Search results for "BES"

showing 10 items of 3692 documents

Enhancing the mechanical performance of polymer based nanocomposites by plasma-modification of nanoparticles

2012

Abstract The possibility of enhancing the mechanical performance of two different polymer-based nanocomposites using polyamide 6 (PA6) and poly[ethylene-co-(vinyl acetate)] (EVA) as matrices was investigated. The nanofillers used were, respectively, either carbon nanotubes (CNTs) or an organically modified montmorillonite (Cloisite 15A), both previously modified by plasma treatment to introduce polar moieties. The nanofillers were fully characterized by Raman spectroscopy, XPS, FT-IR and XRD, demonstrating their effective modification with oxygenated groups. The nanocomposites were prepared by melt processing in order to obtain films and fibres. The mechanical tests carried out on the nanoc…

chemistry.chemical_classificationNanocompositeMaterials scienceNanocompositePolymers and PlasticsOrganic ChemistryNanoparticlePolymerCarbon nanotubeCarbon nanotubelaw.inventionCarbon nanotubes; Functionalization; Nanocomposite; Nanoclay; Nanoparticle; Plasma.chemistry.chemical_compoundNanoparticlechemistrylawPolyamideVinyl acetateNanoclaySurface modificationComposite materialFunctionalizationElastic modulusPlasma.
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Halloysite nanotubes as polyolefin fillers

2015

Artykuł stanowi przegląd najnowszej literatury dotyczącej nanokompozytów poliolefinowych napełnianych nanorurkami haloizytowymi (HNT). Omówiono wpływ dodatku HNT na osnowę poliolefinową, ze szczególnym uwzględnieniem morfologii oraz właściwości mechanicznych nanokompozytów poliolefina/HNT. Modyfikowane HNT wykazywały wysoki stopień rozproszenia w osnowie poliolefinowej, dzięki czemu powodowały poprawę właściwości mechanicznych poliolefinowych nanokompozytów napełnianych nanorurkami haloizytowymi. Połączenie korzystnych właściwości poliolefin, ekonomicznych metod ich przetwórstwa oraz unikatowych w³aoeciwooeci HNT pozwoli na szersze rozpowszechnienie nanokompozytów wytworzonych z ich udziałe…

chemistry.chemical_classificationNanocompositeMaterials sciencePolymers and PlasticsGeneral Chemical Engineeringnanorurki haloizytowehalloysite nanotubesPolymerengineering.materialHalloysitePolyolefinaluminosilicate modificationpolyolefin nanocompositeschemistry.chemical_compoundmodyfikacja glinokrzemianówchemistryChemical engineeringMaterials Chemistryengineeringnanokompozyty poliolefinowePolimery
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Biocompatible Poly(N-isopropylacrylamide)-halloysite Nanotubes for Thermoresponsive Curcumin Release

2015

The grafting of poly(N-isopropylacrylamide) (PNIPAAM) onto the halloysite external surface is proposed in order to obtain a novel thermoresponsive drug carrier for curcumin delivery. The new nanomaterial is characterized by means of FT-IR spectroscopy, thermogravimetric analysis, and SEM investigations. A high density of polymer chain was achieved at the nanoparticle surface. The PNIPAAM dehydration phenomenon was observed in water above 32 °C that is nearly coincident with the lower critical solution temperature for the polymer. The colloidal stability as well as the wettability of the obtained nanomaterial may be triggered by temperature stimuli. In vitro tests simulating the gastro-intes…

chemistry.chemical_classificationThermogravimetric analysisMaterials scienceNanoparticleNanotechnologySettore CHIM/06 - Chimica OrganicaPolymerengineering.materialLower critical solution temperatureHalloysiteSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsNanomaterialschemistry.chemical_compoundGeneral EnergychemistryPoly(N-isopropylacrylamide)engineeringPhysical and Theoretical ChemistryDrug carrierhalloysite nanotubes PNIPAAM covalent grafting curcumin releaseSettore CHIM/02 - Chimica FisicaThe Journal of Physical Chemistry C
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Guest-Induced Folding and Self-Assembly of Conformationally Adaptive Macrocycles into Nanosheets and Nanotubes

