Search results for "Biomimetics"

showing 10 items of 54 documents

Visualization of RNA-Quadruplexes in Live Cells

2015

Visualization of DNA and RNA quadruplex formation in human cells was demonstrated recently with different quadruplex-specific antibodies. Despite the significant interest in these immunodetection approaches, dynamic detection of quadruplex in live cells remains elusive. Here, we report on NaphthoTASQ (N-TASQ), a next-generation quadruplex ligand that acts as a multiphoton turn-on fluorescent probe. Single-step incubation of human and mouse cells with N-TASQ enables the direct detection of RNA-quadruplexes in untreated cells (no fixation, permeabilization or mounting steps), thus offering a unique, unbiased visualization of quadruplexes in live cells.

Static ElectricityMelanoma ExperimentalLigands010402 general chemistryG-quadruplex01 natural sciencesBiochemistryCatalysisMice03 medical and health scienceschemistry.chemical_compoundColloid and Surface ChemistryBiomimeticsCationsCell Line TumorFluorescence Resonance Energy TransferAnimalsHumans[CHIM]Chemical Sciences[SDV.BBM]Life Sciences [q-bio]/Biochemistry Molecular Biologyheterocyclic compoundsComputingMilieux_MISCELLANEOUSChelating AgentsFluorescent Dyes030304 developmental biologyPhotons[SDV.GEN]Life Sciences [q-bio]/Genetics0303 health sciencesbiologyChemistryRNADNAGeneral ChemistryFluorescenceMolecular biology3. Good health0104 chemical sciencesCell biologyVisualizationG-QuadruplexesFörster resonance energy transferMicroscopy FluorescenceCell cultureMCF-7 Cellsbiology.proteinRNAAntibodyDNAJournal of the American Chemical Society
researchProduct

Dynamics of Pattern Formation in Biomimetic Systems

2008

This paper is an attempt to conceptualize pattern formation in self-organizing systems and, in particular, to understand how structures, oscillations or waves arise in a steady and homogenous environment, a phenomenon called symmetry breaking. The route followed to develop these ideas was to couple chemical oscillations produced by Belousov-Zhabotinsky reaction with confined reaction environments, the latter being an essential requirement for any process of Life. Special focus was placed on systems showing organic or lipidic compartments, which represent more reliable biomimetic matrices.

Statistics and Probability{CHEMICAL} {OSCILLATORS}Belousov-Zhabotinsky reactionLipid BilayersPattern formationNanotechnology{CHEMICAL} {OSCILLATORS}; Lipid systems; Reverse microemulsionsModels BiologicalTuring structuresGeneral Biochemistry Genetics and Molecular BiologyDiffusionBiomimeticsChemical oscillatorsAnimalsSymmetry breakingPhysicsGeneral Immunology and MicrobiologyChemistry PhysicalSystems BiologyApplied MathematicsLipid systemsBiomimetic systemsGeneral MedicineBelousov-Zhabotinsky reaction; Chemical oscillators; Turing structures; Biomimetic systems; Lipid systems; Reverse microemulsionsReverse microemulsionsBelousov–Zhabotinsky reactionModeling and SimulationEmulsionsGeneral Agricultural and Biological SciencesBiological system
researchProduct

Biomimetic synthesis of the tumor-associated (2,3)-sialyl-T antigen and its incorporation into glycopeptide antigens from the mucins MUC1 and MUC4.

