Search results for " symmetry"
showing 10 items of 701 documents
The crystal structure of 3,5-diisopropyl-4-nitropyrazole from X-ray powder diffraction data
2001
The crystal structure of 3,5-diisopropyl-4-nitropyrazole, 3c, has been determined by a Patterson Search method from laboratory X-ray powder diffraction data. The crystal data are: monoclinic symmetry with the unit-cell parameters aa 19:530O5U; ba 6:485O1U and ca 17:937O3U A; ba 100:32O1U8; space group I2/a ,C 9H15N3O2, Za 8, 293 K. After indexing the powder pattern by two methods, the unit-cell parameters found were refined by a least-squares technique. A whole pattern- fitting program was used to extract the integrated intensities. The structure was solved taking a related compound as a search model and the final Rietveld refinement converged to Rwpa 0.1971 and Rpa 0.1437. The structure pr…
Exploring the atomic structure of 1.8 nm monolayer-protected gold clusters with aberration-corrected STEM
2017
Abstract Monolayer-protected (MP) Au clusters present attractive quantum systems with a range of potential applications e.g. in catalysis. Knowledge of the atomic structure is needed to obtain a full understanding of their intriguing physical and chemical properties. Here we employed aberration-corrected scanning transmission electron microscopy (ac-STEM), combined with multislice simulations, to make a round-robin investigation of the atomic structure of chemically synthesised clusters with nominal composition Au 144 (SCH 2 CH 2 Ph) 60 provided by two different research groups. The MP Au clusters were “weighed” by the atom counting method, based on their integrated intensities in the high …
Mutilation of RNA phage Qβ virus-like particles: from icosahedrons to rods
2000
Icosahedral virus-like particles (VLPs) of RNA phage Qbeta are stabilized by four disulfide bonds of cysteine residues 74 and 80 within the loop between beta-strands F and G (FG loop) of the monomeric subunits, which determine the five-fold and quasi-six-fold symmetry contacts of the VLPs. In order to reduce the stability of Qbeta VLPs, we mutationally converted the amino acid stretch 76-ANGSCD-81 within the FG loop into the 76-VGGVEL-81 sequence. It led to production in Escherichia coli cells of aberrant rod-like Qbeta VLPs, along with normal icosahedral capsids. The length of the rod-like particles exceeded 4-30 times the diameter of icosahedral Qbeta VLPs.
The origin of in-plane stresses in axially moving orthotropic continua
2016
In this paper, we address the problem of the origin of in-plane stresses in continuous, two-dimensional high-speed webs. In the case of thin, slender webs, a typical modeling approach is the application of a stationary in-plane model, without considering the effects of the in-plane velocity field. However, for high-speed webs this approach is insufficient, because it neglects the coupling between the total material velocity and the deformation experienced by the material. By using a mixed Lagrange–Euler approach in model derivation, the solid continuum problem can be transformed into a solid continuum flow problem. Mass conservation in the flow problem, and the behaviour of free edges in th…
From hybrid to quadratic inflation with high-scale supersymmetry breaking
2014
Motivated by the reported discovery of inflationary gravity waves by the BICEP2 experiment, we propose an inflationary scenario in supergravity, based on the standard superpotential used in hybrid inflation. The new model yields a tensor-to-scalar ratio r ~ 0.14 and scalar spectral index ns ~ 0.964, corresponding to quadratic (chaotic) inflation. The important new ingredients are the high-scale, (1.6-10) x 10^13 GeV, soft supersymmetry breaking mass for the gauge singlet inflaton field and a shift symmetry imposed on the K\"ahler potential. The end of inflation is accompanied, as in the earlier hybrid inflation models, by the breaking of a gauge symmetry at (1.2-7.1) x 10^16 GeV, comparable…
Upper bound on the tensor-to-scalar ratio in GUT-scale supersymmetric hybrid inflation
2014
We explore the upper bound on the tensor-to-scalar ratio r in supersymmetric (F-term) hybrid inflation models with the gauge symmetry breaking scale set equal to the value 2.86⋅1016 GeV2.86⋅1016 GeV, as dictated by the unification of the MSSM gauge couplings. We employ a unique renormalizable superpotential and a quasi-canonical Kähler potential, and the scalar spectral index nsns is required to lie within the two-sigma interval from the central value found by the Planck satellite. In a sizable region of the parameter space the potential along the inflationary trajectory is a monotonically increasing function of the inflaton, and for this case, r≲2.9⋅10−4r≲2.9⋅10−4, while the spectral index…
Infrared and quantum-chemical studies of the structure and vibrations of methyldisilylamine
2002
Abstract Infrared spectra are reported from labelled species of methyldisilylamine (N(CH 3 )(SiH 3 ) 2 ) in the gas and solid phase. Quantum-chemical (QC) calculations of structure and force field have been carried out at HF, MP2 and B3LYP levels using 6-31G ∗ and 6-311G ∗∗ basis sets. The equilibrium structure belongs to the point group C s with the plane of symmetry at right angles to the NSi 2 angle and a slight non-planarity of the CNSi 2 moiety ( C s ,⊥ ). Spectra in the ν SiH region however suggest an effective C 2 v structure, with two distinct types of SiH bond. Two strong SiH bonds lie in the skeletal plane, eclipsing each other. The single ν is CH band in the CHD 2 species suggest…
Structural characterization and magnetic property studies of a mixed-valence {CoIIICoII4} complex with a μ4-oxo tetrahedral {CoII4} motif
2020
We have synthesized and structurally characterized a new mixed valence pentanuclear Co complex, bearing a rare μ4-O-tetrahedral CoII4 unit, by employing a pyridine-like Schiff base ligand. We have performed DC magnetic susceptibility and magnetization measurements over polycrystalline samples and chemical quantum computations in order to understand the exchange interaction pattern within Co(II) sites and ground state magnetic anisotropy. This new complex shows an overall antiferromagnetic exchange interaction whose strength strongly depends on the local symmetry of Co(II) sites. Also, local ion magnetic anisotropy reveals a strongly axial behaviour with the lowest Kramers doublet (KD) at ea…
Three-dimensional singletons
1990
The three-dimensional analog of singleton gauge theory turns out to be related to the topological gauge theory of Schwartz and Witten. It is a fully-fledged gauge theory, though it involves only a single scalar field. Real, physical degrees of freedom propagate in 3-space, but they are ‘confined’ in the sense that they cannot be detected locally. The physical Hamiltonian density is not zero, but it is concentrated on the boundary at spatial infinity. This boundary surface, a torus, supports a two-dimensional conformal field theory.
Arabesques des images de l'ironie
2006
The author of this article analyzes the field of images of irony, starting from some Douglas C. Muecke’s works and some other personal analyses developed in «Poétique de l’ironie». He questions himself about the tension that exists between a possible archetypal image of irony, which would provide a vertical relationship of power, and its most recent images, which would highlight the fundamental ambiguity of the phenomenon. Between rhetoric and hermeneutics, between violence and conciliation, the outline of an arabesque of irony is defined, which allows us to organize the field of study around the notion of symmetry. Resuming important commentaries made by Sören Kierkegaard and Connop Thirlw…