Search results for "CLASSIFICATION."

showing 10 items of 29269 documents

Synthesis and biological evaluation of novel peptidomimetics as rhodesain inhibitors

2016

Novel rhodesain inhibitors were developed by combining an enantiomerically pure 3-bromoisoxazoline warhead with a 1,4-benzodiazepine scaffold as specific recognition moiety. All compounds were proven to inhibit rhodesain with Ki values in the low-micromolar range. Their activity towards rhodesain was found to be coupled to an in vitro antitrypanosomal activity, with IC50 values ranging from the mid-micromolar to a low-micromolar value for the most active rhodesain inhibitor (R,S,S)-3. All compounds showed a good selectivity against the target enzyme since all of them were proven to be poor inhibitors of human cathepsin L. Novel rhodesain inhibitors were developed by combining an enantiomeri…

rhodesainPharmacologychemistry.chemical_classificationCathepsinPeptidomimetic010405 organic chemistryChemistryPeptidomimeticProton Magnetic Resonance SpectroscopyenPeptidomimetics; rhodesain; trypanosomaGeneral Medicine01 natural sciencesCombinatorial chemistryIn vitro0104 chemical sciencesCysteine Endopeptidases010404 medicinal & biomolecular chemistryEnzymeDrug DiscoveryIc50 valuesMoietyPeptidomimeticsCarbon-13 Magnetic Resonance SpectroscopytrypanosomaBiological evaluationJournal of Enzyme Inhibition and Medicinal Chemistry
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Detection of natural killer T cells in mice infected with Rickettsia conorii.

2013

Little information is available regarding the role of natural killer T (NKT) cells during the early stage of Rickettsia conorii infection. Herein, C3H/HeN mice were infected with the Malish 7 strain of R. conorii. Splenocytes from these mice were analysed in the early stage of the infection by flow cytometry and compared with uninfected controls. Our results showed an increase in NKT cells in infected mice. Additionally, NKT interleukin (IL)-17(+) cells increased three days after infection, together with a concurrent decrease in the relative amount of NKT interferon (IFN)-γ(+) cells. We also confirmed a higher amount of NK IFN-γ(+) cells in infected mice. Taken together, our data showed tha…

rickettsiosis; interleukin 17; interferon-γchemical and pharmacologic phenomenaSpleenrickettsiosisBiologyBoutonneuse FeverFlow cytometryMiceInterferonmedicineAnimalsCells CulturedImmunity CellularMice Inbred C3HGeneral VeterinaryGeneral Immunology and Microbiologymedicine.diagnostic_testInterleukinGeneral Medicinemedicine.diseaseNatural killer T cellbiology.organism_classificationInterferon-γ; interleukin 17; rickettsiosisVirologyRickettsia conoriiRickettsiosismedicine.anatomical_structureImmunologyNatural Killer T-CellsInterferon-γInterleukin 17Rickettsia conoriiinterleukin 17Spleenmedicine.drugTransboundary and emerging diseases
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The Effect of Mechanocatalytic Pretreatment on the Structure and Depolymerization of Willow

2020

In this study, the effect of a mechanocatalytic pretreatment on the structure of willow and sugar release from pretreated willow was explored. In the mechanocatalytic approach, the pretreatment consists of solvent-free impregnation with sulfuric acid and a mechanical treatment with ball milling. Willow sawdust and pretreated samples were analyzed with field emission scanning electron microscope and X-ray diffraction. The products in the sugar solution were determined as the total reducing sugars with the 3,5-dinitrosalicylic acid method and monosaccharides with capillary electrophoresis. According to the results, milling increased the sugar production, depending on the sulfuric acid load. T…

rikkihappo020209 energyselluloosaWillow sawdustpajut02 engineering and technology010501 environmental sciencesXyloseesikäsittelylcsh:Chemical technologycomplex mixtures01 natural sciencesCatalysisHydrolysatepolymerointilcsh:ChemistryBall millingchemistry.chemical_compoundlignocellulose0202 electrical engineering electronic engineering information engineeringmechanocatalytic pretreatmentMonosaccharidelcsh:TP1-1185Physical and Theoretical ChemistrySugarBall mill0105 earth and related environmental scienceschemistry.chemical_classificationDepolymerizationSulfuric acidsulfuric aciddigestive oral and skin physiologytechnology industry and agriculturefood and beveragesSulfuric acidwillow sawdustlcsh:QD1-999chemistryvisual_artvisual_art.visual_art_mediumball millingSawdustLignocelluloseMechanocatalytic pretreatmentNuclear chemistryCatalysts
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Risk map of transmission of urogenital schistosomiasis by Bulinus truncatus (Audouin, 1827) (Mollusca Gastropoda, Bulinidae) in Spain and Portugal