2017

A conformationally adaptive macrocycle is presented, namely zorb[4]arene, which exists in multiple conformations in the uncomplexed state. The binding cavity of zorb[4]arene is concealed, either due to a collapsed conformation or by self-inclusion. The zorb[4]arene with long alkyl chains manifests itself with surprisingly low melting point and thus exist as an oil at room temperature. Binding of a guest molecule induces the folding and conformational rigidity of zorb[4]arene and leads to well-defined three-dimensional structures, which can further self-assemble into nanosheets or nanotubes upon solvent evaporation, depending on guest molecules and the conformations they can induce.

chemistry.chemical_classificationadaptive macrocyclesnanosheets010405 organic chemistryStereochemistryOrganic ChemistryLow melting pointGeneral Chemistry010402 general chemistry01 natural sciencesCatalysissupramolecular chemistryguest-induced folding0104 chemical sciencesnanotubesFolding (chemistry)Solvent evaporationchemistryMoleculeSelf-assemblyta116AlkylChemistry: A European Journal
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Livelli serici di insulina nel soggetto normale (Obeso e non) e nel diabetico obeso Dopo Carico Intragastrico di Aminoacidi

1968

Gli AA. hanno somministrato in 5 soggetti normali normosomici, in 5 obesi metabolicamente sani e in 5 diabetici obesi un carico intragastrico (mediante sondino) di 9 aminoacidi essenziali (arginina, fenil-alanina, valina, leucina, lisina, metionina, isoleucina, istidina, triptofano) per un totale di g 30 ed hanno valutato la risposta insulo-pancreatica. In tutti i casi di soggetti in esame si e messo in evidenza un significativo aumento dell'insulinemia, determinata con metodo radioimmunologico. Il picco insulinemico e stato di 45 ± 11 µU/ml nei normali normosomici, di 65 ± 6 µU/ml negli obesi e di 52 ± 8 nei diabetici obesi, rispettivamente a 75 mp, a 60 mp e a 105 mp. La caduta insulinemi…

chemistry.chemical_classificationmedicine.medical_specialtybusiness.industryEndocrinology Diabetes and MetabolismInsulinmedicine.medical_treatmentGeneral Medicinemedicine.diseaseAmino acidEndocrinologyEndocrinologychemistryNon obeseIntragastric administrationDiabetes mellitusInternal medicineInternal MedicinemedicinebusinessActa Diabetologica Latina
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Sugar reduction: Stevia rebaudiana Bertoni as a natural sweetener

2020

Abstract Excessive sugar consumption is associated with the development of numerous health problems, such as obesity and many chronic diseases (e.g., cardiovascular disease, diabetes). Obesity is a rapidly growing public health problem, thus its prevention and treatment are crucial to improve the quality of life. Among others, sugar-sweetened beverage consumption was considered as a key risk factor that contributes to a significant excess of sugar in the diet. The World Health Organization is intensively working on strategies to reduce sugar intake by featuring educational methods and innovative marketing techniques for various communities, media, governments, and industries. Despite many s…

chemistry.chemical_classificationmedicine.medical_specialtybusiness.industryPublic healthfood and beveragesGlycosideBiologymedicine.diseasebiology.organism_classificationSteviaObesityBiotechnologychemistry.chemical_compoundStevia rebaudianachemistryDiabetes mellitusmedicineSugarbusinessSteviol glycoside
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Nanocomposite, an innovative route to large structure and infrastructure protection. A case of study: CNT-doped polyurea

