Search results for "CORROSION"
showing 10 items of 456 documents
Photoelectrochemical monitoring of rouging and de-rouging on AISI 316L
2017
Electrochemical conditions for inducing rouging on surface of AISI 316L in quasi neutral aqueous solution are studied. Potentiostatic polarization at 0.6 V vs. SSC at pH ∼ 7 allowed growth of colourless passive films with a band gap slightly lower than that estimated for the oxide grown on the SS surface by air exposure due to chromium dissolution. Under stronger anodic polarization (UE = 1.5 V vs. SSC) coloured passive films are formed, mainly constituted by iron oxide according to their band gap (Eg = 2.0 eV). Etching in citric acid at 60 °C results to be effective in removing rouging.
Semiconducting properties of passive films and corrosion layers on weathering steel
2020
Abstract Anodic films were grown on Weathering Steel by potentiostatic polarization in slightly alkaline solution. The photoelectrochemical results reveal that they are n-type iron oxide with Eg = 2.0 eV. Rust layer grown by atmospheric corrosion are n-type semiconductors with a band gap higher than that estimated for the anodic film attributed to the formation of γ-lepidocrocite. The electrochemical impedance spectra allow to evidence that rust layers have a higher conductivity with respect to anodic films due to the presence of highly doped iron oxide layers. The use of Mott-Schottky theory to model the dependence of oxide capacitance as function of potential is critically discussed.
Photocurrent spectroscopy in passivity studies
2018
The aim of this article is to present photocurrent spectroscopy as useful in situ technique for the physicochemical characterization of passive films and corrosion layers. The response of (both amorphous and crystalline) semiconductor/electrolyte junction under irradiation is treated and discussed in order to get information about solid-state properties such as band gap and flat band potential. The possibility to use Photocurrent Spectroscopy (PCS), in a quantitative way, to get information on the composition of corrosion layers is discussed through a semiempirical correlation between the band gap of the oxides (or hydroxides) and the difference of electronegativity of their constituents. F…
Moment-axial force domain of corroded R.C. columns
2016
In the present paper, a simple model to determine the moment-axial force domain of the cross-section of reinforced concrete (R.C.) columns subjected to corrosion process is presented. The model considers members with square and rectangular cross-sections and it accounts for—cover spalling; buckling of longitudinal reinforcing bars; loss of bond of bar in tension; reduction of confinement pressures (due to the reduction of the area of stirrups and cracking of concrete induced by rust formation). The analytical expressions for prediction of the area reduction of steel, bond strength and critical load of longitudinal bars utilized were verified against experimental data available in the litera…
Influence of axial force and corrosion on failure of prestressed concrete structures considering M-V interaction
2021
Abstract Existing prestressed concrete structures suffer from degradation of prestressing for two main reasons: a defect of the sheath infills (cement grout) of bonded tendons, and corrosion of steel strands. These two causes, often concomitant, lead to a reduction over time of the effectiveness of initial prestressing, in addition to the ordinary tension losses due to concrete shrinkage and creep, and to steel relaxation. In many cases a consequence of bad grouting in bonded tendons is that the structure shows an intermediate behavior between that of external prestressing and that of internal bonded prestressing. This, added to damage to wires due to corrosion, makes it essential for the d…
Chitosan-Coating Deposition via Galvanic Coupling
2019
A galvanic method to deposit chitosan coatings on stainless steel substrate is reported. Deposition of suitable coatings is desired to improve biocompatibility and corrosion resistance of metallic medical devices to be implanted in human body. In the present work, a thin hydrogel layer of chitosan was deposited on 304SS by a galvanic displacement reaction, which is advantageous first as it does not require external power supply. 304SS was immersed into an aqueous solution of chitosan/lactic acid and electrochemically coupled with magnesium acting as a sacrificial anode. SEM images showed the formation of a uniform layer of chitosan with a thickness controlled by deposition time. Corrosion t…
New generation super alloy candidates for medical applications: Corrosion behavior, cation release and biological evaluation
2014
Three super alloy candidates (X1 CrNiMoMnW 24-22-6-3-2 N, NiCr21 MoNbFe 8-3-5 AlTi, CoNiCr 35-20 Mo 10 BTi) for a prolonged contact with skin are evaluated in comparison with two reference austenitic stainless steels 316L and 904L. Several electrochemical parameters were measured and determined (E(oc), E(corr), i(corr), b(a), b(c), E(b), R(p), E(crev) and coulometric analysis) in order to compare the corrosion behavior. The cation release evaluation and in vitro biological characterization also were performed. In terms of corrosion, the results reveal that the 904L steels presented the best behavior followed by the super austenitic steel X1 CrNiMoMnW 24-22-6-3-2 N. For the other two super a…
The effect of electrochemically simulated titanium cathodic corrosion products on ROS production and metabolic activity of osteoblasts and monocytes/…
2006
Nowadays aseptic loosening is the most common cause of orthopaedic implant failure. Some of its reasons have already been described up to now; however, others remain still hypothetical. Besides the inflammatory response to wear particles originating at different sources, the role of reactive oxygen species as products of cellular reactions and/or as a result of the process of corrosion of an implant leading to implant failure has recently been discussed too. In the present study, we used a galvanostatic polarization to simulate the cathodic partial reaction of the corrosion process at a titanium alloy surface. With respect to cells occurring at the interface of a metal implant, the behaviou…
Risk of failure in existing RC balcony and strength verification under degradation phenomena
2020
Abstract In the present paper, the safety conditions of reinforced concrete (RC) balconies subject to degradation phenomena caused by carbonation, presence of chlorides or water infiltration were examined. After a brief review of the typical damages of balconies occurring with detachments of plaster and bricks expulsion, some cases of collapses of balconies recently occurred were presented. Therefore, a calculation model was proposed for a hand verification of the flexural and shear strength of existing corroded T beams cast in place of lightened RC orthotropic slabs forming the balcony and for the calculus of deflection including slippage of steel bars. Diffused and pitting corrosion on st…
Heterogeneous crystallization of zinc hydroxystannate on galvanized steel for enhancing the bond strength at the rebar/concrete interface
2021
Abstract Zinc hydroxystannate (ZnSn(OH)6) coatings were deposited on galvanized carbon steel samples by an electroless heterogeneous crystallization process. Structural and morphological features of the coatings as a function of the immersion time were determined by X-ray diffraction, Raman Spectroscopy and Scanning Electron Microscopy revealing the presence of truncated octahedrons of crystalline ZnSn(OH)6. Electrochemical characterization in a simulated concrete pore solution without and with addition of chloride ions proved that the cathodic protection is preserved and that ZnSn(OH)6 improved the corrosion resistance of the rebars. Pull-out tests demonstrated an enhanced bond strength at…