Search results for "CERAMICS"
showing 10 items of 1599 documents
Grooving by Nd:YAG laser treatment
2000
Abstract The properties of the laser beam have been used to produce deep and thin grooves in metals, melted material being removed with the assistance of a high velocity gas. Preliminary experiments show that the geometry and the location of the gas inlet tube are the main parameters governing the evacuation of the scoria. The influence of the nature of the materials on the depth of the grooves is discussed from examination of the grooves realized on various metals (copper, aluminum, titanium,…). Finally, a statistical study is performed to indicate the parameters that have to be controlled to secure regular grooves. It appears that the groove width is not too much affected by parameter var…
Very strong −N–X+⋯−O–N+ halogen bonds
2016
A new (-)N-X(+)(-)O-N(+) paradigm for halogen bonding is established by using an oxygen atom as an unusual halogen bond acceptor. The strategy yielded extremely strong halogen bonded complexes with very high association constants characterized in either CDCl3 or acetone-d6 solution by (1)H NMR titrations and in the solid-state by single crystal X-ray analysis. The obtained halogen bond interactions, RXB, in the solid-state are found to be in the order of strong hydrogen bonds, viz. RXB ≈ RHB.
Heat capacity and thermal conductivity of multiferroics Bi1-xPrxFeO3
2019
The heat capacity and thermal conductivity of multiferroics Bi1–xPrxFeO3 (0 ≤ x ≤ 0.50) has been studied in the temperature range of 130–800 K. A slight substitution of praseodymium for bismuth is found to lead to a noticeable shift of the antiferromagnetic phase transition temperature whilst the heat capacity increases. The temperature dependences of the heat capacity and thermal conductivity exhibit additional anomalies during phase transitions. The experimental results suggest that the excess heat capacity can be attributed to the Schottky effect for three-level states. The basic mechanisms of the heat transfer of phonons are highlighted and the dependence of the mean free path on temper…
Biological Effects of New Hydraulic Materials on Human Periodontal Ligament Stem Cells.
2019
Background: The aim of this study was: to evaluate the biological properties of new hydraulic materials: Bio-C Repair and Bio-C Sealer. Methods: Periodontal ligament stem cells were exposed to several dilutions of Bio-C Repair and Bio-C Sealer. The ion release profile and pH were determined. Metabolic activity, cell migration and cell survival were assessed using the 3-(4, 5-dimethylthiazol-2-yl)-2, 5-diphenyltetrazolium bromide (MTT), wound-healing assays and Annexin assays, respectively. Cells were cultured in direct contact with the surface of each material. These were then analyzed via scanning electron microscopy (SEM) and energy dispersive X-ray (EDX). Statistical differences were ass…
Effect of in Doping on the ZnO Powders Morphology and Microstructure Evolution of ZnO:In Ceramics as a Material for Scintillators
2018
Transparent ZnO ceramics are of interest for use as material for high-efficiency fast scintillators. Doping ZnO ceramics in order to improve complex of their properties is a promising direction. In the present research, the role of indium in the ZnO nanopowders surface interactions and in the change of microstructures and photoluminescence (PL) characteristics of sintered cera-mics is considered. Undoped and 0.13 wt% In doped ZnO ceramics are obtained by hot pressing sintering. It has been found that indium leads to the transition of initially faceted ZnO particles to rounded, contributing to good sintering with formation of diffusion active grain boundaries (GBs). Unlike ZnO ceramics, ZnO:…
La evolución energética del sector español de baldosas cerámicas
2014
espanolEl presente texto analiza como ha ido evolucionando el consumo y la eficiencia energetica de la industria espanola de baldosas ceramicas durante el siglo XX, y explora las posibilidades que se le plantean en el siglo XXI. Durante el pasado siglo este sector industrial acometio tres transiciones radicales al pasar de los combustibles tradicionales de biomasa a los hidrocarburos liquidos (fueloleo y gasoleo), y posteriormente a los gaseosos, principalmente gas natural. Aunque la informacion que permite evaluar de manera fiable la eficiencia energetica real en las plantas de fabricacion no es facil de obtener, los datos disponibles indican que se ha llegado a una elevada eficiencia con …
The technological evolution of the Castellón ceramic tile district: the contribution of the frit, glaze and colour industry
2008
[EN]: The industrial district of Castellón is characterized by a great dynamism based on technological innovation, both product and process, the origins of which are to be found on its providers, the machinery industry and the frit, glaze and colours industry. In this paper the current situation of the frit, glaze and colour industry is analyzed, accounting also for the situation of its main European competitor in Italy. The formation and development of the industry is also described in relation to the industrial district and the innovation system where it belongs, together with the R&D activity, the innovation activity, and the main technological milestones that have made it become the wor…
Asymmetric [N–I–N]+halonium complexes in solution?
2020
Assessment of the solution equilibria of [bis(pyridine)iodine(I)]+ complexes by ESI-MS and NMR reveals the preference of iodine(I) to form complexes with a more basic pyridine. Mixtures of symmetric [bis(pyridine)iodine(I)]+ complexes undergo statistical ligand exchange, with a predominant entropic driving force favoring asymmetric systems. The influence of ligand basicity, concentration, temperature, and ligand composition is evaluated. Our findings are expected to facilitate the investigations, and the supramolecular and synthetic applications of halonium ions’ halogen bonds. peerReviewed
Potent affinity material for tracing acetone and related analytes based on molecular recognition by halogen bonds.
2014
Affinity materials based on halogen bonds turned out to be a powerful tool for the molecular recognition of acetone or related carbonyl compounds in the presence of ubiquitous protic molecules. The superior selectivity and sensitivity were found by the gravimetric detection of volatile organic compounds by quartz crystal microbalances.
Structural Changes of Titanium Oxide Induced by Chromium Addition as Determined by an X-Ray Diffraction Study
1995
Abstract An X-ray diffraction study has been carried out on a series of polycrystalline TiO 2 (anatase) catalysts containing Cr(III) at different atomic concentrations (0.2-5.0 at. %), prepared by a co-precipitation method. Analysis of the variation of the unit cell parameters of chromium-doped anatase with respect to pure anatase has allowed us to estimate the solubility limit for the system at around 1.4 at. %. There is no evidence for the existence of a separate crystalline chromium oxide phase. Temperature effects on the cell parameter and on the anatase-rutile transformation rate were also analyzed. An increase in temperature produced release of the chromium from the solid solution. At…