Search results for "CONST"
showing 10 items of 7706 documents
Hydrolysis and chemical speciation of dioxouranium(VI) ion in aqueous media simulating the major ion composition of seawater
2004
Abstract The hydrolysis and chemical speciation of the dioxouranium(VI) ion at 25 °C was studied in a number of binary electrolytes (LiCl, NaCl, MgCl2, CaCl2, Na2SO4) and some mixtures (NaCl–Na2SO4, NaNO3–Na2SO4, CaCl2–MgCl2) as well as artificial seawater (SSWE) as a function of ionic strength. The results in LiCl, CaCl2 and MgCl2 solutions confirmed the formation of (UO2)2(OH)22+, (UO2)3(OH)42+, (UO2)3(OH)5+ and (UO2)3(OH)7− species (at I=0 mol l−1: log Tβ22=−5.76, log Tβ34=−11.82, log Tβ35=−15.89 and log Tβ37=−29.26). For NaNO3, NaCl and artificial seawater the hydrolysis constant for the formation of the UO2(OH)+ species was also determined (at I=0 mol l−1: log Tβ11=−5.19). The results …
Novel solutions for closed-loop Reverse Electrodialysis: thermodynamic characterisation and perspective analysis
2019
Abstract Closed-loop Reverse Electrodialysis is a novel technology to directly convert low-grade heat into electricity. It consists of a reverse electrodialysis (RED) unit where electricity is produced exploiting the salinity gradient between two salt-water solutions, coupled with a regeneration unit where waste-heat is used to treat the solutions exiting from the RED unit and restore their initial composition. One of the most important advantages of closed-loop systems compared to the open systems is the possibility to select ad-hoc salt solutions to achieve high efficiencies. Therefore, the properties of the salt solutions are essential to assess the performance of the energy generation a…
A series expansion of the extended Debye-H�ckel equation and application to linear prediction of stability constants
1996
The Debye-Hückel semiempirical extended equation is frequently used to calculate activity coefficients of chemical species and equilibrium constants at ionic strengths different from those used in their experimental evaluation. A series expansion of the extended Debye-Hückel equation is proposed here and checked with experimental data taken from the literature. The expansion is linear in the ionic parameters and yields a geometrical series which converges rapidly and that enables the accurate calculation of interpolated and extrapolated activity coefficients and equilibrium constants by simple and multiple linear regression without previous knowledge of the ionic parameters.
Binding of a fluorescent dansylcadaverine-substance P analogue to negatively charged phospholipid membranes.
2000
Abstract We have investigated the binding of a new dansylcadaverine derivative of substance P (DNC-SP) with negatively charged small unilamellar vesicles composed of a mixture of phosphatidylcholine (PC) and either phosphatidylglycerol (PG) or phosphatidylserine (PS) using fluorescence spectroscopic techniques. The changes in fluorescence properties were used to obtain association isotherms at variable membrane negative charges and at different ionic strengths. The experimental association isotherms were analyzed using two binding approaches: (i) the Langmuir adsorption isotherm and the partition equilibrium model, that neglect the activity coefficients; and (ii) the partition equilibrium m…
Adaptive memory programing for the robust capacitated international sourcing problem
2008
The International Sourcing Problem consists of selecting a subset from an available set of potential suppliers internationally located. The selected suppliers must meet the demand for items from a set of plants, which are also located worldwide. Since the costs are affected by macroeconomic conditions in the countries where the supplier and the plant are located, the formulation considers the uncertainty associated with changes in these conditions. We formulate the robust capacitated international sourcing problem by means of a scenario-optimization approach. When dealing with uncertainty, one of the most common approaches in the literature is to formulate the problem via a set of possible …
Data-based modeling of vehicle crash using adaptive neural-fuzzy inference system
2014
Vehicle crashes are considered to be events that are extremely complex to be analyzed from the mathematical point of view. In order to establish a mathematical model of a vehicle crash, one needs to consider various areas of research. For this reason, to simplify the analysis and improve the modeling process, in this paper, a novel adaptive neurofuzzy inference system (ANFIS-based) approach to reconstruct kinematics of colliding vehicles is presented. A typical five-layered ANFIS structure is trained to reproduce kinematics (acceleration, velocity, and displacement) of a vehicle involved in an oblique barrier collision. Subsequently, the same ANFIS structure is applied to simulate different…
Measuring single small molecule binding via rupture forces of a split aptamer.
2011
The rupture force of a split (bipartite) aptamer that forms binding pockets for adenosine monophosphate (AMP) was measured by atomic force spectroscopy. Changes in the rupture force were observed in the presence of AMP, while this effect was absent when mutant aptamers or inosine were used. Thus, changes in the rupture force were a direct consequence of specific binding of AMP to the split aptamer. The split aptamer concept allowed the detection of nonlabeled AMP and enabled us to determine the dissociation constant on a single-molecule level.
THE TRANSFORMATION OF THE UNDERSTANDING OF JUDGE INDEPENDENCE IN LATVIA
2012
Latvian people’s craving for freedom culminated in the beginning of 1990-s. The activity of the Constitution of the Republic of Latvia was renewed, and the state power was returned to the people. From this moment, the work on dismantling the Soviet legal system in Latvia had started. A legal system had been redirected to the principles of the Western legal branch. The hard core of these principles was already in the Article 1 of the 1920 Constitution of the Republic of Latvia which states that Latvia is an independent and democratic republic. A key element of a democratic state is of a legal state. The division of powers, which is an essential element of a judge's independence, is in force …
Nanotechnology and earth construction: the mechanical properties of adobe brick stabilized by Laponite nanoparticles
2014
The contribution describes the experimental analysis for the improvement of the mechanical properties of samples of earth with the addition of Laponite nanoparticles. Were made two types of samples: the first consisting of soil, sand and water; the second consisting of soil, water, sand and Laponite nanoparticles. The operations performed were: chemical analysis of soil and sand; preparation of samples; Scanning Electron Microscope (SEM) observation of samples for the distribution of the elements, especially the Laponite nanoparticles; testing of compression strength and flexural strength of two types of samples; comparisons of the resulted of the mechanical tests. The improvement of the me…
Canova divulgato tra «Können» e «Wollen» nell’opera di Alfred Gotthold Meyer
2014
This article is a critical introduction to the Italian translation of Meyer's Canova monograph (1898), it focuses on the editorial process and on the use of photography during this early stage of popular art history. Further consideration is given to Meyer's critical point of view in the context of the German fin-de-siècle art discourse (Burckhardt, Springer, Bode, Wölfflin, Hildebrand).