Search results for "41"

showing 10 items of 3365 documents

Series of Near-IR-Absorbing Transition Metal Complexes with Redox Active Ligands

2020

New soluble and intensely near-IR-absorbing transition metal (Ti, Zr, V, Ni) complexes were synthesized using a redox non-innocent N,N&rsquo

Spectrometry Mass Electrospray IonizationMagnetic Resonance SpectroscopyElectronsChemistry Techniques SyntheticCrystallography X-RayLigandsArticlelcsh:QD241-441Magneticslcsh:Organic chemistryX-Ray DiffractionCoordination ComplexesNickelTransition Elementsorgaaniset yhdisteetSpectroscopy Near-InfraredMolecular Structureredox-active ligandnon-innocent ligandsElectrochemical Techniquesliganditkompleksiyhdisteetmetal organic complexMetalsElectronicsOxidation-Reduction
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Synthesis, Characterization, and Saccharide Binding Studies of Bile Acid − Porphyrin Conjugates

2007

Synthesis and characterization of bile acid-porphyrin conjugates (BAPs) are reported. Binding of saccharides with BAPs in aqueous methanol was studied by monitoring changes in the visible absorption spectral of the porphyrin-moieties. Although these studies clearly showed absorbance changes, suggesting quite high if non-selective binding, the mass spectral studies do not unambiguously support these results.

Spectrometry Mass Electrospray IonizationMagnetic Resonance SpectroscopyPorphyrinsmedicine.drug_classElectrospray ionizationCarbohydratesPharmaceutical ScienceESI MS.ArticleAnalytical ChemistryAbsorbanceBile Acids and Saltslcsh:QD241-441chemistry.chemical_compoundUltraviolet visible spectroscopylcsh:Organic chemistryHeterocyclic Compoundsvisible spectroscopyDrug Discoverymedicinepolycyclic compoundsOrganic chemistryPhysical and Theoretical ChemistrysaccharideAqueous solutionBile acidMolecular StructureOrganic Chemistry1H-NMRPorphyrinCombinatorial chemistryBile acidschemistryChemistry (miscellaneous)Proton NMRMolecular Medicinesense organsporphyrinConjugateMolecules
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Structural analysis of the lipid A isolated from Hafnia alvei 32 and PCM 1192 lipopolysaccharides[S]

2010

Hafnia alvei, a Gram-negative bacterium, is an opportunistic pathogen associated with mixed hospital infections, bacteremia, septicemia, and respiratory diseases. The majority of clinical symptoms of diseases caused by this bacterium have a lipopolysaccharide (LPS, endotoxin)-related origin. The lipid A structure affects the biological activity of endotoxins predominantly. Thus, the structure of H. alvei lipid A was analyzed for the first time. The major form, asymmetrically hexa-acylated lipid A built of beta-D-GlcpN4P-(1-->6)-alpha-D-GlcpN1P substituted with (R)-14:0(3-OH) at N-2 and O-3, 14:0(3-(R)-O-12:0) at N-2', and 14:0(3-(R)-O-14:0) at O-3', was identified by ESI-MS(n) and MALDI-tim…

Spectrometry Mass Electrospray IonizationendotoxinLipopolysaccharideAcylationOligosaccharidesQD415-436BiochemistryMicrobiologyLipid Achemistry.chemical_compoundOpportunistic pathogenEndocrinologyPalmitoylationEscherichiapalmitoylationmass spectrometryPolish Collection of MicroorganismsbiologyHafnia alveiBiological activityCell Biologybiology.organism_classificationOxygenHafnia alveiLipid AchemistrySpectrometry Mass Matrix-Assisted Laser Desorption-Ionizationlipids (amino acids peptides and proteins)BacteriaResearch ArticleJournal of Lipid Research
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Genome-wide association analysis identifies six new loci associated with forced vital capacity

