the other cases the most important fragmentation is NH2˙ loss, followed by CO elimination.

Collision-induced dissociationAnalytical chemistryPhotochemistryMass spectrometryBiochemistryIonMasschemistry.chemical_compoundchemistryFragmentation (mass spectrometry)Mass spectrumThiopheneMolecular MedicineInstrumentationSpectroscopyElectron ionizationOrganic Mass Spectrometry
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Studies in organic mass spectrometry. Part 17—Formation of phenol radical ions by rearrangement of the molecular ions of someN-arylthiophenecarboxami…

1995

It has been shown by exact mass measurements and collision-induced dissociation mass-analysed ion kinetic energy spectra that the structure of the m/z 124 ion observed in the mass spectra of N-(4-methoxyphenyl)thiophene-2-carboxamide, N-(4-methoxyphenyl)thiophene-3-carboxamide, N-(4-methoxyphenyl)-5-nitrothiophene-3-carboxamide and N-(4-methoxyphenyl)benzamide is identical with that of the molecular ion of 4-methoxyphenol. This ion becomes abundant in metastable energy window reactions. A probable mechanism for its formation is discussed.

Collision-induced dissociationChemistryPolyatomic ionMass spectrumAnalytical chemistryFast atom bombardmentMass spectrometryTandem mass spectrometryPhotochemistrySpectroscopyIon sourceIonJournal of Mass Spectrometry
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Antimonic acid hydrate xerogels as proton electrolytes

1993

Abstract Two high stability types of protonic solid electrolytes based on antimonic acid hydrate xerogels have been obtained by the sol-gel technique: Sb 2 O 5 ·(3–4)H 2 O (colloidal) and Sb 2 O 5 ·5H 2 O (polymeric). The first one is a white compact material with conductivity 0.40 mS/cm (298 K) for n =3.7. The last one is transparent for visible light with a conductivity of 0.80 mS/cm. An electrochromic system based on the colloidal gel electrolyte in the form of paste has good performance-more than 10 7 cycles and a lifetime of more than five years.

ColloidMaterials scienceProtonElectrochromismInorganic chemistryFast ion conductorGeneral Materials ScienceGeneral ChemistryElectrolyteConductivityCondensed Matter PhysicsHydrateVisible spectrumSolid State Ionics
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Parenting Stress in Families of Children with Autism Spectrum Disorder and ADHD

2015

The purpose of this study was to compare the parenting stress experienced by parents of 121 children from 5 to 9 years old with autism spectrum disorder (ASD), attention deficit/hyperactivity disorder (ADHD), comorbid ASD+ADHD, and typical development in different domains related to child and parent characteristics using the Parenting Stress Index. The three clinical groups presented greater perceived parenting stress than did the comparison group (CG). The ADHD group obtained higher levels of parenting stress related to attachment and depression than did the other groups. The ASD+ADHD group presented a unique profile of differences from the CG on Health and Spouse subscales. Results highl…

Comparison Group (CG)Health and Spouse subscalesAttention Deficit/hyperactivity Disorder (ADHD)Parenting stressmedicine.diseaseChildren from 5 to 9 years oldComorbiditybehavioral disciplines and activitiesEducationDevelopmental psychologyAutism Spectrum Disorder (ASD)Parenting stressSpouseAutism spectrum disorderIntervention (counseling)mental disordersDevelopmental and Educational PsychologymedicineAttention deficit hyperactivity disorderAutismPsychologyDepression (differential diagnoses)Clinical psychology
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Anaphor Processing During Reading Comprehension in Students With Autism Spectrum Disorder

2021

With the purpose of promoting academic inclusion, it is essential for educators to understand the nature underlying poor reading comprehension in children with Autism Spectrum Disorder (ASD). In th...