2004

Glycoproteins on epithelial tumor cells often exhibit aberrant glycosylation profiles. The incomplete formation of the glycan side chains resulting from a down-regulated glucosamine transfer and a premature sialylation results in additional peptide epitopes, which become accessible to the immune system in mucin-type glycoproteins. These cancer-specific structure alterations are considered to be a promising basis for selective immunological attack on tumor cells. Among the tumor-associated saccharide antigens, the (2,3)-sialyl-T antigen has been identified as the most abundant glycan, found in several different carcinoma cell lines. According to a linear biomimetic strategy, the (2,3)-sialyl…

ThreonineGlycanMagnetic Resonance SpectroscopyMolecular Sequence DataCancer VaccinesCatalysisEpitopeMass SpectrometryImmune systemAntigenAntigens NeoplasmBiomimeticsMUC1Chromatography High Pressure LiquidGlycoproteinschemistry.chemical_classificationbiologyMucin-4Organic ChemistryMucinMucin-1GlycopeptidesMucinsGeneral ChemistryGlycopeptidecarbohydrates (lipids)chemistryBiochemistryCarbohydrate SequenceTandem Repeat Sequencesbiology.proteinIndicators and ReagentsGlycoproteinChemistry (Weinheim an der Bergstrasse, Germany)
researchProduct

Biologically inspired information processing and synchronization in ensembles of non-identical threshold-potential nanostructures.

2013

Nanotechnology produces basic structures that show a significant variability in their individual physical properties. This experimental fact may constitute a serious limitation for most applications requiring nominally identical building blocks. On the other hand, biological diversity is found in most natural systems. We show that reliable information processing can be achieved with heterogeneous groups of non-identical nanostructures by using some conceptual schemes characteristic of biological networks (diversity, frequency-based signal processing, rate and rank order coding, and synchronization). To this end, we simulate the integrated response of an ensemble of single-electron transisto…

Time FactorsTransistors ElectronicScienceMaterials ScienceMonte Carlo methodSynchronizationMaterial by AttributeSet (abstract data type)BiomimeticsImage Processing Computer-AssistedNanotechnologyBiologyNanomaterialsComputational NeurosciencePhysicsCoding MechanismsSignal processingMultidisciplinaryQInformation processingRComputational BiologySignal Processing Computer-AssistedSensory SystemsNanostructuresBionanotechnologyElectronic MaterialsProbability distributionMedicineBiological systemMonte Carlo MethodRealization (systems)Biological networkResearch ArticleBiotechnologyNeurosciencePLoS ONE
researchProduct

Inverse Tone Mapping Based upon Retina Response

2014

International audience; The development of high dynamic range (HDR) display arouses the research of inverse tone mapping methods, which expand dynamic range of the low dynamic range (LDR) image to match that of HDR monitor. This paper proposed a novel physiological approach, which could avoid artifacts occurred in most existing algorithms. Inspired by the property of the human visual system (HVS), this dynamic range expansion scheme performs with a low computational complexity and a limited number of parameters and obtains high-quality HDR results. Comparisons with three recent algorithms in the literature also show that the proposed method reveals more important image details and produces …

[INFO.INFO-AR]Computer Science [cs]/Hardware Architecture [cs.AR]Computational complexity theoryArticle SubjectComputer sciencemedia_common.quotation_subjectComputingMethodologies_IMAGEPROCESSINGANDCOMPUTERVISIONlcsh:MedicineTone mappinglcsh:TechnologyRetinaGeneral Biochemistry Genetics and Molecular BiologyImage (mathematics)BiomimeticsDistortionImage Interpretation Computer-AssistedHumansContrast (vision)Computer visionlcsh:ScienceHigh dynamic rangeGeneral Environmental Sciencemedia_commonDynamic rangebusiness.industrylcsh:Tlcsh:RGeneral MedicineImage EnhancementHuman visual system modellcsh:QArtificial intelligence[ INFO.INFO-AR ] Computer Science [cs]/Hardware Architecture [cs.AR]businessAlgorithmsColor PerceptionResearch ArticleThe Scientific World Journal
researchProduct

Harnessing nature's insights: synthetic small molecules with peroxidase-mimicking DNAzyme properties.