2014

Forced vital capacity (FVC), a spirometric measure of pulmonary function, reflects lung volume and is used to diagnose and monitor lung diseases. We performed genome-wide association study meta-analysis of FVC in 52,253 individuals from 26 studies and followed up the top associations in 32,917 additional individuals of European ancestry. We found six new regions associated at genome-wide significance (P <5 x 10(-8)) with FVC in or near EFEMP1, BMP6, MIR129-2-HSD17B12, PRDM11, WWOX and KCNJ2. Two loci previously associated with spirometric measures (GSTCD and PTCH1) were related to FVC. Newly implicated regions were followed up in samples from African-American, Korean, Chinese and Hispani…

SpirometryLung DiseasesVital capacityQuantitative Trait LociVital CapacityGenome-wide association studyBiologyPolymorphism Single NucleotideArticleDISEASEPulmonary function testingCohort StudiesFEV1/FVC ratioIdiopathic pulmonary fibrosisSDG 3 - Good Health and Well-beingMeta-Analysis as TopicForced Expiratory VolumeDatabases GeneticGeneticsmedicineHumansRestrictive lung diseaseLung volumesGenetic Predisposition to Diseaselung; spriometry; SNP; geneGENE-EXPRESSIONGeneticsmedicine.diagnostic_testGenome HumanHERITABILITYHEALTHY TWINMORTALITYta3141respiratory systemmedicine.diseasePrognosis3. Good healthRespiratory Function Testsrespiratory tract diseasesFAMILYLUNG-FUNCTIONGenetic LociSpirometryImmunologyCELLSIDIOPATHIC PULMONARY-FIBROSISTRAITSFollow-Up StudiesGenome-Wide Association StudyNature Genetics
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Mathematical Modeling and Parameters Estimation of Car Crash Using Eigensystem Realization Algorithm and Curve-Fitting Approaches

2013

Published version of an article in the journal: Mathematical Problems in Engineering. Also available from the publisher at: http://dx.doi.org/10.1155/2013/262196 Open Access An eigensystem realization algorithm (ERA) approach for estimating the structural system matrices is proposed in this paper using the measurements of acceleration data available from the real crash test. A mathematical model that represents the real vehicle frontal crash scenario is presented. The model's structure is a double-spring-mass-damper system, whereby the front mass represents the vehicle-chassis and the rear mass represents the passenger compartment. The physical parameters of the model are estimated using cu…

State systemEngineeringArticle Subjectbusiness.industryGeneral Mathematicslcsh:MathematicsStructural systemGeneral EngineeringCrashlcsh:QA1-939Crash testAccelerationlcsh:TA1-2040Curve fittingVDP::Matematikk og Naturvitenskap: 400::Matematikk: 410::Anvendt matematikk: 413Eigensystem realization algorithmbusinesslcsh:Engineering (General). Civil engineering (General)AlgorithmSimulationMathematical Problems in Engineering
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Time-dependent weak rate of convergence for functions of generalized bounded variation

2016

Let $W$ denote the Brownian motion. For any exponentially bounded Borel function $g$ the function $u$ defined by $u(t,x)= \mathbb{E}[g(x{+}\sigma W_{T-t})]$ is the stochastic solution of the backward heat equation with terminal condition $g$. Let $u^n(t,x)$ denote the corresponding approximation generated by a simple symmetric random walk with time steps $2T/n$ and space steps $\pm \sigma \sqrt{T/n}$ where $\sigma > 0$. For quite irregular terminal conditions $g$ (bounded variation on compact intervals, locally H\"older continuous) the rate of convergence of $u^n(t,x)$ to $u(t,x)$ is considered, and also the behavior of the error $u^n(t,x)-u(t,x)$ as $t$ tends to $T$

Statistics and ProbabilityApproximation using simple random walkweak rate of convergence01 natural sciencesStochastic solution41A25 65M15 (Primary) 35K05 60G50 (Secondary)010104 statistics & probabilityExponential growthFOS: Mathematics0101 mathematicsBrownian motionstokastiset prosessitMathematicsosittaisdifferentiaaliyhtälötApplied MathematicsProbability (math.PR)010102 general mathematicsMathematical analysisfinite difference approximation of the heat equationFunction (mathematics)Rate of convergenceBounded functionBounded variationnumeerinen analyysiapproksimointiStatistics Probability and UncertaintyMathematics - ProbabilityStochastic Analysis and Applications
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R&D, Competition and Growth with Human Capital Accumulation Revisited