ComprehensionLinguistics and LanguagePoor readingReading comprehensionAutism spectrum disordermental disordersmedicinePsychologymedicine.diseasebehavioral disciplines and activitiesInclusion (education)EducationDevelopmental psychologyReading & Writing Quarterly
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On the Fučík spectrum of the p-Laplacian with no-flux boundary condition

2023

In this paper, we study the quasilinear elliptic problem \begin{align*} \begin{aligned} -\Delta_{p} u&= a\l(u^+\r)^{p-1}-b\l(u^-\r)^{p-1} \quad && \text{in } \Omega,\\ u & = \text{constant} &&\text{on } \partial\Omega,\\ 0&=\int_{\partial \Omega}\left|\nabla u\right|^{p-2}\nabla u\cdot \nu \,\diff \sigma,&& \end{aligned} \end{align*} where the operator is the $p$-Laplacian and the boundary condition is of type no-flux. In particular, we consider the Fu\v{c}\'{\i}k spectrum of the $p$-Laplacian with no-flux boundary condition which is defined as the set $\fucik$ of all pairs $(a,b)\in\R^2$ such that the problem above has a nontrivial solution. It turns out…

Computational MathematicsApplied MathematicsGeneral EngineeringGeneral MedicineEigenvalue problem first nontrivial curve Fucik spectrum no-flux boundary condition p-Laplace differential operatorGeneral Economics Econometrics and FinanceAnalysis
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Customization Support in Computer-Based Technologies for Autism: A Systematic Mapping Study

2020

Autism Spectrum Disorder (ASD) is a neurodevelopmental condition characterized by social interaction and communication difficulties, along with narrow and repetitive interests. Being a spectrum dis...

Computer science05 social sciencesComputer basedHuman Factors and Ergonomics02 engineering and technologymedicine.diseaseSocial relationComputer Science ApplicationsPersonalizationHuman-Computer InteractionHuman–computer interactionAutism spectrum disorder020204 information systems0202 electrical engineering electronic engineering information engineeringmedicineAutism0501 psychology and cognitive sciencesSystematic mapping050107 human factorsInternational Journal of Human–Computer Interaction
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Enhancing HSUPA system level performance with dual carrier capability

2010

The purpose of this paper is to analyze how dual carrier capability can enhance High Speed Uplink Packet Access performance in comparison to using only single carrier. Dual carrier operation gives the User Equipment the possibility to transmit simultaneously using two 5 MHz bands, theoretically doubling the peak data rates and user throughput. The analysis is conducted with a system level simulation tool. This paper first indicates with single carrier simulations that, especially in small cells, terminals have spare power available for dual carrier operation. These observations are verified with dual carrier simulations by showing that the burst throughput can be practically doubled. In the…

Computer scienceCode division multiple accessbusiness.industryComputerSystemsOrganization_COMPUTER-COMMUNICATIONNETWORKSSystem-level simulationData_CODINGANDINFORMATIONTHEORYInterference (wave propagation)Electronic mailSpread spectrumUser equipmentElectronic engineeringFadingbusinessThroughput (business)Computer networkIEEE 5th International Symposium on Wireless Pervasive Computing 2010
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Boolean Networks: A Primer

2021

Abstract Autism Spectrum Disorders (ASDs) stand out as a relevant example where omics-data approaches have been extensively and successfully employed. For instance, an outstanding outcome of the Autism Genome Project relies in the identification of biomarkers and the mapping of biological processes potentially implicated in ASDs’ pathogenesis. Several of these mapped processes are related to molecular and cellular events (e.g., synaptogenesis and synapse function, axon growth and guidance, etc.) that are required for the development of a correct neuronal connectivity. Interestingly, these data are consistent with results of brain imaging studies of some patients. Despite these remarkable pr…

Computer scienceIn silicoAttractor Autism spectrum disorders (ASDs) Axon guidance Basin of attraction Boolean network BoolNet Computational model Copy number variants (CNVs) Growth cone In silico mutagenesis Mutations Neurodevelopmental disorders Systems biologyGenome projectComputational biologyGene mutationmedicine.diseasePhenotypeEndophenotypemental disordersmedicineAutismIdentification (biology)Function (biology)
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