Search results for "Bio based"
showing 10 items of 14 documents
From Laboratory Mixes Evaluation to Full Scale Test: Fatigue Behavior of Bio-Materials Recycled Asphalt Mixtures
2020
The present paper describes the full-scale accelerated test, carried out on asphalt pavements made up with bio-materials, especially designed to help reusing Reclaimed Asphalt (RA) by re-activating the aged binder. Four pavement sections were evaluated: three pavement sections with innovative bio-materials (bio-recycled asphalt mixtures), and a reference section with a conventional, high modulus asphalt mix (EME2). In this study, fatigue resistance was first evaluated in laboratory, with two-points bending test, and then at full scale under heavy traffic loading, with the IFSTTAR accelerated pavement testing facility. The evolution of bio-materials recycled asphalt mixture characteristics, …
Bio‐based Materials
2021
Effect of two novel bio-based rejuvenators on the performance of 50% RAP mixes - a statistical study on the complex modulus of asphalt binders and as…
2019
An experimental study was conducted to evaluate the effectiveness of two bio-additives as rejuvenators on the properties of asphalt mixtures containing 50% RAP and their binder constituents containing 37% RAP binder. Before mixing, the rejuvenators were blended with fresh bitumen and the extracted and recovered RAP bitumen, and changes in the rheological properties of the binders were assessed using performance grading (PG) criteria. The results showed that both rejuvenators could improve the low-temperature performance of the aged RAP binder and restore its low-temperature properties. Master curves for the unaged, RTFO-aged, and PAV aged blends were constructed using both the Christensen-A…
A methodology to assess the energetic valorization of bio-based polymers from the packaging industry: pyrolysis of reprocessed polylactide
2012
The energetic valorization process of bio-based polymers is addressed in this study, taking polylactide (PLA) as model. The pyrolysis of virgin and multiple-injected PLA was simulated by means of multi-rate linear-non-isothermal thermogravimetric experiments. A complete methodology, involving control of gases, thermal stability and thermal decomposition kinetics was proposed. The release of gases was monitored by Evolved Gas Analysis of the fumes of pyrolysis, by in-line FT-IR, with the aid of 2D-correlation IR characterization. A novel model to establish the thermal stability of PLAs under any linear heating profile was proposed. A kinetic strategy was methodically applied to assess the th…
Synthèse et réactivité chimiques et électrochimiques de dérivés d'imidazoliums : vers des procédés éco-responsables
2015
This work deals with the use of electrochemistry as a tool for alternative synthesis of new azolium-based molecules.A new electrosynthesis method was developed for the synthesis of imidazolium carboxylates (masked carbenes) leading to a wide library of compounds. This approach was compared to already reported chemical syntheses. In the current context of sustainable development, bio based products have been synthesized and optimization of the process was achieved in order to reduce waste and energy consumption.The key role of the hydrogenoxalate anion was demonstrated in the synthesis of ionic liquids and/or imidazolium salts. Some of them were employed as recyclable catalysts for Fischer e…
Anionic Polymerization of Terpene Monomers: New Options for Bio-Based Thermoplastic Elastomers
2021
Bio materials with reclaimed asphalt: from lab mixes properties to non-damaged full scale monitoring and mechanical simulation
2019
Three innovative environmentally friendly pavement materials, designed with 50% of Reclaimed Asphalt and three different biomaterials (2 bio-additivated bitumens and 1 bio-binder), were produced in an industrial plant. These mixes were tested in lab and also at full scale using an Accelerated Pavement Test facility. The asphalt mix viscoelastic properties were measured in lab and their intrinsic viscoelastic response were simulated. These rheological models are used to simulate the pavement mechanical response using both elastic and viscoelastic multilayer codes. Hence, full scale measurement performed during the full scale test at an early stage (without damages) can be compared with these…
Influence of bio-based additives on RAP clustering and asphalt binder rheology
2017
The use of high Reclaimed Asphalt Pavement (RAP) content in Hot Mix Asphalt (HMA) allows developing innovative materials for the construction and/or rehabilitation of sustainable infrastructures. The chemo-physical phenomena occurring during production of HMA containing high RAP content should be investigated and considered for the mix design optimization. In fact, when additives are used as rejuvenators of the aged bitumen, these phenomena can be affected causing significant variations in the mixture characteristics. This paper aims at studying the influence of two bio-based additives specifically on RAP clustering, phenomena which can significantly affect the performance of high-content R…
Myrcenol-Based Monomer for Carbanionic Polymerization: Functional Copolymers with Myrcene and Bio-Based Graft Copolymers
2020
A bio-based hydroxyl group-containing diene monomer, silyl-protected β-myrcenol (MyrOSi), is introduced to the field of carbanionic polymerization. Polymerization in cyclohexane, using sec-butyllit...
Thermal characterisation of Bio Based Building Materials
2006
This paper describes how the characterization of indigenous renewable biomass sources that are applicable for making bio-based building (BBB) materials is crucial as it can significantly affect the cost of production and the quality of material. Nowadays, in any specific area, wide ranges of biomass sources are usually available but only a few sources may be suitable for making BBB material. Therefore the suited sources should be determined. In this paper, the use of BBB materials is focused on Insulation Materials which are widely used in the buildings. Compared with currently used materials, these materials are bio-degradable. Insulation material with a good energy-adsorbing property and …