2011

International audience

biology010405 organic chemistryOrganic ChemistryDeoxyribozymeNanotechnologyGeneral Chemistry[CHIM.CATA]Chemical Sciences/CatalysisDNA Catalytic010402 general chemistry01 natural sciencesSmall moleculeCatalysis0104 chemical scienceschemistry.chemical_compoundHeterocyclic Compounds 1-RingchemistryPeroxidasesBiomimetic MaterialsBiomimeticsbiology.proteinBioorganic chemistryHeminComputingMilieux_MISCELLANEOUSHeminPeroxidaseChemistry (Weinheim an der Bergstrasse, Germany)
researchProduct

A Step into the Future: Applications of Nanoparticle Enzyme Mimics.

2018

We describe elementary concepts, up-to-date developments, and perspectives of the emerging field of nanoparticle enzyme mimics (so-called "nanozymes") at the interface of chemistry, biology, materials, and nanotechnology. The design and synthesis of functional enzyme mimics is a long-standing goal of biomimetic chemistry. Metal complexes, polymers and engineered biomolecules capturing the structure of natural enzymes or their active centers have been made to achieve high rates and enhanced selectivities. Still, the design of new "artificial enzymes" that are not related to proteins but with capacity of production and stability at industrial level, remains a goal. Inorganic nanoparticles bea…

chemistry.chemical_classificationHigh rateBiomoleculeOrganic ChemistryIrregular shapeNanoparticleProteinsNanotechnology02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesCatalysis0104 chemical sciencesNanomaterialsEnzymesEnzymechemistryBiomimeticsCoordination ComplexesNanoparticlesNanotechnology0210 nano-technologyInorganic nanoparticlesChemistry (Weinheim an der Bergstrasse, Germany)
researchProduct

Increased conformational rigidity of humic substances by oxidative biomimetic catalysis

2005

A synthetic water-soluble meso-tetra(2,6-dichloro-3-sulfonatophenyl)porphyrinate of iron(III) chloride, Fe(TDCPPS)Cl, was employed as a biomimetic catalyst in the oxidative coupling of terrestrial humic materials. High-performance size-exclusion chromatography (HPSEC), solid-state nuclear magnetic resonance (CPMAS-(13)C NMR), electron paramagnetic resonance (EPR), and diffuse reflectance infrared spectroscopy (DRIFT) were used to follow conformational and structural changes brought about in different humic materials by the oxidative coupling. Increase in apparent weight-average molecular weight (Mw(a)) occurred invariably for all humic substances with the oxidative polymerization catalyzed …

conformationMagnetic Resonance SpectroscopySpectrophotometry InfraredPolymers and PlasticsDiffuse reflectance infrared spectroscopy (DRIFT)Biomimetic materialsaromatic compoundgel permeation chromatographyMolecular ConformationPhotochemistryIron compoundslaw.inventionPolymerizationenvironmental managementcovalent bondlawSize exclusion chromatographyBiomimetic catalysisBiomimeticsMaterials ChemistryOrganic chemistryHumic acidElectron paramagnetic resonanceInfrared spectroscopyChromatography High Pressure Liquidchemistry.chemical_classificationSettore CHIM/03 - Chimica Generale e InorganicaCarbon IsotopesChromatographyindustryCatalystsChemistrytetra(2articleelectrophoretic mobilitybiomimetic materialNuclear magnetic resonance spectroscopyunclassified drugConformationsacetic acidpriority journalCovalent bondSpectrophotometrySynthesis (chemical)High Pressure Liquidtechnology6 dichloro 3 sulfonatophenyl)porphyrinic acid derivativeInfraredOxidation-Reductionmolecular stabilityHumic materialsoxidationSettore AGR/13 - Chimica AgrariaSupramolecular chemistryBioengineeringcomplex mixturesCatalysisCatalysisdiffuse reflectance spectroscopyhumic substanceBiomaterialsalkyl etherElectron spin resonance spectroscopycomplex formationParticle SizeNuclear magnetic resonance spectroscopyHumic Substancesfree radicalbiomimetic oxidative humicelectron spin resonanceHigh performance size exclusion chromatography (HPSEC)ferrous chloridemolecular weightsolid statecarbon nuclear magnetic resonancePolymerizationSolubilitychemical structureOxidative coupling of methaneCatalysts; Conformations; Electron spin resonance spectroscopy; Infrared spectroscopy; Iron compounds; Nuclear magnetic resonance spectroscopy; Oxidation; Polymerization; Size exclusion chromatography; Solubility; Synthesis (chemical); Biomimetic catalysis; Diffuse reflectance infrared spectroscopy (DRIFT); High performance size exclusion chromatography (HPSEC); Humic materials; Biomimetic materials; acetic acid; alkyl ether; aromatic compound; biomimetic material; ferrous chloride; free radical; tetra(26 dichloro 3 sulfonatophenyl)porphyrinic acid derivative; unclassified drug; article; carbon nuclear magnetic resonance; catalysis; catalyst; chemical structure; complex formation; conformation; covalent bond; diffuse reflectance spectroscopy; electron spin resonance; electrophoretic mobility; environmental management; gel permeation chromatography; humic substance; industry; molecular stability; molecular weight; oxidation; polymerization; priority journal; solid state; technology; Biomimetics; Carbon Isotopes; Catalysis; Chromatography High Pressure Liquid; Electron Spin Resonance Spectroscopy; Humic Substances; Magnetic Resonance Spectroscopy; Molecular Conformation; Oxidation-Reduction; Particle Size; Spectrophotometry Infraredcatalyst
researchProduct

