Search results for "Biomonitoring"
showing 10 items of 200 documents
Biomonitoring of Enniatin B1 and Its Phase I Metabolites in Human Urine: First Large-Scale Study
2020
Enniatins (Enns) are mycotoxins produced by Fusarium spp. which are a fungus widely spread throughout cereals and cereal-based products. Among all the identified enniatins, Enn B1 stands as one of the most prevalent analogues in cereals in Europe. Hence, the aim of this study was to evaluate for the first time the presence of Enn B1 and its phase I metabolites in 300 human urine samples using an ultrahigh-performance liquid chromatography high resolution mass spectrometry (UHPLC-Q-Orbitrap HRMS) methodology. Enn B1 was detected in 94.3% of samples ranging from 0.007 to 0.429 ng/mL (mean value: 0.065 ng/mL). In accordance with previous in vitro and in vivo analysis, hydroxylated metabolites …
Brominated flame retardants and organochlorines in the European environment using great tit eggs as a biomonitoring tool
2009
Large-scale studies are essential to assess the emission patterns and spatial distribution of organohalogenated pollutants (OHPs) in the environment. Bird eggs have several advantages compared to other environmental media which have previously been used to map the distribution of OHPs. In this study, large-scale geographical variation in the occurrence of OHPs, such as polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs) and organochlorine pesticides (OCPs), was investigated throughout Europe using eggs of a terrestrial residential passerine species, the great tit (Parus major). Great tit eggs from 22 sampling sites, involving urban, rural and remote areas, in 14 Europea…
Geothermal mercury output at Nisyros Volcano (Greece)
2019
Nisyros (Greece) is an active volcano in the eastern part of the South Aegean Active Volcanic Arc (SAAVA), hosting a high-enthalpy geothermal system. On June 2013, an extensive survey on Hg concentrations in different types of matrices (fumarolic fluids, atmosphere, soils and plants) was carried out at Lakki plain, an area affected by widespread soil degassing and fumarolic manifestations. To investigate the spatial distribution of mercury emission and its possible relationships with diffuse degassing of hydrothermal fluids, Hg concentrations in soils were related to their physicochemical parameters (e.g. temperature, soil-pH, hydrothermal gases and elemental C, N and S concentrations). Fur…
Biomarkers, matrices and analytical methods targeting human exposure to chemicals selected for a European human biomonitoring initiative
2020
E-mail addresses: kvo@envs.au.dk (K. Vorkamp), Castano@isciii.es (A. Castaño), Jean-Philippe.Antignac@oniris-nantes.fr (J.-P. Antignac), Luis.Boada@ulpgc.es (L.D. Boada), ECequier@quimica.udl.cat (E. Cequier), Adrian.Covaci@uantwerpen.be (A. Covaci), M.Esteban@isciii.es (M. Esteban López), LineSmastuen.Haug@fhi.no (L.S. Haug), Kasper@ipa-dguv.de (M. Kasper-Sonnenberg), Koch@ipa-dguv.de (H.M. Koch), Octavio.Perez@ulpgc.es (O. Pérez Luzardo), Agnese.Osite@lu.lv (A. Osīte), Loic.Rambaud@santepubliquefrance.fr (L. Rambaud), mtpin@ticino.com (M.-T. Pinorini), Gabriele.Sabbioni@bluewin.ch (G. Sabbioni), Cathrine.Thomsen@fhi.no (C. Thomsen).; International audience; The major purpose of human biom…
Country-specific correlations across Europe between modelled atmospheric cadmium and lead deposition and concentrations in mosses
2012
Previous analyses at the European scale have shown that cadmium and lead concentrations in mosses are primarily determined by the total deposition of these metals. Further analyses in the current study show that Spearman rank correlations between the concentration in mosses and the deposition modelled by the European Monitoring and Evaluation Programme (EMEP) are country and metal-specific. Significant positive correlations were found for about two thirds or more of the participating countries in 1990, 1995, 2000 and 2005 (except for Cd in 1990). Correlations were often not significant and sometimes negative in countries where mosses were only sampled in a relatively small number of EMEP gr…
Spectrum of styrene-induced DNA adducts: the relationship to other biomarkers and prospects in human biomonitoring.
2002
Styrene is an important industrial chemical that has shown genotoxicity in many toxicology assays. This is believed to be related to the DNA-binding properties of styrene-7,8-oxide (SO), a major metabolite of styrene. In this review, we have summarized knowledge on various aspects of styrene genotoxicity, especially in order to understand the formation and removal of primary DNA lesions, and the usefulness of biomarkers for risk assessment. Biological significances of specific DNA adducts and their role in the cascade of genotoxic events are discussed. Links between markers of external and internal exposure are evaluated, as well as metabolic aspects leading to the formation of DNA adducts …
Distribution and air-sea exchange of mercury (Hg) in polluted marine environments
2012
Mercury (Hg) is emitted in the atmosphere by anthropogenic and natural sources, these last accounting for one third of the total emissions. Since the pre-industrial age, the atmospheric deposition of mercury have increased notably, while ocean emissions have doubled owing to the re-emission of anthropogenic mercury. Exchange between the atmosphere and ocean plays an important role in cycling and transport of mercury. We present the preliminary results from a study on the distribution and evasion flux of mercury at the atmosphere/sea interface in the Augusta basin (SE Sicily, southern Italy), a semi-enclosed marine area affected by a high degree of contamination (heavy metals and PHA) due to…
Occurrence of palladium and platinum in human scalp hair of adolescents living in urban and industrial sites
2023
Platinum group elements (PGEs) can be naturally found at very low concentrations in the Earth's crust. However, the increasing uses of PGEs in vehicle exhaust catalysts, in addition to some other applications (industry, jewelry, anticancer drugs) cause their anthropogenic emission and dispersion in the environment. The use of human hair samples analysis is considered a suitable biological indicator to assess human occupational and environmental exposure. It is an easily accessible material for individuals or population groups of non-invasive sampling. The aim of this study is a comparative analysis to investigate human hair content of Pd and Pt in adolescents, of both genders, residing near…
Environmental impact of antifouling technologies: state of art and perspectives
2001
1. Marine fouling affects most man-made surfaces temporarily or permanently immersed in the sea, resulting in significant (or substantial) economic costs. Intense research is aimed at preventing or reducing fouling. 2. The most widespread solution to avoid fouling formation is to make surfaces unsuitable for settlers, coating them with antifouling (AF) paints containing toxic compounds. Most AF agents (e.g. tributyltin, (TBT)) have undesirable effects on non-target species, including commercially important organisms. 3. To date, the use of TBT in AF paints has been restricted (but not prohibited) in a number of countries and new biocides are in use. 4. The environmental problems posed to ma…
Exposure and cumulative risk assessment to non-persistent pesticides in Spanish children using biomonitoring.
2020
Abstract The main objective of the present research is to evaluate the exposure to pesticides in children (n = 568) from the Valencian Region (Spain). Six non-specific and 20 specific metabolites of organophosphate pesticides (OPs), herbicides (Herb), and pyrethroids (Pyr) were analyzed in urine samples. The biomarkers with the highest detection frequencies (>70%) were diethyl phosphate, p-nitrophenol, 3-phenoxybenzoic acid, and 3,5,6-trichloro-2-pyridinol, whose geometric mean concentrations (ng·ml-n1) were 1.53, 1.03, 1.51 and 1.19, respectively. Robust regression models showed that the province of residence and the recent consumption of vegetables, legumes and cereals were some of the mo…