2010

<p>In this work we focus on experimental studies of polymer-nanocomposites intended for passive protection of civil structures. The material consists of a polyurea-matrix enhanced by different quantities of multiwalled carbon nanotubes. Several tensile and cyclic tests are performed to evaluate and characterize the mechanical behaviour of this new material. Furthermore, we subject the material to accelerated thermal aging and study its performance deterioration which is fairly unknown. The results on the unaged specimens are intuitive and indicate that an arbitrary amount of CNTs may result in suboptimal performance. More specifically, 1% in weight of CNTs yields the best mechanical p…

chemistry.chemical_compoundMaterials scienceNanocompositechemistrynanomaterials carbon nanotubes polymer matrix composite materials polyurea accelerated aging thermal loadingDopingSettore ICAR/10 - Architettura TecnicaNanotechnologyComposite materialPolyurea
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Templating effect of carbon nanoforms on highly cross-linked imidazolium network: Catalytic activity of the resulting hybrids with Pd nanoparticles

2019

Two different carbon nanoforms (CNFs), namely multi-walled carbon nanotubes (MWCNTs) and carbon nanohorns (CNHs), have been chosen as support for the direct polymerization of a bis-vinylimidazolium salt. Transmission electron microscopy analyses revealed a templating effect of the CNFs on the growth of the polymeric network, which perfectly covers their whole surfaces creating a cylindrical or spherical coating for MWCNTs and CNHs, respectively. Subsequently, the CNFs-polyimidazolium have been used as stabilizers for Pd nanoparticles (Pd NPs), and the obtained materials have been characterized by means of analytical and spectroscopic techniques and then employed as easily recoverable and re…

chemistry.chemical_elementSettore CHIM/06 - Chimica OrganicaGeneral ChemistryHeterogeneous catalysisCatalysisnanotubesInorganic ChemistrySuzuki–Miyaura reactionC c couplingHeck reactionheterogeneous catalysischemistryHeck reactionPd nanoparticlesPolymer chemistrynanotubeheterogeneous catalysiC-C couplingSuzuki-Miyaura reactionCarbon
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Normal-weight obesity and cardiometabolic risk : A 7-year longitudinal study in girls from prepuberty to early adulthood

2017

Objective: To study whether normal-weight obesity in childhood is associated with increased cardiometabolic risk in early adulthood. Methods: This study assessed data for 236 girls followed from prepuberty to early adulthood. Growth chart data were obtained from birth to 18 years. Body composition was assessed by dual-energy x-ray absorptiometry and cardiometabolic risk by calculating continuous clustered risk score (at ages 11, 14, and 18). The association of body weight status with cardiometabolic risk from childhood to early adulthood was examined. Results: Subjects with normal-weight obesity were virtually indistinguishable from their normal-weight lean peers in terms of relative body w…

childrencardiometabolic riskrasvaprosenttisydän- ja verisuonitauditlihavuuslapset (ikäryhmät)ylipainoadolescentsbody fat percentageriskitnormal-weight obesitypainonhallintakehonkoostumus
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Les sépultures de Truchtersheim "Holderacker" (Bas-Rhin) et les pratiques funéraires du Bronze A1 dans le sud de la plaine du Rhin supérieur

2023

Die Freilegung 2019 eines kleinen frühbronzezeitlichen (2030-1900 v. Chr.) Bestattungsensemblesin Truchtersheim „Holderacker“, etwa 12 km nordwestlich von Straßburg, hat uns bewegt uns mit der gesamten für das Elsassverfügbaren Dokumentation der frühbronzezeitlichen Bestattungssitten zu befassen. Dieser bisher kaum dokumentiertechronologische Horizont wurde kürzlich durch eine Reihe von Funden bereichert, die vorwiegend zwischen 2017 und 2019bei präventivarchäologischen Operationen im Vorfeld der Bauarbeiten der Westumgehung von Straßburg entdeckt wurden.Das bescheidene regionale Corpus mit 20 Gräbern erlaubt nur begrenzte Beobachtungen, es weist jedoch doch mehrere für dieFrühbronzezeit ch…

chronologie absolue[SHS.ARCHEO] Humanities and Social Sciences/Archaeology and PrehistoryElsassmortuary practicespratiques funérairesFrühbronzezeitabsolute ChronologieKnochenschmuckperles en faïenceearthenware beadsAlsaceBestattungssittenBronze ancienosseous body ornamentsKeramikperlenabsolute chronologyEarly Bronzeparures en matière dure animale
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