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showing 10 items of 196 documents
Liquid Crystalline Orientation of Semiconducting Nanorods in a Semiconducting Matrix
2008
This paper describes the synthesis of narrowly distributed block copolymers consisting of a hole conducting triarylamine block and an anchor block via RAFT polymerization. The anchor block is thereby introduced via a reactive ester approach. Block copolymers with dopamine anchor groups bind to oxidic semiconductors like TiO 2 , SnO 2 , and ZnO. Thus, it becomes possible to cover inorganic electron conducting (acceptor) nanomaterials with a corona of an organic hole conducting (donor) polymer like poly(triphenylamine), giving new hybrid materials. The poly(triphenylamine) grafted to inorganic nanorods allows the preparation of stable nanorod dispersions in appropriate solvents. At higher con…
Formation and distortion of iodidoantimonates(III): the first isolated [SbI6]3- octahedron
2017
The ability to intentionally construct, through different types of interactions, inorganic–organic hybrid materials with desired properties is the main goal of inorganic crystal engineering. The primary deformation, related to intrinsic interactions within inorganic substructure, and the secondary deformation, mainly caused by the hydrogen bond interactions, are both responsible for polyhedral distortions of halogenidoantimonates(III) with organic cations. The evolution of structural parameters, in particular the Sb—I secondary- and O/N/C—H...I hydrogen bonds, as a function of temperature assists in understanding the contribution of those two distortion factors to the irregularity of [SbI6]…
?Contratti di soggiorno? e COVID-19. Parte prima. Nel periodo emergenziale.
2020
This paper analyses the destiny of ?sojourn contracts? (?contratti di soggiorno?) entered into prior to the outbreak of the Coronavirus pandemic, for services to be enjoyed during the emergency period. The work focuses, in particular, on the analysis of the emergency provisions introduced by the Italian legislator in favour of the tourism sector, by allowing professionals operating in the tourism sector to postpone the timing of the sojourn by issuing a voucher to be used in one year following the issuance date as an alternative to the reimbursement of any payment made prior to the emergency periods solutions in conformity with the principles of solidarity adopted in order to balance and sa…
Observation of ψ(3686)→η′e+e−
2018
Abstract Using a data sample of 448.1 × 10 6 ψ ( 3686 ) events collected with the BESIII detector at the BEPCII collider, we report the first observation of the electromagnetic Dalitz decay ψ ( 3686 ) → η ′ e + e − , with significances of 7.0σ and 6.3σ when reconstructing the η ′ meson via its decay modes η ′ → γ π + π − and η ′ → π + π − η ( η → γ γ ), respectively. The weighted average branching fraction is determined to be B ( ψ ( 3686 ) → η ′ e + e − ) = ( 1.90 ± 0.25 ± 0.11 ) × 10 − 6 , where the first uncertainty is statistical and the second systematic.
Dehydrogenative Anodic C−C Coupling of Phenols Bearing Electron‐Withdrawing Groups
2019
Abstract We herein present a metal‐free, electrosynthetic method that enables the direct dehydrogenative coupling reactions of phenols carrying electron‐withdrawing groups for the first time. The reactions are easy to conduct and scalable, as they are carried out in undivided cells and obviate the necessity for additional supporting electrolyte. As such, this conversion is efficient, practical, and thereby environmentally friendly, as production of waste is minimized. The method features a broad substrate scope, and a variety of functional groups are tolerated, providing easy access to precursors for novel polydentate ligands and even heterocycles such as dibenzofurans.
A Next‐Generation Air‐Stable Palladium(I) Dimer Enables Olefin Migration and Selective C−C Coupling in Air
2020
Abstract We report a new air‐stable PdI dimer, [Pd(μ‐I)(PCy2 tBu)]2, which triggers E‐selective olefin migration to enamides and styrene derivatives in the presence of multiple functional groups and with complete tolerance of air. The same dimer also triggers extremely rapid C−C coupling (alkylation and arylation) at room temperature in a modular and triply selective fashion of aromatic C−Br, C−OTf/OFs, and C−Cl bonds in poly(pseudo)halogenated arenes, displaying superior activity over previous PdI dimer generations for substrates that bear substituents ortho to C−OTf.
Du sens à l'expérience : gastronomie et œnologie au prisme de leurs terminologies : [actes du 2ème colloque international "Les terminologies professi…
2018
National audience; Entre expérience sensorielle, sensible et symbolique, cet ouvrage nous convie à un voyage particulier où se jouent les interactions de toute nature qui accompagnent les moments de notre existence. De la langue au langage, des perceptions aux émotions, de la culture à la nature ou de la suggestion à la relation, le discours gastronomique et øenologique construit un imaginaire en s'appuyant sur des fragments de réalité qu'il tend à comprendre et analyser.
Transport properties of nitrogen doped p‐gallium selenide single crystals
1996
Nitrogen doped gallium selenide single crystals are studied through Hall effect and photoluminescence measurements in the temperature ranges from 150 to 700 K and from 30 to 45 K, respectively. The doping effect of nitrogen is established and room temperature resistivities as low as 20 Ω cm are measured. The temperature dependence of the hole concentration can be explained through a single acceptor‐single donor model, the acceptor ionization energy being 210 meV, with a very low compensation rate. The high quality of nitrogen doped GaSe single crystals is confirmed by photoluminescence spectra exhibiting only exciton related peaks. Two phonon scattering mechanisms must be considered in orde…
The VN2 negatively charged defect in diamond. A quantum mechanical investigation of the EPR response
2020
Abstract The VN 2 − defect in diamond consists of a vacancy surrounded by two substitutional nitrogen atoms, which lower the local symmetry from Td to C2v. Calculations of the doublet ground state geometry, electronic structure, EPR parameters, and IR spectra of this defect are reported along with a preliminary investigation of the observed optical transition. For the most part our results were obtained using a uniform charge compensated supercell approach together with the B3LYP functional and all-electron Gaussian basis sets designed for the properties studied. In particular, the computed hyperfine and quadrupolar EPR parameters for the carbon and nitrogen atoms adjacent to the vacancy ag…
K-ϵ-L model in turbulent superfluid helium
2020
We generalize the K−ϵ model of classical turbulence to superfluid helium. In a classical viscous fluid the phenomenological eddy viscosity characterizing the effects of turbulence depends on the turbulent kinetic energy K and the dissipation function ϵ, which are mainly related to the fluctuations of the velocity field and of its gradient. In superfluid helium, instead, we consider the necessary coefficients for describing the effects of classical and quantum turbulence, involving fluctuations of the velocity, the heat flux, and the vortex line density of the quantized vortex lines. By splitting the several fields into a time-average part and a fluctuating part, some expressions involving t…