Search results for "BIF"
showing 10 items of 539 documents
Isomerization and Application of Aroylnorbornenecarboxylic Acids for Stereoselective Preparation of Heterocycles
2002
When boiled in acidic or basic solution, diendo-3-aroylbicyclo[2.2.1]heptane-2-carboxylic acids (1 and la) isomerize to exo-3-aroylbicyclo[2.2.1]heptane-endo-2-carboxylic acids (2 and 2a). Similar endo→exo and even exo → endo isomerization of the aroyl group occurred when the Diels-Alder product containing a mixture of 3-exo-p-toluoylbicyclo[2.2.1 ]hept-5-ene-2-endo-carboxylic acid (4) and 3-endo-p-toluoylbicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid (5) was reacted with bifunctional reagents: o-aminothiophenol, 3-amino-1-propanol, 1,4-diaminobutane or diexo-3-hydroxymethylbicyclo[2.2.1]heptane-2-amine. All the reactions yielded mixtures of norbornene diendo- and diexo-fused heterocycles (…
New potential bimodal imaging contrast agents based on DOTA-like and porphyrin macrocycles
2011
A bifunctional chelator featuring (DO3A-AM)-Porphyrin units has been prepared. The high-field relaxivity of the Gd complex is similar to those of currently available contrast agents clearly showing that the first coordination sphere remains identical to the parent molecule [Gd(DO3A-AM)(H2O)], with one coordinated water molecule.
Polymorphic and regular localized activity structures in a two-dimensional two-component reaction–diffusion lattice with complex threshold excitation
2010
Abstract Space–time dynamics of the system modeling collective behaviour of electrically coupled nonlinear units is investigated. The dynamics of a local cell is described by the FitzHugh–Nagumo system with complex threshold excitation. It is shown that such a system supports formation of two distinct kinds of stable two-dimensional spatially localized moving structures without any external stabilizing actions. These are regular and polymorphic structures. The regular structures preserve their shape and velocity under propagation while the shape and velocity as well as other integral characteristics of polymorphic structures show rather complex temporal behaviour. Both kinds of structures r…
Investigations of Low Temperature Phase Transitions in BiFeO3Ceramic by Infrared Spectroscopy
2011
In this paper, results of new infrared FIR-MIR measurements (wavenumber range of 4000–100 cm−1) in the range of the temperature 300 ÷ 8 K of the BiFeO3 ceramic are presented. Below 200 K only one symmetric band at ca. 800 cm−1 is visible. The full width at half maximum of this band decreases exponentially on cooling. The shape of the band at ca. 545 cm−1connected with A1 (TO) mode also changes between 60–40 K, this is in the vicinity of the phase transition at 50 K. Initially a broad band reveals its components as shoulder bands. Theirs FWHM decrease with cooling.
NODAPA-OH and NODAPA-(NCS)n: Synthesis, 68Ga-radiolabelling and in vitro characterisation of novel versatile bifunctional chelators for molecular ima…
2008
This report concerns synthesis, (68)Ga-radiolabelling and stability data of 1,4,7-triazacyclononane-1,4-diacetic acid-7-p-isothio-cyanatophenyl-acetic acid (NODAPA-NCS), 1,4,7-triazacyclononane-1-acetic acid-4,7-di-p-isothiocyanatophenyl-acetic acid (NODAPA-(NCS)(2)) and 1,4,7-triazacyclononane-1,4-diacetic acid-7-p-hydroxyphenyl-acetic acid (NODAPA-OH), versatile bifunctional chelators with potential for molecular imaging. Protein binding and exemplified conjugation are also reported.
From Continuous to Discontinuous Transitions in Social Diffusion
2018
Models of social diffusion reflect processes of how new products, ideas or behaviors are adopted in a population. These models typically lead to a continuous or a discontinuous phase transition of the number of adopters as a function of a control parameter. We explore a simple model of social adoption where the agents can be in two states, either adopters or non-adopters, and can switch between these two states interacting with other agents through a network. The probability of an agent to switch from non-adopter to adopter depends on the number of adopters in her network neighborhood, the adoption threshold $T$ and the adoption coefficient $a$, two parameters defining a Hill function. In c…
Anharmonic effects on the dynamic behavior’s of Klein Gordon model’s
2021
Abstract This work completes and extends the Ref. Tchakoutio Nguetcho et al. (2017), in which we have focused our attention only on the dynamic behavior of gap soliton solutions of the anharmonic Klein-Gordon model immersed in a parameterized on-site substrate potential. We expand our work now inside the permissible frequency band. These considerations have crucial effects on the response of nonlinear excitations that can propagate along this model. Moreover, working in the allowed frequency band is not only interesting from a physical point of view, it also provides an extraordinary mathematical model, a new class of differential equations possessing vital parameters and vertical singular …
Temporal Soliton “Molecules” in Mode-Locked Lasers: Collisions, Pulsations, and Vibrations
2008
A few years after the discovery of the stable dissipative soliton pairs in passively mode-locked lasers, a large variety of multi-soliton complexes were studied in both experiments and numerical simulations, revealing interesting new behaviors. This chapter focuses on the following three subjects: collisions between dissipative solitons, pulsations of dissipative solitons, and vibrations of soliton pairs. Different outcomes of collisions between a soliton pair and a soliton singlet are discussed, showing possible experimental control in the formation or dissociation of ‘soliton molecules’. Long-period pulsations of single and multiple dissipative solitons are presented as limit cycles and o…
Comb-like Turing patterns embedded in Hopf oscillations: Spatially localized states outside the 2:1 frequency locked region
2017
A generic distinct mechanism for the emergence of spatially localized states embedded in an oscillatory background is demonstrated by using 2:1 frequency locking oscillatory system. The localization is of Turing type and appears in two space dimensions as a comb-like state in either $\pi$ phase shifted Hopf oscillations or inside a spiral core. Specifically, the localized states appear in absence of the well known flip-flop dynamics (associated with collapsed homoclinic snaking) that is known to arise in the vicinity of Hopf-Turing bifurcation in one space dimension. Derivation and analysis of three Hopf-Turing amplitude equations in two space dimensions reveals a local dynamics pinning mec…
Bifurcation of traveling waves in a Keller–Segel type free boundary model of cell motility
2018
We study a two-dimensional free boundary problem that models motility of eukaryotic cells on substrates. This problem consists of an elliptic equation describing the flow of cytoskeleton gel coupled with a convection-diffusion PDE for the density of myosin motors. The two key properties of this problem are (i) presence of the cross diffusion as in the classical Keller-Segel problem in chemotaxis and (ii) nonlinear nonlocal free boundary condition that involves curvature of the boundary. We establish the bifurcation of the traveling waves from a family of radially symmetric steady states. The traveling waves describe persistent motion without external cues or stimuli which is a signature of …