2019

Mapa del riesgo de contraer schistosomiasis urogenital provocada por Bulinus truncatus (Audouin, 1827) (Mollusca Gastropoda, Bulinidae) en España y Portugal Se da a conocer el mapa de la distribución geográfica de Bulinus truncatus en España y Portugal en el que se recopilan las localidades históricas y actuales, que coincide con el mapa del riesgo de contraer schistosomiasis urogenital provocada por este caracol de agua dulce. Se revisan las muestras de esta especie depositadas en el Museu de Ciències Naturals de Barcelona y en el Museo de Ciencias Naturales de Madrid, así como datos propios, incluidas algunas aportaciones inéditas. Este mapa permitirá conocer el área óptima de esta especi…

risk mapBulinus truncatusSchistosomiasisMol·luscosBulinus truncatus; Bulinidae; Schistosomiasis urogenital; Mapa de riesgo; España; Portugallcsh:ZoologyGastropodaspainmedicinebulinus truncatusUrogenital Schistosomiasislcsh:QL1-991MolluscaFreshwater molluscNature and Landscape ConservationSchistosoma haematobiumbiologybulinidaeBulinus truncatus; Bulinidae; Urogenital schistosomiasis; Risk map; Spain; Portugalurogenital schistosomiasismedicine.diseasebiology.organism_classificationportugalMalalties parasitàriesGeographyRisk mapAnimal Science and ZoologyHumanitiesAnimal Biodiversity and Conservation
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Selection of spawning substratum by European river lampreys (Lampetra fluviatilis) in experimental tanks

2014

The selection of spawning substratum by the river lamprey (Lampetra fluviatilis) was studied in two experimental tanks with different flow conditions. In both tanks, four gravel sizes mixed with 15% sand were available to the test animals. In the tank with the lower current speed, lampreys selected in favour of the finest (2–8 mm) gravel size available against gravel sizes 4–20 mm and 8–40 mm. Selection was also significantly different in the tank with higher current speed where selection against the medium-sized substratum (4–20 mm) was evident, but there were no differences between selection for gravel sizes 2–8 mm, 2–40 mm and 8–40 mm relative to availability. Substratum selection and ob…

river lampreyPhysiologyLampreyspawninghabitatselectionsubstrateAquatic ScienceBiologyOceanographybiology.organism_classificationSubstrate (marine biology)FisheryCurrent (stream)Lampetra fluviatilisHabitatLampetraNestta1181Selection (genetic algorithm)Marine and Freshwater Behaviour and Physiology
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Classification of Venezuelan affiliates according to their conditions for the local environment

2007

El objetivo del artículo es proponer una clasificación de filiales venezolanas de empresas multinacionales según sus condiciones frente al entorno local. Para ello se usa una metodología cualitativa con estudios de ca-sos de filiales localizadas en Venezuela y se emplean como dimensiones el determinismo del entorno y la proactividad de la filial. Se identifican cuatro grupos de filiales: favorecidas, desfavorecidas, adaptadas y aventajadas. Se exponen los elementos que sirven para construir cada categoría, los efectos que se observaron en los roles de las filiales y las respuestas de los directivos en cada grupo, tanto en la filial como en la matriz, frente a las condiciones del entorno. Th…

rol estratégicostrategic roleclassificationentornoAffiliate abroadclasificaciónenvironmentfilial en el exterior
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Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines

2016

International audience; Direct unequal C-H bond difunctionalization of phosphorylated diamantane was achieved in high yield from the corresponding phosphonates. Reduction of the functionalized phosphonates provides access to novel primary and secondary alkyl/aryl diamantane phosphines. The prepared primary diamantyl phosphines are quite air stable compared to their adamantyl and especially alkyl or aryl analogues. This finding is corroborated by comparing the singly occupied molecular orbital energy levels of the corresponding phosphine radical cations obtained by density functional theory computations.

room-temperaturemolecular tripoddeactivated aryl chlorideshomogeneous catalysts010402 general chemistryDiamondoidselective preparationchemistry01 natural sciencesMedicinal chemistryChemical reaction[ CHIM ] Chemical Scienceschemistry.chemical_compoundOrganic chemistry[CHIM]Chemical SciencesarylationAlkylNanodiamonds ; Diamondoid Phosphines ; diamantane ; adamantane ; adamantylphosphinechemistry.chemical_classification010405 organic chemistryChemistryligandsArylOrganic Chemistrypalladiumphosphorylated adamantanes3. Good health0104 chemical sciencesChemical bondDensity functional theoryDiamantanePhosphine
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Carbon stocks in a 50‑year‑oldEucalyptus camaldulensisstand in Sicily, Italy

