Search results for "BIM"
showing 10 items of 365 documents
Mono- and Bimetallic Zwitterionic Chromium(0) and Tungsten(0) Allenyls
2015
A series of stable chiral (racemic), formally neutral, zwitterionic mono- and bimetallic M(CO)5[C(OEt)═C═CR(NHC)] (M = Cr, W) σ-allenyls are ready available by the addition of N-heterocyclic carbenes (NHCs) to Cr(0) and W(0) alkynyl Fischer carbene complexes. Different classes of NHCs, (e.g., 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene, 1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene, and their six- and seven-membered analogues and 1,3-bis(dimethyl)imidazol-2-ylidene) were employed as nucleophiles in these C-C bond-forming reactions yielding the novel complexes in essentially quantitative yields. A systematic experimental and computational study of the electronic properties of the C…
Synthesis, crystal structures and magnetic properties of single and double cyanide-bridged bimetallic Fe2(III)Cu(II) zigzag chains.
2004
The bimetallic complexes [[Fe(III)(phen)(CN)4]2Cu(II)(H2O)2].4H2O (1), [[Fe(III)(phen)(CN)4]2Cu(II)].H2O (2) and [[Fe(III)(bipy)(CN)4]2Cu(II)].2H2O (3) and [[Fe(III)(bipy)(CN)4]2Cu(II)(H2O)2].4H2O (4) (phen = 1,10-phenanthroline and bipy = 2,2'-bipyridine) have been prepared and the structures of 1-3 determined by X-ray diffraction. The structure of 1 is made up of neutral cyanide-bridged Fe(III)-Cu(II) zigzag chains of formula [[Fe(III)(phen)(CN)4]2Cu(II)(H2O)2] and uncoordinated water molecules with the [Fe(phen)(CN)4]- entity acting as a bis-monodentate bridging ligand toward two trans-diaquacopper(II) units through two of its four cyanide groups in cis positions. The structure of 2 can …
Triphosphine-supported bimetallic Au(I)-M(I) (M = Ag, Cu) alkynyl clusters.
2014
The reactions of gold acetylides (AuC2R)n with triphosphine ligands PPh2-(CH2)n-PPh-(CH2)2-PPh2 (n = 1, dpmp; 2, dpep) in the presence of M(+) ions (M = Cu, Ag) lead to an assembly of the heterometallic clusters, the composition of which is determined by the steric bulkiness of the alkynyl groups and the flexibility of the phosphine motifs. For R = Ph, an unprecedented hexanuclear complex [Au5Cu(C2R)4(dpmp)2](2+) (1) was isolated, while for the aliphatic alkynes (R = 1-cyclohexanolyl, 2-borneolyl, 2,6-dimethyl-4-heptanolyl) a family of compounds based on a tetrametallic framework was prepared, [Au3Cu(C2R)3(dpmp)](+) (2, R = 1-cyclohexanolyl), [Au3M(C2R)3(dpep)]2(+2) (3, M = Cu, R = 1-cycloh…
Stochastic model of memristor based on the length of conductive region
2021
Abstract We propose a stochastic model of a voltage controlled bipolar memristive system, which includes the properties of widely used dynamic SPICE models and takes into account the fluctuations inherent in memristors. The proposed model is described by rather simple equations of Brownian diffusion, does not require significant computational resources for numerical modeling, and allows obtaining the exact analytical solutions in some cases. The noise-induced transient bimodality phenomenon, arising under resistive switching, was revealed and investigated theoretically and experimentally in a memristive system, by finding a quite good qualitatively agreement between theory and experiment. B…
Reactivity of the ansa-Bridged Metallocene Dichlorides [X(η5-C5H4)2]MCl2 (X = SiMe2, CMe2; M = Mo, W) toward Metallophosphide Anions [PPh2M‘(CO)x]- (…
1997
Two kinds of ansa derivatives, [SiMe2(η5-C5H4)2]MCl2 and [CMe2(η5-C5H4)2]MCl2 (M = Mo, W), are reacted with metallophosphide anions [PPh2M‘(CO)x]- (M‘ = Cr, Mo, W, x = 5; M‘ = Fe, x = 4). The silicon-bridged derivatives give the bimetallic systems [SiMe2(η5-C5H4)(η5-C5H3PPh2M‘(CO)x)]M(H)(Cl), which result from a regioselective substitution at the 3-position on the cyclopentadienyl ligand. In contrast, with the CMe2-bridged compounds, the substitution reaction occurs at the metallic center, giving μ-phosphido bimetallic complexes [CMe2(η5-C5H4)2]M(Cl)(μ-PPh2)M‘(CO)x. The solid-state structure of the bimetallic complex [CMe2(η5-C5H4)2]W(Cl)(μ-PPh2)Fe(CO)4 (7d) is reported.