2012

In this paper, we have presented a generalization of Bucci's (2003) model in which have disentangled the monopolistic mark-up in the intermediate goods sector, the intermediate goods share in the final output and the returns to specialization in order to have a better measurement of competition. Indeed, unlike Bucci (2003), in our model, the measure of competition is completely independent of the intermediate goods share in the final output and the returns to specialization. Our main finding is that, unlike Bucci (2003), we show that the competition does not play any role in growth. This result is explained by the complementarity of innovation and human capital assumed in the research produ…

Statistics and ProbabilityEconomics and EconometricsJ24O41technological changejel:D43Endogenous growth; horizontal differentiation; technological change; imperfect competition; human capitalHuman capitaljel:J24MicroeconomicsCompetition (economics)jel:O41Monopolistic competitionhorizontal differentiationSpecialization (functional)ddc:330Per capitaEconomicsProduction (economics)[ SHS.ECO ] Humanities and Social Sciences/Economies and financesimperfect competitionhuman capital[SHS.ECO] Humanities and Social Sciences/Economics and FinanceComputingMilieux_MISCELLANEOUSO31Endogenous growth theory[SHS.ECO]Humanities and Social Sciences/Economics and FinanceL16Endogenous growthjel:O31jel:L16HUMAN CAPITALImperfect competitionD43
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Rough linear PDE's with discontinuous coefficients - existence of solutions via regularization by fractional Brownian motion

2020

We consider two related linear PDE's perturbed by a fractional Brownian motion. We allow the drift to be discontinuous, in which case the corresponding deterministic equation is ill-posed. However, the noise will be shown to have a regularizing effect on the equations in the sense that we can prove existence of solutions for almost all paths of the fractional Brownian motion.

Statistics and ProbabilityFractional Brownian motion010102 general mathematicsMathematical analysisProbability (math.PR)fractional Brownian motionlocal times01 natural sciencesRegularization (mathematics)VDP::Matematikk og Naturvitenskap: 400::Matematikk: 410010104 statistics & probabilityDeterministic equation60H05FOS: Mathematics60H1560J5560H1060G220101 mathematicsStatistics Probability and Uncertaintystochastic PDEsrough pathsregularization by noiseMathematics - ProbabilityMathematics
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Random dynamical system generated by the 3D Navier-Stokes equation with rough transport noise

2022

We consider the Navier-Stokes system in three dimensions perturbed by a transport noise which is sufficiently smooth in space and rough in time. The existence of a weak solution was proved recently, however, as in the deterministic setting the question of uniqueness remains a major open problem. An important feature of systems with uniqueness is the semigroup property satisfied by their solutions. Without uniqueness, this property cannot hold generally. We select a system of solutions satisfying the semigroup property with appropriately shifted rough path. In addition, the selected solutions respect the well accepted admissibility criterium for physical solutions, namely, maximization of th…

Statistics and ProbabilityMathematics - Analysis of PDEsProbability (math.PR)FOS: MathematicsStatistics Probability and UncertaintyVDP::Matematikk og Naturvitenskap: 400::Matematikk: 410Mathematics - ProbabilityAnalysis of PDEs (math.AP)
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Girsanov Theorem for Multifractional Brownian Processes

2017

In this article we will present a new perspective on the variable order fractional calculus, which allows for differentiation and integration to a variable order, i.e. one differentiates (or integrates) a function along the path of a regularity function. The concept of multifractional calculus has been a scarcely studied topic within the field of functional analysis in the last 20 years. We develop a multifractional derivative operator which acts as the inverse of the multifractional integral operator. This is done by solving the Abel integral equation generalized to a multifractional order. With this new multifractional derivative operator, we are able to analyze a variety of new problems,…

Statistics and ProbabilityMathematics - Functional AnalysisModeling and SimulationProbability (math.PR)FOS: MathematicsPhysics::Data Analysis; Statistics and ProbabilityVDP::Matematikk og Naturvitenskap: 400::Matematikk: 410Mathematics - ProbabilityFunctional Analysis (math.FA)
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