Biomimetic strategy towards gelatin coatings on PET. Effect of protocol on coating stability and cell-interactive properties

2019

Gelatin-modified poly(ethylene terephthalate) (PET) surfaces have been previously realized via an intermediate dopamine coating procedure that resulted in surfaces with superior haemocompatibility compared to unfunctionalized PET. The present study addresses the biocompatibility assessment of these coated PET surfaces. In this context, the stability of the gelatin coating upon exposure to physiological conditions and its cell-interactive properties were investigated. The proposed gelatin–dopamine-PET surfaces showed an increased protein coating stability up to 24 days and promoted the attachment and spreading of both endothelial cells (ECs) and smooth muscle cells (SMCs). In parallel, physi…

food.ingredientBiocompatibilityCellBiomedical Engineering02 engineering and technologyengineering.material010402 general chemistry01 natural sciencesGelatinfoodCoatingSmooth muscleBiomimeticsmedicineGeneral Materials ScienceChemistryPolyethylene TerephthalatesGeneral ChemistryGeneral Medicine021001 nanoscience & nanotechnology0104 chemical sciencesPolyestermedicine.anatomical_structureengineeringSurface modificationGelatin0210 nano-technologyVascular graftBiomedical engineeringSURFACE MODIFICATION; CHEMISTRY; POLYESTER; ADHESION; FUNCTIONALIZATION; BIOCOMPATIBILITY; IMMOBILIZATION; PROLIFERATION; COMPATIBILITY; BIOMATERIALS
researchProduct

Visual learning in Drosophila: Application on a roving robot and comparisons

2011

Visual learning is an important aspect of fly life. Flies are able to extract visual cues from objects, like colors, vertical and horizontal distributedness, and others, that can be used for learning to associate a meaning to specific features (i.e. a reward or a punishment). Interesting biological experiments show trained stationary flying flies avoiding flying towards specific visual objects, appearing on the surrounding environment. Wild-type flies effectively learn to avoid those objects but this is not the case for the learning mutant rutabaga defective in the cyclic AMP dependent pathway for plasticity. A bio-inspired architecture has been proposed to model the fly behavior and experi…

genetic structuresPunishment (psychology)business.industryeducationfungiDrosophila; Hybrid robot; Spiking neurons; STDP; Visual cue-based navigationBiologySpiking neuronsbiology.organism_classificationSTDPVisual ObjectsHybrid robotRobotComputer visionDrosophilaArtificial intelligenceBiomimeticsVisual cue-based navigationbusinesscomputerDrosophilaVisual learningSensory cuecomputer.programming_language
researchProduct