Supervisores bursátiles, gobierno corporativo y cumplimiento de las NIIF: el caso de la CNMV
2015
Las Normas Internacionales de Información Financiera (NIIF), emitidas por el International Accounting Standards Board (IASB) y los US-GAAP, son hoy el referente global en convergencia hacia un estándar global. Las NIIF se utilizan fundamentalmente en los mercados de capitales, si bien carecen de una superestructura que garantice un sistema contable de elevada calidad. La Unión Europea, en su nueva propuesta de reglamento de auditoría para Entidades de Interés Público (EIP), da un gran protagonismo a los supervisores bursátiles como controladores de una adecuada aplicación de estas normas en la confección de los estados financieros. En este contexto, el objetivo que persigue el presente trab…
Mechanical properties and accommodation processes on metallic interfaces
1998
Bimetallic joints Al/Pb, Al/Sn, Pb/Sn, Pb/Pb, etc. with clean interfaces, obtained by a special cold welding method, are used as a model of phase boundaries for investigation of accommodation processes and strength properties of interfaces. To reduce the volume diffusion-induced relaxation processes, investigations were carried out at relatively low temperatures 0.1-0.5 T m . The role of surface diffusion and the effect of phase boundary energy on the healing of micropore ensembles on interfaces was investigated. The accommodation processes on the phase boundaries are considered as a result of mechanoactivation of both the interaction and structure formation of such non-equilibrium systems.…
Smart Sustainable Cities of the New Millennium: Towards Design for Nature
2021
AbstractUrban environments consist of a mosaic of natural fragments, planned and unintentional habitats hosting both introduced and spontaneous species. The latter group exploits abandoned and degraded urban niches which, in the case of plants, form what is called thethird landscape. In the Anthropocene, cities, open spaces and buildings must be planned and designed considering not only human needs but also those of other living organisms. The scientific approach of habitat sharing is defined asreconciliation ecology, whilst the action of implementing the ecosystem services and functioning of such anthropogenic habitats is calledUrban Rehabilitation. However, urban development still represe…
Représentation hybride du modèle numérique pour la gestion d'un patrimoine bâti dit ancien
2013
International audience; Ce projet de recherche explore et repousse les limites inhérentes à la représentation numérique du bâti ancien dans la préparation et le suivi de travaux de rénovation. A Cluny, l'Ecole Nationale Supérieure des Arts et Métiers est logée en partie dans les bâtiments de l'ancienne abbaye clunisienne. La représentation numérique d'un bâtiment permet d'archiver la connaissance tout au long de son cycle de vie. L'édifice, datant du XVIIIème siècle, est classé aux monuments historiques. En matière de rénovation les opérations sont strictement encadrées. L'étude de cas portera sur l'isolation intérieure d'un bureau au niveau de la baie ancienne. Elle consiste en l'ajout d'u…
SimpleBIM: From full ifcOWL graphs to simplified building graphs
2016
International audience; Recent research in semantic web technologies for the built environment has resulted in several proposals to further improve information exchange among stakeholders from the domain. Most notable is the production of several OWL ontologies that allow to capture building data in RDF graphs. For example, an ifcOWL ontology allows to capture IFC data in an RDF graph. As the building data is now available in a semantic graph with an explicit formal basis, it can be restructured and simplified so that it more easily matches the different requirements associated with practical use case scenarios. In this paper, we investigate several proposals and technological approaches to…