Search results for "Capacitance"
showing 10 items of 112 documents
Highly Porous Wood Based Carbon Materials for Supercapacitors
2015
Wood based activated carbons synthesized by two-stage thermocatalytical synthesis with NaOH activator were studied and used as supercapacitor electrodes (sulphuric acid electrolyte). Porous structure and electrochemical properties of carbons vs synthesis conditions were assessed. It was found that there are correlations between carbons synthesis variables, their porosity and supercapacitors functional characteristics. At the temperature 600 o C and activator/precursor ratio 1.25 porosity decreased, however energy capacitance of supercapacitor increased calculating on elementary cell mass.
Direct Metal‐Free Chemical Vapor Deposition of Graphene Films on Insulating Substrates for Micro‐Supercapacitors with High Volumetric Capacitance
2019
Direct, metal‐free synthesis of graphene films on insulating substrates in a controlled manner is of great importance for applications in (opto)electronic and energy storage devices. Graphene films are fabricated on fused silica substrates without metal catalyst via chemical vapor deposition (CVD), using propionic acid as a carbon source. Film‐thickness is readily adjustable between 5 and 45 nm by changing the deposition time and flow rate of the precursor, displaying sheet resistance in the range of 0.27–1.86 kΩ□−1. The resulting graphene films are directly integrated into micro‐supercapacitors without film transfer or liquid‐phase processing, and demonstrate ultrahigh operation rates up t…
Metal-functionalized covalent organic frameworks as precursors of supercapacitive porous N-doped graphene
2017
Covalent Organic Frameworks (COFs) based on polyimine with several metal ions (FeIII, CoII and NiII) adsorbed into their cavities have shown the ability to generate N-doped porous graphene from their pyrolysis under controlled conditions. These highly corrugated and porous graphene sheets exhibit high values of specific capacitance, which make them useful as electrode materials for supercapacitors.
Cover Picture: Direct Metal‐Free Chemical Vapor Deposition of Graphene Films on Insulating Substrates for Micro‐Supercapacitors with High Volumetric …
2019
Impact of transparent conductive oxide on the admittance of thin film solar cells
2010
Abstract The impact of transparent electrically conducting oxide (TCO) on the admittance measurements of thin film p–i–n a-Si:H solar cells was investigated. Admittance measurements on solar cell devices, with different area and geometry, in a wide range of frequencies and biases were performed. The admittance measurements of the investigated solar cells, which use the TCO as an electrical contact, showed that the high frequency admittance per area unit depends on the area. This effect increases both with the probe frequency and the size of the solar cells. Transmission line model valid for strip geometry which explains how the resistivity of the TCO layer impacts the measured admittance of…
Photon Scanning Tunneling Microscopy and Reflection Scanning Microscopy
1991
The Photon Scanning Tunneling Microscope (PSTM) is the photon analogue to the Electron Scanning Tunneling Microscope (ESTM). It uses the evanescent field due to the total internal reflection (TIR) of a light beam in a prism modulated by a sample attached to the prism. The exponential decay of the evanescent field is characterized by the penetration depth dp and depends on the angle of incidence θ, the wavelength and polarization of the incident beam. Changes in intensity are monitored by a probe tip scanned over the surface, and the data are processed to generate an image of the sample. Images produced by a prototype instrument are shown to have a vertical resolution of about 3 A and a late…
Simplified hybrid PD model in voids: Pattern validation
2013
The purpose of the present work is to show the validation of a new model to simulate the physical phenomenon of partial discharge (PD) produced in air voids inside insulating epoxy resin. The model has been developed on the basis of a new approach that combines the known circuit model of three capacitors with a model used to describe the behavior of the ionized channel inside of the inclusion during the discharge phenomenon, short-circuiting the capacity that represents the void. The approach is based on time-variable conductance of the void, subjected to multistress conditions: voltage, temperature and pressure. The new approach has been developed from a time variable conductivity model us…
CMOS Capacitance-to-Time Converter-Based Interface for Differential Capacitive Sensors
2020
This paper presents pre-layout simulation results on a CMOS implementation of a capacitance-to-time converter-based electronic interface for differential capacitive sensors. Its simple architecture, comprising only three operational amplifiers (OA) and a digital mixer (inverted XOR gate) allows, by properly setting the values of seven biasing resistors, to fit the working range anywhere from few fF to hundreds of pF, giving the output quasi-digital signals (T and PW) in the useful μs-ms range (appropriate for direct interfacing with general purposes microcontrollers). A couple of illustrative examples are provided.
Analysis of adsorption of phospholipids at the 1,2-dichloroethane/water interface by electrochemical impedance spectroscopy: A study of the effect of…
2007
Abstract The adsorption behaviour of a series of phosphatidylcholines (PCs) with saturated carbon chains of different length (DLPC, DPPC, DSPC, DAPC, and DBPC) at the electrified 1,2-dichloroethane/water interface was studied by measuring electrochemical impedance spectroscopy at the polarized interface. Two different trends in the interfacial capacitance were observed for any of the PCs the capacity dependence on the applied potential: strong adsorption occurs at negative potential with a marked decrease of C ( E ); increase of capacity is observed at positive potentials. It is demonstrated that the interfacial lipid adsorption was dependent on phospholipid concentration, applied potential…