Search results for "COMPOSITE"

The performance of thin-film Li-ion batteries under flexural deflection

2006

A method is introduced to study the effects of flexural deformation on the electrical performance of thin-film lithium-ion batteries. Flexural deformation of thin films is of interest to engineers for applications that can be effective in conformal spaces in conjunction with multi-functional composite laminates in structural members under mechanical deflections such as thin airfoils used in unmanned aerial vehicles (UAVs). A test fixture was designed and built using rapid prototyping techniques. A baseline reference charge/discharge cycle was initially obtained with the device in its un-flexed state, in order to later contrast the performance of the thin-film battery when subjected to defle…

Equivalence Problem of Composite Class Diagrams

2001

Multiplicity constraints in a UML composite class diagram may be inconsistent. An algorithm is given for eliminating all such inconsistencies. Using this algorithm an algorithm is constructed which for two given composite class diagrams solves the equivalence problem. These algorithms can be embedded in CASE tools for automated detection of multiplicity inconsistencies.

Luminescence of silica glass containing aluminum oxide

2004

Abstract Optical properties of silica glass with different doping of Al 2 O 3 up to 1.5 mol% were studied. Alumina stimulates creation of a luminescence centers with specific band at 3.3 eV. A new band at 8.2 eV appears in luminescence excitation spectra. There is transport of energy to other luminescence centers associated with an impurity (Ag, Ce) at this energy. Alumina stimulates creation of E′ centers under γ-irradiation beside trapped hole on AlO 4 tetrahedron as well as creation of a silicon related oxygen deficient center (SiODC) under cathodoexcitation. Visually, the samples look inhomogeneous even after γ-irradiation. The explanation could be heterogeneity of the samples. Alumina …

2001

A new manganese(III) oxamato dimer possesing an unprecedented Mn2(μ-O2CR)(μ-OH2⋯O2 CR) core has been synthesised, structurally and magnetically characterised, and used as a catalyst for the oxidation of alkanes to alcohols and ketones by ButO2H and O2 in CH2Cl2 at rt.

Improved (photo)catalytic propene hydration in a gas/solid system by using heteropolyacid/oxide composites: Electron paramagnetic resonance, acidity,…

2017

Binary materials composed of the oxides SiO2, TiO2 and N-doped TiO2 and the Keggin heteropolyacid (PW12) were prepared and physicochemically characterized. They were used as catalysts and photocatalysts for the hydration of propene to 2-propanol. The characterization of the samples, particularly the electron paramagnetic resonance (EPR) spectroscopy results and the acidity properties, were useful to explain the key role played by the PW12 in the composite materials in the thermal and photoassisted catalytic processes. The simultaneous pres-ence of heat and UV light improved the activity of PW12 in the thermal process, and the binary materials showed better (photo)catalytic activities than t…

Recent advances in the synthesis of functionalised monofluorinated compounds.

2018

Over the past few years, we have tackled the synthesis of interesting monofluorinated organic molecules, such as: dihydronaphthalene derivatives, β-fluoro sulfones and related carbonyl compounds, fluorohydrins and allylic alcohols. Overall, a wide range of modern synthetic techniques are covered in this feature article including transition-metal, photo- and organocatalysis, nucleophilic and electrophilic fluorinations, chiral auxiliaries and enantioselective catalysis.

γ-Silylboronates in the chiral Brønsted acid-catalysed allylboration of aldehydes.

2014

The use of functionalised allylboronic esters in the catalytic enantioselective allylboration of aldehydes is described for the first time. γ-Silylallyl pinacolate derivatives give rise to α-silyl homoallylic alcohols in high yields, with complete diastereoselectivities and high enantioselectivities, in most of the cases. The usefulness of such intermediates is showcased by their transformation into fluorinated allylic alcohols.

Haemostatic agents on the shear bond strength of self-adhesive resin

2015

Background Dentin surface contaminated with haemostatic agents can interfere with the bonding of self-adhesive resin cement. Therefore the purpose of this study was to evaluate the effect of various haemostatic agents such as Aluminium chloride, Ferric sulphate and Tannic acid on the shear bond strength of self-adhesive resin luting agent. Material and Methods The buccal surfaces of extracted premolars were flattened to expose the dentine. The teeth were then randomly divided into four groups. In Group I Aluminium Chloride was applied on the flattened dentinal surface, in Group II Ferric Sulphate was applied to exposed dentin surface, in Group III tannic acid was applied on to the dentinal …

Pyroxene-based glass-ceramics as glazes for floor tiles

2005

Abstract Crystallization of a glass with composition in the diopside primary crystallization field in the MgO–CaO–Al 2 O 3 –SiO 2 quaternary system was investigated. Also the action of some additives, nucleants and fluxes, in the pyroxene development was examined. Glasses were prepared by conventional melting of a mixture of raw materials and cooled by pouring in water. Pellets of glass powder specimens were thermally treated at several temperatures up to 1200 °C. The crystallization path was followed by X-ray diffraction powder (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDX). The results proved that, in addition to the effect of B 2 O 3 and TiO 2 in…

Influence of Joint Geometry on Micro and Macro Mechanical Properties of Friction Stir Spot Welded Joints

2014

AbstractSpot welding can be considered a very common joining technique in automotive and transportation industries as it permits to obtain effective lap-joints with short process times and what is more it is easily developed through robots and automated systems. Recently, Friction Stir Spot Welding (FSSW) has been proposed as a natural evolution of the already known Friction Stir Welding (FSW) process, allowing to obtain sound spot joints that do not suffer from the insurgence of typical welding defects due to the melting of the base material. Similarly to FSW, both geometrical and technological parameters must be considered as they affect the material flow and the heat flux generated durin…