Search results for "CERAMICS"
showing 10 items of 1599 documents
Chromo-fluorogenic BODIPY-complexes for selective detection of V-type nerve agent surrogates
2014
Two new Eu3+ and Au3+ BODIPY-complexes capable of chromofluorogenically detecting micromolar concentrations of V-type nerve agent surrogates by a simple displacement assay are described
Modulating the reaction pathway of phenyl diazonium ions using host–guest complexation with cucurbit[7]uril
2022
Aryl diazonium ions are known to be an important intermediate in the divergent synthesis of azo compounds and substituted aromatics. The presence of more than one electrophilic center in a diazonium ion could lead to undesirable side reactions during a synthesis. Herein, we report that the electrophilic α-carbon on a phenyl diazonium [PhN2]+ ion can be selectively deactivated upon host–guest complexation with cucurbit[7]uril (CB7) in aqueous media, achieving a ∼60-fold increase in the half-life of [PhN2]+. Notably, however, the electrophilic nitrogen of the encapsulated diazonium ion remains active towards diazo coupling with strong nucleophiles, allowing the formation of azo compounds usin…
Increasing the nuclearity and spin ground state in a new family of ferromagnetically-coupled {Ni10} disk-like complexes bearing exclusively end-on br…
2018
The synthesis of a new family of ferromagnetically-coupled {Ni10} clusters counterbalanced by various [Ln(NO3)5]2− ions is herein described. The resulting compounds are organic chelate-free and the metal ions are exclusively bridged by end-on azido ligands to stabilize a beautiful disk-like topology reminiscent of the structure of the brucite mineral.
Photoluminescence quantum yield exceeding 80% in low dimensional perovskite thin-films via passivation control
2017
Quasi-2D perovskites with the BA : MA molar ratio equal to 3 : 3 show a remarkable PLQY exceeding 80%, thanks to the use of an electron donor as the passivating agent. These films have been applied in LEDs that exhibit high brightness exceeding 1000 cd m−2 and current efficiencies >3 cd A−1.
Formation of an unprecedented (CuBr)5 cluster and a zeolite-type 2D-coordination polymer: a surprising halide effect
2013
A unique pentanuclear cluster within a zeolite-type polymer ([Cu5(μ4-Br)(μ3-Br)2(μ2-Br)2](μ2-MeSPr)3)n (1; void space >81%) and a luminescent 1D ([Cu(μ3-I)]4(MeSPr)3)n polymer, 2, are formed when MeSPr reacts with CuBr and CuI.
An 8-year prospective clinical investigation on the survival rate of feldspathic veneers: Influence of occlusal splint in patients with bruxism
2020
Este artículo se encuentra disponible en la siguiente URL: https://www.sciencedirect.com/science/article/abs/pii/S0300571220300944?via%3Dihub This is the pre-peer reviewed version of the following article: Faus-Matoses, V., Ruiz-Bell, E., Faus-Matoses, I., Özcan, M., Salvatore, S. & Faus-Llácer, VJ. An 8-year prospective clinical investigation on the survival rate of feldspathic veneers: influence of occlusal splint in patients with bruxism. Journal of Dentistry, vol. 99, art. 103352 (aug. 2020), which has been published in final form at https://doi.org/10.1016/j.jdent.2020.103352 Este es el pre-print del siguiente artículo: Faus-Matoses, V., Ruiz-Bell, E., Faus-Matoses, I., Özcan, M., Salv…
Building ceramics: Brick, tile, and clay
2022
Tiles for use in construction were made in quantity at Vagnari, as Alastair Small’s investigations made clear. He uncovered one tile kiln in the vicus area north of the ravine and five south of the ravine that were producing tiles from the 1st to the 4th century AD, although not all at the same time (Small 2011b: 231–64). There may well have been more, as yet undiscovered, kilns in and around the settlement, together with the requisite tile-making provisions, such as drying sheds or yards and large ponds or basins for mixing clay and water. Archaeologically explored and well-preserved tile-making facilities of local and regional importance in northeast Spain give us an idea of the complex p…
The effect of human osteoblasts on proliferation and neo-vessel formation of human umbilical vein endothelial cells in a long-term 3D co-culture on p…
2008
Angiogenesis is a key element in early wound healing and is considered important for tissue regeneration and for directing inflammatory cells to the wound site. The improvement of vascularization by implementation of endothelial cells or angiogenic growth factors may represent a key solution for engineering bone constructs of large size. In this study, we describe a long-term culture environment that supports the survival, proliferation, and in vitro vasculogenesis of human umbilical vein endothelial cells (HUVEC). This condition can be achieved in a co-culture model of HUVEC and primary human osteoblasts (hOB) employing polyurethane scaffolds and platelet-rich plasma in a static microenvir…
Preservation of dendritic cell function upon labeling with amino functionalized polymeric nanoparticles.
2010
Dendritic cells (DCs) are key players in eliciting immunity against antigens, therefore making them the focus of many investigations on immune responses in infections, cancer and autoimmune diseases. Nanosized materials have just recently been investigated for their use as carriers of antigens and as labeling agents for DCs. For this later use nanoparticles should be non-toxic and should most importantly not alter the physiological functions of DCs. Here we demonstrate that by the use of polymeric fluorescent nanoparticles as synthesized by the miniemulsion process immature DCs (iDCs) can be efficiently labeled intracellularly. Amino functionalized nanoparticles are more effective than carb…
Stable amorphous calcium oxalate: synthesis and potential intermediate in biomineralization.
2014
Amorphous calcium oxalate nanoparticles with sizes of 10–30 nm were synthesized at room temperature by the hydrolysis of a dimethyl oxalate from ethanol solution.