2015

Eucalyptus stands in semi-arid areas may contribute to enhance carbon (C) stocks in both biomass and soil. However, the limited information available is mainly focused on short-rotation plantations. In this study, the above- and below-ground C pools in five 50-year-old Eucalyptus camaldulensis Dehnh. stands planted on Miocenic evaporitic deposits in Sicily, Italy, with a xeric and thermic pedoclimate, were measured. Above-ground biomass was determined by partitioning and weighing branches, stem and leaves. Below-ground C pools included the determination of litter, root biomass, and soil organic and inorganic C. In terms of the above-ground biomass, the E. camaldulensis stand accumulated on …

rootsbelow-ground biomassSettore AGR/05 - Assestamento Forestale E Selvicolturasemi-arid Mediterranean climateSettore AGR/13 - Chimica AgrariaBiomassDeserts and xeric shrublandssoillitterbelow-ground biomaabove-ground biomassTotal organic carbonevaporitic depositsSoil organic matterabove-ground biomass; below-ground biomass; evaporitic deposits; litter; roots; semi-arid Mediterranean climate; soil; ForestryForestrySoil classificationForestryrootEucalyptusevaporitic depositEucalyptus camaldulensisAgronomySettore AGR/14 - PedologiaLitterEnvironmental scienceabove-ground biomaSouthern Forests: a Journal of Forest Science
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NMR-based quantification of rosmarinic and carnosic acids, GC-MS profile and bioactivity relevant to neurodegenerative disorders of Rosmarinus offici…

2013

Abstract A comparative study of phytochemicals content and biological properties of eight Rosmarinus officinalis (rosemary) populations (RO1–RO8) collected in different areas of Tunisia was carried out. Two of the main rosemary constituents, rosmarinic and carnosic acids, were quantified by an NMR technique. Carnosic acid content was higher than that of rosmarinic acid. The non-polar constituents were examined by GC and GC–MS. Total phenols and flavonoids content were also determined in order to discuss the possible correlation between these phytochemicals and bioactivity. Antioxidant activity was investigated through different in vitro assays. Sample RO3 from a sub-humid area showed the hi…

rosmarinic acidAntioxidantDPPHmedicine.medical_treatmentMedicine (miscellaneous)Rosmarinuschemistry.chemical_compoundAntioxidant activitymedicineAnticholinesterese activityTX341-641Settore BIO/15 - Biologia FarmaceuticaPhenolscarnosic acidNutrition and DieteticsABTSChromatographybiologyChemistryNutrition. Foods and food supplyRosmarinic acidCarnosic acidSettore CHIM/06 - Chimica OrganicaRosmarinic and carnosic acidsbiology.organism_classificationNMRBiochemistryRosmarinic and carnosic acidOfficinalisRosmarinus officinalisneurodegenerative disorderPhytochemicals contentFood Science
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Development of high-performance thin layer chromatography method for identification of phenolic compounds and quantification of rosmarinic acid conte…

2020

ABSTRACT Aim: Representatives of Nepetoideae Burnett subfamily are promising species of the Lamiaceae Martinov family because of accumulating such valuable groups of secondary metabolites as terpenoids and polyphenols. A high-performance thin layer chromatography (HPTLC) fingerprint method for the qualitative determination of phenolic compounds and for the quantification of rosmarinic acid (RA) content in methanol extracts of five species of this subfamily was developed for the first time. Materials and Methods: Dried aerial parts of Dracocephalum moldavica L., Ocimum americanum L., Lophanthus anisatus (Nutt.) Benth., Monarda fistulosa L., and Satureja hortensis L. collected in flowering pe…

rosmarinic acidlcsh:Analytical chemistrylcsh:RS1-441BioengineeringGeneral Biochemistry Genetics and Molecular Biologylamiaceaelcsh:Pharmacy and materia medica03 medical and health scienceschemistry.chemical_compound0302 clinical medicineChlorogenic acidCaffeic acid030212 general & internal medicineHigh performance thin layer chromatographyGeneral Pharmacology Toxicology and PharmaceuticsDracocephalum moldavicaphenolic compoundChromatographylcsh:QD71-142biologyRosmarinic acidchromatographic fingerprints030206 dentistrybiology.organism_classificationhigh-performance thin layer chromatographyThin-layer chromatographyOcimum americanumchemistryOriginal ArticleLamiaceaeJournal of Pharmacy and Bioallied Sciences
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