Search results for "Characterisation"
showing 10 items of 45 documents
Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H2O)2](C(CN)3)4…
2002
A new polynuclear copper(II) complex [Cu7(OH)6Cl2- (pn)6(H2O)2](C(CN)3)4Cl2 with hydroxo-bridging ligands has been prepared; the centrosymmetric cluster cation can be described as two Cu4O3Cl distorted cubane units sharing one copper cation. Clemente Juan, Juan Modesto, Juan.M.Clemente@uv.es ; Gomez Garcia, Carlos Jose, Carlos.Gomez@uv.es ; Coronado Miralles, Eugenio, Eugenio.Coronado@uv.es
Imaging pore space in tight gas sandstone reservoir: insights from broad ion beam cross-sectioning
2010
Monetization of tight gas reservoirs, which contain significant gas reserves world-wide, represents a challenge for the entire oil and gas industry. The development of new technologies to enhance tight gas reservoir productivity is strongly dependent on an improved understanding of the rock properties and especially the pore framework. Numerous methods are now available to characterize sandstone cores. However, the pore space characterization at pore scale remains difficult due to the fine pore size and delicate sample preparation, and has thus been mostly indirectly inferred until now. Here we propose a new method of ultra high-resolution petrography combining high resolution SEM and argon…
Similaritons in optical fiber Raman amplifiers
2005
This thesis presents the generation of optical similaritons in a normally dispersive Raman amplifier at telecom wavelengths. The pulses experimentally characterized by FROG technique exhibit a parabolic intensity profile with a linear chirp, in good agreement with results of numerical simulations.Several theoretical features of the similaritons have been experimentally studied. The dynamics of two similaritons with same or different central wavelengths is also investigated: similaritons are robust against collisions, whereas the interaction of similaritons leads to the generation of high-repetition rate dark soliton train.The similariton properties have been finally applied into three field…
Isolation and characterisation of autochthonous Saccharomyces cerevisiae from 'Pago' Merlot wines of Utiel-Requena (Spain) origin
2022
[EN] Background and Aims To achieve both the control of the undesirable yeasts and the improvement of the characteristics of Merlot 'Pago' wines, Saccharomyces cerevisiae yeast diversity was investigated in a spontaneous 'Pago' Merlot fermentation from the Utiel-Requena region (Spain). Isolates of S. cerevisiae were characterised by a holistic procedure using the same Merlot grape must from which they were isolated. Methods and Results Yeasts were identified by internal transcribed spacer analysis and typed by HinfI mDNA restriction analysis. Growth and metabolic characteristics of the isolates were determined by laboratory-scale (50 L) fermentations of Merlot must and the composition of th…
Detection and localisation of disulphide bonds in a synthetic peptide reproducing the sequence 1-30 of Par j 1.0101 by electrospray ionisation mass s…
2001
The structural characterisation of a synthetic peptide reproducing the sequence 1–30 of Par j 1.0101, a major allergenic protein present in the pollen of Parietaria judaica, by combined use of chemical and enzymatic cleavage, reversed-phase high-performance liquid chromatography (RP-HPLC) and electrospray ionisation mass spectrometry (ESI-MS), is described. Direct ESI-MS of the synthetic peptide after reaction with methyl iodide showed that the product is a mixture of two peptides: one form in which two out of the four cysteine residues present in the sequence are oxidised and a minor amount of another form in which all the cysteines are fully reduced. It was ascertained, using the combined…
Microstructural sensitivity of local porosity distributions
1992
The recently introduced concept of local porosity distributions for the geometric characterization of arbitrary porous media is scrutinized using computer generated pore space images. The paper presents the first direct determination of local porosity distributions from digital images. Pore space images with identical two point correlation functions are employed to analyse the geometrical sensitivity of the local porosity concept. The main finding is that local distributions can be used to discriminate between images which are indistinguishable using standard correlation functions. We also discuss the question of length scales associated with the local porosity concept.
Exact and approximate calculations for the conductivity of sandstones
1999
We analyze a three-dimensional pore space reconstruction of Fontainebleau sandstone and calculate from it the eective conductivity using local porosity theory. We compare this result with an exact calculation of the eective conductivity that solves directly the disordered Laplace equation. The prediction of local porosity theory is in good quantitative agreement with the exact result. c 1999 Elsevier Science B.V. All rights reserved.
Effect of the applied organic load rate on biodegradable polymer production by mixed microbial cultures in a Sequencing Batch Reactor
2006
This article studies the operation of a new process for the production of biopolymers (polyhydroxyalkanoates, PHAs) at different applied organic load rates (OLRs). The process is based on the aerobic enrichment of activated sludge to obtain mixed cultures able to store PHAs at high rates and yields. A mixture of acetic, lactic, and propionic acids at different concentrations (in the range 8.5-31.25 gCOD/L) was fed every 2 h in a sequencing batch reactor (SBR). The resulting applied OLR was in the range 8.5-31.25 gCOD/L/day. Even though, as expected, the increase in the OLR caused an increase in biomass concentration (up to about 8.7 g COD/L), it also caused a relevant decrease of maximal po…
Endosperm cintribution to Medicago truncatula seed development : characterization of a DOF transcription factor expressed in chalazal endosperm
2014
In the current context, which necessitates a reduction in inputs in crop systems and boosting of production of plant proteins to reduce France’s dependency on feed imports,, growing legumes represents an alternative. Grain legumes are major sources of proteins for animal and human nutrition. In the UMR1347 Agroécologie, the objectives of the study group "déterminismes Génétiques et Environnementaux de l’Adaptation des Plantes à des Systèmes de culture Innovants" (GEAPSI) are to promote legume cultivation and adaptation to environmental stresses, via multidisciplinary approaches (genetics, ecophysiology, molecular physiology). This thesis project was carried out in the "Étude des Mécanismes …
Tēlu raksturojums un galvenās tēmas Džeinas Ostinas romānā „Lepnums un aizspriedumi” un tā ekranizācijā
2017
Bakalaura darbs atspoguļo angļu rakstnieces Džeinas Ostinas noveles “Lepnums un aizspriedumi” (1813) un angļu kinorežisora Džo Raita filmas “Lepnums un aizspriedumi” (2005) analīzi. Pētījuma galvenais akcents ir vērsts uz apskatu par līdzībām un atšķirībām novelē un tās ekranizācijas tēlu raksturošanā un svarīgākajās tēmās, kuras ikdienas lasītājs vai skatītājs nevar pamanīt. Pētījuma metodes ietver tēlu raksturošanu, tēmu un filmu teorētisko materiālu, kā arī izvēlētās noveles un tās ekranizējuma analīzi. Pēc pētījuma veikšanas Bakalaura darba autors nonāk pie slēdziena, ka pēc Džeinas Ostinas noveles “Lepnums un aizspriedumi” Džo Raita režisētā filma “Lepnums un aizspriedumi” meistarīgi a…