Search results for "CONDENSED MATTER"
showing 10 items of 13918 documents
$PT$-symmetric graphene under a magnetic field
2016
We propose a $PT$-symmetrically deformed version of the graphene tight-binding model under a magnetic field. We analyze the structure of the spectra and the eigenvectors of the Hamiltonians around the $K$ and $K'$ points, both in the $PT$-symmetric and $PT$-broken regions. In particular we show that the presence of the deformation parameter $V$ produces several interesting consequences, including the asymmetry of the zero-energy states of the Hamiltonians and the breakdown of the completeness of the eigenvector sets. We also discuss the biorthogonality of the eigenvectors, which {turns out to be} different in the $PT$-symmetric and $PT$-broken regions.
Autocatalytic reaction-diffusion processes in restricted geometries
2008
We study the dynamics of a system made up of particles of two different species undergoing irreversible quadratic autocatalytic reactions: $A + B \to 2A$. We especially focus on the reaction velocity and on the average time at which the system achieves its inert state. By means of both analytical and numerical methods, we are also able to highlight the role of topology in the temporal evolution of the system.
Generalized heat equation and transitions between different heat-transport regimes in narrow stripes
2019
Abstract In the framework of weakly nonlocal thermodynamic theory, in this paper we derive a nonlocal and nonlinear heat-transport equation beyond the Fourier law by means of thermodynamic considerations in agreement with the second law. The obtained equation describes the transitions among different heat-transport regimes. The stability of the solution of that equation is also analyzed in a special case.
Dynamics of Strongly Coupled Modes between Surface Plasmon Polaritons and Photoactive Molecules: The Effect of the Stokes Shift
2017
We have investigated the dynamics of strongly coupled modes of surface plasmon polaritons (SPPs) and fluorescent molecules by analyzing their scattered emission polarization. While the scattered emission of SPPs is purely transverse magnetic (TM) polarized, the strong coupling with molecules induces transverse electric (TE) polarized emission via the partial molecular nature of the formed SPP–molecule polariton mode. We observe that the TM/TE ratio of the polariton emission follows the contribution of the molecular excited states in this hybrid mode. By using several types of molecules, we observe that, in addition to the coupling strength, which determines the contribution of the molecular…
Preparation and physico-chemical study of inclusion complexes between idebenone and modified beta-cyclodextrins
1996
The inclusion properties of modifiedβ-cyclodextrins (trimethyl-β-cyclodextrin, dimethyl-β-cyclodextrin and hydroxypropyl-β-cyclodextrin) towards idebenone were compared with naturalβ-cyclodextrin. The inclusion complexes were prepared by different methods (coprecipitation, kneading, and freeze-drying) and characterized by differential scanning calorimetry, X-ray diffractometry, UV, CD and NMR spectroscopy. The results obtained by CD and NMR spectroscopy indicate a different orientation of idebenone in dimethyl-β-cyclodextrin with respect to other cyclodextrins. Stability constants of the complexes were determined in water at various temperatures and consequently thermodynamic parameters wer…
Tailoring oxide properties: An impact on adsorption characteristics of molecules and metals
2014
Abstract Both density functional theory calculations and numerous experimental studies demonstrate a variety of unique features in metal supported oxide films and transition metal doped simple oxides, which are markedly different from their unmodified counterparts. This review highlights, from the computational perspective, recent literature on the properties of the above mentioned surfaces and how they adsorb and activate different species, support metal aggregates, and even catalyse reactions. The adsorption of Au atoms and clusters on metal-supported MgO films are reviewed together with the cluster׳s theoretically predicted ability to activate and dissociate O 2 at the Au–MgO(100)/Ag(100…
Détection d'endommagement dans les composites fibres/résine à l'aide de la technologie micro-onde
2006
National audience; On présente dans cet article une méthode novatrice de contrôle non destructif d'endommagement dans les matériaux composites. Elle est fondée sur l'observation et l'analyse des modifications des propriétés diélectriques d'un milieu dues à un endommagement. Plus précisément, son originalité réside dans le fait que le diagnostic cherché est obtenu via un circuit résonant microbande soumis à un champ électromagnétique dans la gamme des micro-ondes. Dans cet article on montre la faisabilité de la méthode sur la détection de la rupture des fibres d'une éprouvette en composite unidirectionnel soumise à un effort de flexion et on indique en quoi elle possède potentiellement des a…
Squeezing of Quantum Noise of Motion in a Micromechanical Resonator
2015
A pair of conjugate observables, such as the quadrature amplitudes of harmonic motion, have fundamental fluctuations which are bound by the Heisenberg uncertainty relation. However, in a squeezed quantum state, fluctuations of a quantity can be reduced below the standard quantum limit, at the cost of increased fluctuations of the conjugate variable. Here we prepare a nearly macroscopic moving body, realized as a micromechanical resonator, in a squeezed quantum state. We obtain squeezing of one quadrature amplitude $1.1 \pm 0.4$ dB below the standard quantum limit, thus achieving a long-standing goal of obtaining motional squeezing in a macroscopic object.
Substituent effects of nitro group in cyclic compounds
2020
AbstractNumerous studies on nitro group properties are associated with its high electron-withdrawing ability, by means of both resonance and inductive effect. The substituent effect of the nitro group may be well described using either traditional substituent constants or characteristics based on quantum chemistry, i.e., cSAR, SESE, and pEDA/sEDA models. Interestingly, the cSAR descriptor allows to describe the electron-attracting properties of the nitro group regardless of the position and the type of system. Analysis of classical and reverse substituent effects of the nitro group in various systems indicates strong pi-electron interactions with electron-donating substituents due to the re…
High-resolution spectroscopy of difference and combination bands of SF6 to elucidate the ν3 + ν1 − ν1 and ν3 + ν2 − ν2 hot band structures in the ν3 …
2014
The strong infrared absorption in the ν3 S–F stretching region of sulphur hexafluoride (SF6) near 948 cm−1 makes it a powerful greenhouse gas. Although its present concentration in the atmosphere is very low, it is increasing rapidly, due to industrial pollution. The ground state population of this heavy species is only 32% at room temperature and thus many hot bands are present. Consequently, a reliable remote-sensing spectroscopic detection and monitoring of this species require an accurate modelling of these hot bands. We used two experimental set-ups at the SOLEIL French synchrotron facility to record some difference and combination bands of SF6: (1) a new cryogenic multiple pass cell w…