Search results for "BAND"

In-beam spectroscopic study of Cf244

2018

The ground-state rotational band of the neutron-deficient californium (Z = 98) isotope 244Cf was identified for the first time and measured up to a tentative spin and parity of I I-pi = 20(+). The observation of the rotational band indicates that the nucleus is deformed. The kinematic and dynamic moments of inertia were deduced from the measured gamma-ray transition energies. The behavior of the dynamic moment of inertia revealed an up-bend due to a possible alignment of coupled nucleons in high-j orbitals starting at a rotational frequency of about (h) over bar (omega) = 0.20 MeV. The results were compared with the systematic behavior of the even-even N = 146 isotones as well as with avail…

Ligand engineering in Cu(ii) paddle wheel metal–organic frameworks for enhanced semiconductivity

2020

We report the electronic structure of two metal-organic frameworks (MOFs) with copper paddle wheel nodes connected by a N2(C2H4)3 (DABCO) ligand with accessible nitrogen lone pairs. The coordination is predicted, from first-principles density functional theory, to enable electronic pathways that could facilitate charge carrier mobility. Calculated frontier crystal orbitals indicate extended electronic communication in DMOF-1, but not in MOF-649. This feature is confirmed by bandstructure calculations and effective masses of the valence band egde. We explain the origin of the frontier orbitals of both MOFs based on the energy and symmetry alignment of the underlying building blocks. The effe…

Layout influence on microwave performance of graphene field effect transistors

2018

The authors report on an in-depth statistical and parametrical investigation on the microwave performance of graphene FETs on sapphire substrate. The devices differ for the gate-drain/source distance and for the gate length, having kept instead the gate width constant. Microwave S -parameters have been measured for the different devices. Their results demonstrate that the cut-off frequency does not monotonically increase with the scaling of the device geometry and that it exists an optimal region in the gate-drain/source and gate-length space which maximises the microwave performance.

Assessment and inter-comparison of recently developed/reprocessed microwave satellite soil moisture products using ISMN ground-based measurements

2019

Soil moisture (SM) is a key state variable in understanding the climate system through its control on the land surface energy, water budget partitioning, and the carbon cycle. Monitoring SM at regional scale has become possible thanks to microwave remote sensing. In the past two decades, several satellites were launched carrying on board either radiometer (passive) or radar (active) or both sensors in different frequency bands with various spatial and temporal resolutions. Soil moisture algorithms are in rapid development and their improvements/revisions are ongoing. The latest SM retrieval products and versions of products that have been recently released are not yet, to our knowledge, com…

Monitoring 10-m LST from the Combination MODIS/Sentinel-2, Validation in a High Contrast Semi-Arid Agroecosystem

2020

Downscaling techniques offer a solution to the lack of high-resolution satellite Thermal InfraRed (TIR) data and can bridge the gap until operational TIR missions accomplishing spatio-temporal requirements are available. These techniques are generally based on the Visible Near InfraRed (VNIR)-TIR variable relations at a coarse spatial resolution, and the assumption that the relationship between spectral bands is independent of the spatial resolution. In this work, we adopted a previous downscaling method and introduced some adjustments to the original formulation to improve the model performance. Maps of Land Surface Temperature (LST) with 10-m spatial resolution were obtained as output fro…

Remote Patient Monitoring Within a Future 5G Infrastructure

2010

Published version of an article from the journal: Wireless Personal Communications. The original publication is available at Spingerlink. http://dx.doi.org/10.1007/s11277-010-0078-5 Systems of wearable or implantable medical devices (IMD), sensor systems for monitoring and transmitting physiological recorded signals, will in future health care services be used for purposes of remote monitoring. Today, there exist several constraints, probably preventing the adoption of such services in clinical routine work. Within a future 5G infrastructure, new possibilities will be available due to improved addressing solutions and extended security services in addition to higher bandwidth in the wireles…

Temporaneità

2022

Il saggio riflette sul tema della Temporaneità considerata, ormai, prassi strettamente connessa a quello dell’urban shrinkage, condizione centrale nel dibattito scientifico quanto nell’agenda politica di diverse città europee. Dagli anni ’90 a livello globale, nelle città e nei territori abbondano i luoghi dell’abbandono e dell’inutilizzato che ci restituiscono uno scenario di progressiva contrazione non solo demografica ma anche economica e sociale. In questo controverso quadro di mutazione strutturale delle città e dei territori si stanno sperimentando strategie, strumenti e schemi di governance efficaci per governare la decrescita e l’abbandono il cui comun denominatore è il ricorso …

Comparing different profiles to characterize the atmosphere for three MODIS TIR bands

2015

Abstract Accurate land surface temperature (LST) retrievals from sensors aboard orbiting satellites are dependent on the corresponding atmospheric correction, especially in the thermal infrared (TIR) spectral domain (8–14 μm). To remove the atmospheric effects from at-sensor measured radiance in the TIR range it is needed to characterize the atmosphere by means of three specific variables: the upwelling path and the hemispherical downwelling radiances plus the atmospheric transmissivity. Those variables can be derived from the previous knowledge of vertical atmospheric profiles of air temperature and relative humidity at different geo-potential heights and pressures. In this work, the above…

ChemInform Abstract: The Valence States of Nickel, Tin, and Sulfur in the Ternary Chalcogenide Ni3Sn2S2 - XPS, 61Ni and 119Sn Moessbauer Investigatio…

2010

On the use of ionic liquids as mobile phase additives in high-performance liquid chromatography. A review.

2015

The popularity of ionic liquids (ILs) has grown during the last decades in several analytical separation techniques. Consequently, the number of reports devoted to the applications of ILs is still increasing. This review is focused on the use of ILs (mainly imidazolium-based associated to chloride and tetrafluoroborate) as mobile phase additives in high-performance liquid chromatography (HPLC). In this approach, ILs just function as salts, but keep several kinds of intermolecular interactions, which are useful for chromatographic separations. Both cation and anion can be adsorbed on the stationary phase, creating a bilayer. This gives rise to hydrophobic, electrostatic and other specific in…