Search results for "Blue"
showing 10 items of 487 documents
Experimental and theoretical study using DFT method for the competitive adsorption of two cationic dyes from wastewaters
2016
Abstract The adsorption of cationic dyes, Basic Yellow (BY28) and Methylene Blue (MB) on a new activated carbon from medlar species were studied in both single and binary system. Some experimental parameters, namely, pH, amount of adsorbent and contact time are studied. Quantum chemical results indicate that the adsorption efficiency was directly related to the dye electrophilicity power. Some theorical parameters were calculated and proved that MB is more electrophilic than BY28, than greatest interaction with surface sites. Kinetic study showed that the adsorption follows the pseudo-second-order model and Freundlich was the best model to describe the phenomenon in the single and binary sy…
Ionic and Free Solvent Motion in Poly(azure A) Studied by ac-Electrogravimetry
2011
International audience; This work is focused on the mechanistic aspects of the redox behavior of poly(azure A) taking advantage of the controlled modulation of their oxidation states by ac-electrogravimetry. The originality of this technique is its ability to discriminate between cation and anion involved in the charge compensation process and the accompanying free solvent transfer, directly or indirectly. Two processes were proposed where the faster ionic exchange is considered to be the participation of the anion species acting as counterions whereas the slower one is related to the proton transfer. The proton is implied as reactants for the two electroactive sites identified in the polym…
Performance Study of Non-beaconed and Beacon-Enabled Modes in IEEE 802.15.4 under Bluetooth Interference
2008
The IEEE 802.15.4 protocol is a flexible technology with great potential for wireless sensor networks applications. The standard distinguishes two network modes; beacon-enabled and nonbeacon-enabled. In this paper, the performance study of beaconed and non-beaconed modes of IEEE 802.15.4 is evaluated using on site PER measurements. The tests are carryout in an urban outdoor environment with commercial available equipment. Likewise, the impact of Bluetooth interference over IEEE 802.15.4 modes is evaluated. The results show that Bluetooth interference and the mode selected have effects over the PER. Furthermore, for distances between 3 to 10 meters the PER doesn't show significance distance …
The Influence of Systemic Hypertension on Intracranial Pressure and Edema Formation in Experimental Intracerebral Hemorrhage
1986
Systemic hypertension is not only the most frequent cause of intracerebral hemorrhage but also the most important complication of this disease. In our clinical investigation of 117 cases almost 70% of the patients suffered from systemic hypertension. Despite advances in diagnosis (Schiirmann, Dei Anang, 1980) mortality of hypertensive patients was 48%. Normotensive hemorrhages showed a better prognosis: only 31% of the patients died and 33% (17% in hypertensive patients) obtained good neurological recovery (Wallenfang et al., 1985).
Universally Designed Beacon-Assisted Indoor Navigation for Emergency Evacuations
2019
International audience; The United Nations (UN) Convention on the Rights of Persons with Disabilities (CRPD) obligates national governments to ensure the protection and safety of persons with disabilities in emergency situations. This article examines the application and accessibility of state-of-the-art ICT solutions in emergency situations. Research has indeed shown that the design and implementation of evacuation procedures in emergency situations play a critical role in ensuring personal safety and protection. While research has examined the experiences of persons including persons with disabilities in emergency situations, research has yet to examine fully the role that cutting-edge in…
Bright Blue Phosphorescence from Cationic Bis-Cyclometalated Iridium(III) Isocyanide Complexes
2012
We report new bis-cyclometalated cationic indium(III) complexes [((CN)-N-boolean AND)(2)Ir(CN-tert-Bu)(2)](CF3SO3) that have tert-butyl isocyanides as neutral auxiliary ligands and 2-phenylpyridine or 2-(4'-fluoropheny1)-R-pyridines (where R is 4-methoxy, 4-tert-butyl, or 5-trifluoromethyl) as (CN)-N-boolean AND ligands. The complexes are white or pale yellow solids that show irreversible reduction and oxidation processes and have a large electrochemical gap of 3.58-3.83 V. They emit blue or bluegreen phosphorescence in liquid/solid solutions from a cyclometalating-ligand-centered excited state. Their emission spectra show vibronic structure with the highest-energy luminescence peak at 440-…
Redox tuning and species distribution in Maya Blue-type materials: a reassessment.
2013
Maya Blue-type specimens prepared from indigo (1 wt %) plus kaolinite, montmorillonite, palygorskite, sepiolite, and silicalite are studied. Liquid chromatography with diode array detection, ultra-performance liquid chromatography coupled with mass spectrometry, and pyrolysis-silylation gas chromatography-mass spectrometry analyses of the extracts from these specimens combined with spectral and solid-state voltammetry, electrochemical impedance spectroscopy, and scanning electrochemical microscopy techniques provide evidence for the presence of a significant amount of dehydroindigo and isatin accompanying indigo and other minority organic compounds in all samples. Solid-state electrochemist…
The Atlantic bluefin tuna: structure and competitiveness of Italian fishing in the international trade
2012
In this paper after showing the productive and international trade background of the Atlantic bluefin tuna, we analyze the competitive position of Italy, important producer and exporter on world scale, compared with the main trade partners, carried out through competitiveness indexes based on trade data. The results highlight Italy's good competitive performance above all with Japan, which represents the main world reference market for the Italian product, but also with the United States, Malta and Turkey The Italian competitive advantage with these countries is stronger for the product taken into account. On the other hand, we can notice a competitive disadvantage with the traditional mark…
Prussian Blue Analogues of Reduced Dimensionality
2012
Abstract: Mixed-valence polycyanides (Prussian Blue analogues) possess a rich palette of properties spanning from room-temperature ferromagnetism to zero thermal expansion, which can be tuned by chemical modifications or the application of external stimuli (temperature, pressure, light irradiation). While molecule-based materials can combine physical and chemical properties associated with molecular-scale building blocks, their successful integration into real devices depends primarily on higher-order properties such as crystal size, shape, morphology, and organization. Herein a study of a new reduced-dimensionality system based on Prussian Blue analogues (PBAs) is presented. The system is …
Le preferenze dei consumatori verso i marchi e le etichette di qualità dei prodotti ittici
2022
Il consumo dei prodotti ittici è ormai sempre più analizzato per via delle implicazioni socio-economico-ambientali che da esso ne derivano. Se da un lato un maggiore consumo è sicuramente positivo in termini di salubrità, dall’altro mette in crisi il sistema ambiente per l’eccessivo sfruttamento degli stock ittici. Negli ultimi anni, vi è stata inoltre una progressiva crescita dell’attenzione del consumatore all’impatto ambientale dei processi produttivi con la conseguente maggiore presenza sul mercato di prodotti che utilizzando brand e label associati procedure certificate cercano di aggiungere alla qualità dei prodotti ittici percepita dai consumatori anche componenti che valorizzano pro…