Search results for "CERAMICS"
showing 10 items of 1599 documents
Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated …
2004
Enantiomerically pure dirhodium(II) complexes with ortho-metalated p-substituted aryl phosphines have been shown to be enantio- and diastereoselective in the cyclopropanation of styrene by ethyl diazoacetate. Enantioselectivities up to 91% and diastereoselectivities up to 90% are observed for ethyl cis-2-phenylcyclopropanecarboxylate. Estevan Estevan, Francisco, Francisco.Estevan@uv.es ; Lahuerta Peña, Pascual, Pascual.lahuerta@uv.es ; Lloret Fillol, Julio, Julio.Lloret@uv.es ; Sanau Torrecilla, Mercedes, Mercedes.Sanau@uv.es ; Ubeda Picot, M Angeles, Angeles.Ubeda@uv.es ; Vila Gomez, Jaume Llorenc, Jaume.Vila@uv.es
Effectiveness of BFRP confinement on the compressive behaviour of clay brick masonry cylinders
2020
Abstract This paper presents the results of an experimental and analytical study on the compressive behaviour of small clay brick masonry cylinders reinforced with a basalt fibre reinforced polymer (BFRP) composite. Fourteen cylinders, manufactured using two assembling schemes and confined using either one or two layers of BFRP grids, were tested under monotonic compression loading. Traditional strain measuring systems were integrated with digital image correlation (DIC) technique. The BFRP confined masonry cylinders showed a ductile behaviour characterised by a softening branch of the stress–strain curve. The experimental strains, strength, and full stress–strain curves were modelled using…
On the mechanical behavior of BFRP to aluminum AA6086 mixed joints
2013
The aim of this work is to analyze the possibility to join aluminum alloy AA6086 and composite laminates reinforced with basalt fibers, an innovative material which use is growing in several applications as an alternative to glass fibers. To this goal, three joining techniques were investigated: mechanical by Self Piercing Riveting (in the next called SPR), adhesive by co-curing technique and mixed in which the joining techniques (i.e. adhesive and mechanical) were combined. Two manufacturing technologies (i.e. hand lay-up and vacuum bagging) were used both to produce composite substrates and to realize co-curing adhesion between the substrates to be joined. Mixed joints were realized by in…
Bilayer biodegradable films prepared by co-extrusion film blowing: Mechanical performance, release kinetics of an antimicrobial agent and hydrolytic …
2020
Abstract Bilayer biodegradable, eco-friendly films were prepared by co-extrusion film blowing, coupling polylactic acid (PLA) and Bio-flex ® (BIO). Furthermore, in the PLA layer, carvacrol (CRV) was added as a natural antimicrobial additive, whereas a nanoclay (D72T) was integrated to protect CRV from volatilization and to modulate release. The materials were analyzed by morphological, chemical-physical, mechanical testing. Furthermore, CRV release and degradation tests were performed. The results pointed out that coupling the two matrices allows gathering the stiffness of PLA with the ductility of BIO. Furthermore, the interlayer adhesion is promoted by CRV. D72T exerts a key-role in avoid…
On the response of flax fiber reinforced composites under salt-fog/dry conditions: Reversible and irreversible performances degradation
2022
Abstract Despite their scarce resistance to humid or wet conditions, natural fiber reinforced composites (NFRCs) seem to be able to partially recover their performances under discontinuous exposition to marine environment. To investigate this peculiarity, flax fiber reinforced composite was at first subjected to salt-fog spray condition at 35 °C for 15 and 30 days, respectively, and then stored in ‘‘dry” condition (i.e., 50% R.H. and 22 °C) between 0 and 21 days. The performances evolution was evaluated through flexural tests, water uptake and contact angle measurements. Moreover, the morphology of fractured mechanical samples was examined by using 3D optical microscope and scanning electro…
Photoinduced DNA damage efficiency and cytotoxicity of novel viologen linked pyrene conjugates.
2010
Novel viologen linked pyrene conjugates permeate cells efficiently and exhibit spacer length dependent DNA damage and cytotoxicity upon photoexcitation.
Oligonucleotide-capped mesoporous silica nanoparticles as DNA-responsive dye delivery systems for genomic DNA detection
2015
[EN] New hybrid oligonucleotide-capped mesoporous silica nanoparticles able to detect genomic DNA were designed.
Giovanni De Simone: Arte, Memoria e Territorio
2019
The essay analyses Giovanni De Simone's artistic career from the beginning to the last period of his production, contextualising it with the historical-artistic panorama of the period.
Synthesis of quadruped-shaped polyfunctionalized o-carborane synthons
2011
[EN] o-Carborane derivatives with precisely defined patterns of substitution have been prepared from 8,9,10,12-I-4-1,2-closo-C2B10H8 by replacing the iodine atoms, bonded to four adjacent boron vertices in the cluster, with allyl, and subsequently 3-hydroxypropyl groups. The resulting structures, comprising four pendant arms and two reactive vertices located on opposite sides of a central o-carborane core, can be envisaged as versatile precursors for dendritic growth
Amphiphilic Dendrimers Control Protein Binding and Corona Formation on Liposome Nanocarriers
2020
Amphiphilic polyphenylene dendrimers (PPDs) with distinct lipophilic and positively or negatively charged surface groups were adsorbed onto liposomes and their impact on protein adsorption in blood plasma was studied. The PPD corona reduced binding of specific opsonins and increased the adsorption of proteins controlling cellular uptake based on their surface patches.